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Spectrophotometric investigation of the complexing reaction between rutin and titanyloxalate anion in 50% ethanol
dc.creator | Kuntić, Vesna | |
dc.creator | Malešev, Dušan | |
dc.creator | Radović, Z | |
dc.creator | Vukojević, Vladana | |
dc.date.accessioned | 2019-09-02T10:51:50Z | |
dc.date.available | 2019-09-02T10:51:50Z | |
dc.date.issued | 2000 | |
dc.identifier.issn | 0026-9247 | |
dc.identifier.uri | https://farfar.pharmacy.bg.ac.rs/handle/123456789/233 | |
dc.description.abstract | In the present work, rutin (3,3',4',5,7-pentahydrohyflavone-3-rhamnoglucoside) was determinated via a complexing reaction with a titanyloxalate anion. K-2[TiO(C2O4)(2)] and rutin react in 50% ethanol forming a 1:2 complex in a pH range from 4.00 to 11.50, in which the TiO(C2O4)(2)(2-) ion is linked to rutin through the 4-carbonyl and 5-hydroxyl group. The thermodynamic stability constant log beta(2)(0) of the complex is determined to 10.80 at pH = 6.50. The change of the standard Gibbs free energy Delta G(0) amounts to -61 kJ . mol(-1), indicating that the process of complex formation is spontaneous. The optimal conditions for the spectrophotometric determination of microconcentrations of rutin are at pH = 6.40 and lambda = 430 nm, where the complex shows an absorption maximum with a molar absorption coefficient a(430) = (60+/-2) . 10(3) dm(3) . mol(-1) . cm(-1). The method is applied rutin determination from tablets. | en |
dc.publisher | Springer-Verlag Wien, Vienna | |
dc.rights | restrictedAccess | |
dc.source | Monatshefte für Chemie Chemical Monthly | |
dc.title | Spectrophotometric investigation of the complexing reaction between rutin and titanyloxalate anion in 50% ethanol | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Радовић, З; Кунтић, Весна; Малешев, Душан; Вукојевић, Владана; | |
dc.citation.volume | 131 | |
dc.citation.issue | 7 | |
dc.citation.spage | 769 | |
dc.citation.epage | 777 | |
dc.citation.other | 131(7): 769-777 | |
dc.citation.rank | M22 | |
dc.identifier.wos | 000088565300009 | |
dc.identifier.doi | 10.1007/s007060050024 | |
dc.identifier.scopus | 2-s2.0-0008626740 | |
dc.type.version | publishedVersion |