Exploring fullerene derivatives for optoelectronic applications: synthesis and characterization study
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2024
Authors
Jakšić, JovanaMilinković, Evgenija
Cvetanović, Katarina
Tokić-Vujošević, Zorana
Jovanov, Vladislav
Mitrović, Aleksandra
Maslak, Veselin
Article (Published version)
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In this study, we conducted a comprehensive investigation of newly synthesized fullerene derivatives developed for potential application in perovskite solar cells (PSCs). We explored three novel dihydrofuran-fused C60 fullerene derivatives (13, 14, and 15) that were specifically designed to enhance solubility and interaction with the substrate, fluorine-doped tin oxide (FTO). A comparative analysis was performed, with reference to the widely used phenyl-C61-butyric acid methyl ester (PCBM) and compound 12, from which 13, 14, and 15 are derived, to assess the impact of sugar units on materials properties. The synthesized compounds demonstrated significant solubility in common organic solvents, a critical factor in their potential application in wet-processed PSCs. Our investigation included electrochemical property analysis, thin film deposition, surface characterization, and electrochemical impedance spectroscopy (EIS). EIS measurements unveiled key insights into charge transfer proper...ties at the electrode/electrolyte interface, making the compounds attractive candidates for electron transport layers (ETLs) in PSCs.
Source:
Physical Chemistry Chemical Physics, 2024, 26, 1, 517-523Publisher:
- Royal Society of Chemistry
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-MESTD-inst-2020-200026)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200168 (University of Belgrade, Faculty of Chemistry) (RS-MESTD-inst-2020-200168)
DOI: 10.1039/d3cp04322c
ISSN: 1463-9076
PubMed: 38086627
WoS: 001122476600001
Scopus: 2-s2.0-85179611159
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PharmacyTY - JOUR AU - Jakšić, Jovana AU - Milinković, Evgenija AU - Cvetanović, Katarina AU - Tokić-Vujošević, Zorana AU - Jovanov, Vladislav AU - Mitrović, Aleksandra AU - Maslak, Veselin PY - 2024 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/5389 AB - In this study, we conducted a comprehensive investigation of newly synthesized fullerene derivatives developed for potential application in perovskite solar cells (PSCs). We explored three novel dihydrofuran-fused C60 fullerene derivatives (13, 14, and 15) that were specifically designed to enhance solubility and interaction with the substrate, fluorine-doped tin oxide (FTO). A comparative analysis was performed, with reference to the widely used phenyl-C61-butyric acid methyl ester (PCBM) and compound 12, from which 13, 14, and 15 are derived, to assess the impact of sugar units on materials properties. The synthesized compounds demonstrated significant solubility in common organic solvents, a critical factor in their potential application in wet-processed PSCs. Our investigation included electrochemical property analysis, thin film deposition, surface characterization, and electrochemical impedance spectroscopy (EIS). EIS measurements unveiled key insights into charge transfer properties at the electrode/electrolyte interface, making the compounds attractive candidates for electron transport layers (ETLs) in PSCs. PB - Royal Society of Chemistry T2 - Physical Chemistry Chemical Physics T1 - Exploring fullerene derivatives for optoelectronic applications: synthesis and characterization study VL - 26 IS - 1 SP - 517 EP - 523 DO - 10.1039/d3cp04322c ER -
@article{ author = "Jakšić, Jovana and Milinković, Evgenija and Cvetanović, Katarina and Tokić-Vujošević, Zorana and Jovanov, Vladislav and Mitrović, Aleksandra and Maslak, Veselin", year = "2024", abstract = "In this study, we conducted a comprehensive investigation of newly synthesized fullerene derivatives developed for potential application in perovskite solar cells (PSCs). We explored three novel dihydrofuran-fused C60 fullerene derivatives (13, 14, and 15) that were specifically designed to enhance solubility and interaction with the substrate, fluorine-doped tin oxide (FTO). A comparative analysis was performed, with reference to the widely used phenyl-C61-butyric acid methyl ester (PCBM) and compound 12, from which 13, 14, and 15 are derived, to assess the impact of sugar units on materials properties. The synthesized compounds demonstrated significant solubility in common organic solvents, a critical factor in their potential application in wet-processed PSCs. Our investigation included electrochemical property analysis, thin film deposition, surface characterization, and electrochemical impedance spectroscopy (EIS). EIS measurements unveiled key insights into charge transfer properties at the electrode/electrolyte interface, making the compounds attractive candidates for electron transport layers (ETLs) in PSCs.", publisher = "Royal Society of Chemistry", journal = "Physical Chemistry Chemical Physics", title = "Exploring fullerene derivatives for optoelectronic applications: synthesis and characterization study", volume = "26", number = "1", pages = "517-523", doi = "10.1039/d3cp04322c" }
Jakšić, J., Milinković, E., Cvetanović, K., Tokić-Vujošević, Z., Jovanov, V., Mitrović, A.,& Maslak, V.. (2024). Exploring fullerene derivatives for optoelectronic applications: synthesis and characterization study. in Physical Chemistry Chemical Physics Royal Society of Chemistry., 26(1), 517-523. https://doi.org/10.1039/d3cp04322c
Jakšić J, Milinković E, Cvetanović K, Tokić-Vujošević Z, Jovanov V, Mitrović A, Maslak V. Exploring fullerene derivatives for optoelectronic applications: synthesis and characterization study. in Physical Chemistry Chemical Physics. 2024;26(1):517-523. doi:10.1039/d3cp04322c .
Jakšić, Jovana, Milinković, Evgenija, Cvetanović, Katarina, Tokić-Vujošević, Zorana, Jovanov, Vladislav, Mitrović, Aleksandra, Maslak, Veselin, "Exploring fullerene derivatives for optoelectronic applications: synthesis and characterization study" in Physical Chemistry Chemical Physics, 26, no. 1 (2024):517-523, https://doi.org/10.1039/d3cp04322c . .