TY  - JOUR
AU  - Mitić, Dragana
AU  - Milenković, Marina
AU  - Milosavljević, Slobodan
AU  - Gođevac, Dejan
AU  - Miodragović, Zoran M.
AU  - Anđelković, Katarina
AU  - Miodragović, Djenana
PY  - 2009
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1222
AB  - In this paper the first complexes of M2+ ions (M2+ = Zn2+, Cd2+ and Co2+) with N-benzyloxycarbonyl-S-phenylalaninato ligand (1-3) are described. The new complexes were characterized by means of elemental analysis, IR and UV-vis spectroscopy, molar conductivity measurements and H-1, C-13 and N-15 NMR spectroscopy (1D and 2D). The Co(II) complex adopts an octahedral geometry, and the Zn(II) and Cd(II) complexes adopt a tetrahedral one. For the first time, the antimicrobial activity of N-benzyloxycarbonyl-S-phenylalaninato ligand (N-Boc-S-phe) and the complexes 1-3 was investigated against Gram-positive: Micrococcus luteus, Staphylococcus aureus, Staphylococcus epidermidis, Enterococcus faecalis and Bacillus subtilis and Gram-negative bacteria: Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa and two strains of the yeast Candida albicans. It was shown that the complexes were effective against most strains. The best activity was detected against the yeast C. albicans.
PB  - Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux
T2  - European Journal of Medicinal Chemistry
T1  - Synthesis, characterization and antimicrobial activity of Co(II), Zn(II) and Cd(II) complexes with N-benzyloxycarbonyl-S-phenylalanine
VL  - 44
IS  - 4
SP  - 1537
EP  - 1544
DO  - 10.1016/j.ejmech.2008.07.017
ER  - 

@article{
author = "Mitić, Dragana and Milenković, Marina and Milosavljević, Slobodan and Gođevac, Dejan and Miodragović, Zoran M. and Anđelković, Katarina and Miodragović, Djenana",
year = "2009",
abstract = "In this paper the first complexes of M2+ ions (M2+ = Zn2+, Cd2+ and Co2+) with N-benzyloxycarbonyl-S-phenylalaninato ligand (1-3) are described. The new complexes were characterized by means of elemental analysis, IR and UV-vis spectroscopy, molar conductivity measurements and H-1, C-13 and N-15 NMR spectroscopy (1D and 2D). The Co(II) complex adopts an octahedral geometry, and the Zn(II) and Cd(II) complexes adopt a tetrahedral one. For the first time, the antimicrobial activity of N-benzyloxycarbonyl-S-phenylalaninato ligand (N-Boc-S-phe) and the complexes 1-3 was investigated against Gram-positive: Micrococcus luteus, Staphylococcus aureus, Staphylococcus epidermidis, Enterococcus faecalis and Bacillus subtilis and Gram-negative bacteria: Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa and two strains of the yeast Candida albicans. It was shown that the complexes were effective against most strains. The best activity was detected against the yeast C. albicans.",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux",
journal = "European Journal of Medicinal Chemistry",
title = "Synthesis, characterization and antimicrobial activity of Co(II), Zn(II) and Cd(II) complexes with N-benzyloxycarbonyl-S-phenylalanine",
volume = "44",
number = "4",
pages = "1537-1544",
doi = "10.1016/j.ejmech.2008.07.017"
}

Mitić, D., Milenković, M., Milosavljević, S., Gođevac, D., Miodragović, Z. M., Anđelković, K.,& Miodragović, D.. (2009). Synthesis, characterization and antimicrobial activity of Co(II), Zn(II) and Cd(II) complexes with N-benzyloxycarbonyl-S-phenylalanine. in European Journal of Medicinal Chemistry
Elsevier France-Editions Scientifiques Medicales Elsevier, Issy-Les-Moulineaux., 44(4), 1537-1544.
https://doi.org/10.1016/j.ejmech.2008.07.017

Mitić D, Milenković M, Milosavljević S, Gođevac D, Miodragović ZM, Anđelković K, Miodragović D. Synthesis, characterization and antimicrobial activity of Co(II), Zn(II) and Cd(II) complexes with N-benzyloxycarbonyl-S-phenylalanine. in European Journal of Medicinal Chemistry. 2009;44(4):1537-1544.
doi:10.1016/j.ejmech.2008.07.017 .

Mitić, Dragana, Milenković, Marina, Milosavljević, Slobodan, Gođevac, Dejan, Miodragović, Zoran M., Anđelković, Katarina, Miodragović, Djenana, "Synthesis, characterization and antimicrobial activity of Co(II), Zn(II) and Cd(II) complexes with N-benzyloxycarbonyl-S-phenylalanine" in European Journal of Medicinal Chemistry, 44, no. 4 (2009):1537-1544,
https://doi.org/10.1016/j.ejmech.2008.07.017 . .

TY  - JOUR
AU  - Vucković, Gordana
AU  - Tanasković, Slađana
AU  - Miodragović, Zoran M.
AU  - Stanić, V.
PY  - 2007
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/996
AB  - Three new binuclear Co(II) mixed-ligand complexes with N,N′,N′′,N′′′-tetrakis( 2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and mono- or dicarboxylate ligands were prepared and some of their physical properties were determined. The general formulas: [Co2(HCOO)2tpmc](ClO4)2·4H2O, [Co2(CH3COO)2tpmc](ClO4)2 and [Co2(tpht)tpmc](ClO4)2·4H2O (tphtH2 = terephthalic acid) were proposed on the basis of elemental analyses (C,H,N) and molar conductivity. UV/Vis absorption and IR spectra, magnetic and CV measurements were used to study their geometries and properties. For the monocarboxylate complexes, an exo coordination of Co(II) with four nitrogens from tpmc and bis-bidentate bonded HCOO-/CH3COO- in the trans position is assumed. Tpmc adopts the chair conformation. For the dicarboxylate complex, it is supposed that a terephthalate dianion, as well as methylene chains from cyclam bridge two Co(II) atoms, while tpmc is in the boat conformation. The complexes were stable against chemical and electrochemical oxidation of Co(II) to Co(III). The data are compared with those for the previously published Cu(II) complexes containing the corresponding ligands and mutual similarities or differences were considered. Finally, some antibacterial activity of the complexes was found.
AB  - Dobijena su tri nova dinuklearna Co(II) mešovito-ligandna kompleksa sa N,N′,N′′,N′′′- -tetrakis(2-piridilmetil)-1,4,8,11-tetraazaciklotetradekanom (tpmc) i mono- ili dikarboksilato ligandima i određena su neka njihova fizička svojstva. Opšte formule: [Co2(HCOO)2tpmc](ClO4)2·4H2O, [Co2(CH3COO)2tpmc](ClO4)2 i [Co2(tpht)tpmc](ClO4)2·4H2O (tphtH2 = tereftalna kiselina) predložene su na osnovu rezultata analize (C,H,N) i merenja molarne električne provodljivosti. UV/Vis i IR spektri, magnetna i CV merenja korišćena su za proučavanje geometrije i osobina ovih jedinjenja. Za monokarboksilatne komplekse predložena je exo koordinacija Co(II) sa četiri azotova atoma tpmc-a i bis-bidentatno vezanim HCOO¯/CH3COO¯) u trans položaju. Tpmc zauzima konformaciju stolice. Pretpostavljeno je da tereftalatni dianjon, kao i metilenske grupe ciklama premošćuju dva atoma Co(II), a tpmc je u konformaciji lađe. Kompleksi su stabilni prema hemijskoj i elektrohemijskoj oksidaciji Co(II) u Co(III). Podaci su upoređeni sa ranije objavljenim Cu(II) kompleksima koji sadrže odgovarajuće ligande i razmatrane su međusobne sličnosti i razlike. Najzad, utvrđena je izvesna antimikrobna aktivnost kompleksa.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - High-spin binuclear Co(II) complexes with a pendant octaazamaclocycle and carboxylates
T1  - Visokospinski Co(II) kompleksi sa pendantnim oktaazamakrociklom i karboksilatima
VL  - 72
IS  - 12
SP  - 1295
EP  - 1308
DO  - 10.2298/JSC0712295V
ER  - 

@article{
author = "Vucković, Gordana and Tanasković, Slađana and Miodragović, Zoran M. and Stanić, V.",
year = "2007",
abstract = "Three new binuclear Co(II) mixed-ligand complexes with N,N′,N′′,N′′′-tetrakis( 2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and mono- or dicarboxylate ligands were prepared and some of their physical properties were determined. The general formulas: [Co2(HCOO)2tpmc](ClO4)2·4H2O, [Co2(CH3COO)2tpmc](ClO4)2 and [Co2(tpht)tpmc](ClO4)2·4H2O (tphtH2 = terephthalic acid) were proposed on the basis of elemental analyses (C,H,N) and molar conductivity. UV/Vis absorption and IR spectra, magnetic and CV measurements were used to study their geometries and properties. For the monocarboxylate complexes, an exo coordination of Co(II) with four nitrogens from tpmc and bis-bidentate bonded HCOO-/CH3COO- in the trans position is assumed. Tpmc adopts the chair conformation. For the dicarboxylate complex, it is supposed that a terephthalate dianion, as well as methylene chains from cyclam bridge two Co(II) atoms, while tpmc is in the boat conformation. The complexes were stable against chemical and electrochemical oxidation of Co(II) to Co(III). The data are compared with those for the previously published Cu(II) complexes containing the corresponding ligands and mutual similarities or differences were considered. Finally, some antibacterial activity of the complexes was found., Dobijena su tri nova dinuklearna Co(II) mešovito-ligandna kompleksa sa N,N′,N′′,N′′′- -tetrakis(2-piridilmetil)-1,4,8,11-tetraazaciklotetradekanom (tpmc) i mono- ili dikarboksilato ligandima i određena su neka njihova fizička svojstva. Opšte formule: [Co2(HCOO)2tpmc](ClO4)2·4H2O, [Co2(CH3COO)2tpmc](ClO4)2 i [Co2(tpht)tpmc](ClO4)2·4H2O (tphtH2 = tereftalna kiselina) predložene su na osnovu rezultata analize (C,H,N) i merenja molarne električne provodljivosti. UV/Vis i IR spektri, magnetna i CV merenja korišćena su za proučavanje geometrije i osobina ovih jedinjenja. Za monokarboksilatne komplekse predložena je exo koordinacija Co(II) sa četiri azotova atoma tpmc-a i bis-bidentatno vezanim HCOO¯/CH3COO¯) u trans položaju. Tpmc zauzima konformaciju stolice. Pretpostavljeno je da tereftalatni dianjon, kao i metilenske grupe ciklama premošćuju dva atoma Co(II), a tpmc je u konformaciji lađe. Kompleksi su stabilni prema hemijskoj i elektrohemijskoj oksidaciji Co(II) u Co(III). Podaci su upoređeni sa ranije objavljenim Cu(II) kompleksima koji sadrže odgovarajuće ligande i razmatrane su međusobne sličnosti i razlike. Najzad, utvrđena je izvesna antimikrobna aktivnost kompleksa.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "High-spin binuclear Co(II) complexes with a pendant octaazamaclocycle and carboxylates, Visokospinski Co(II) kompleksi sa pendantnim oktaazamakrociklom i karboksilatima",
volume = "72",
number = "12",
pages = "1295-1308",
doi = "10.2298/JSC0712295V"
}

Vucković, G., Tanasković, S., Miodragović, Z. M.,& Stanić, V.. (2007). High-spin binuclear Co(II) complexes with a pendant octaazamaclocycle and carboxylates. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 72(12), 1295-1308.
https://doi.org/10.2298/JSC0712295V

Vucković G, Tanasković S, Miodragović ZM, Stanić V. High-spin binuclear Co(II) complexes with a pendant octaazamaclocycle and carboxylates. in Journal of the Serbian Chemical Society. 2007;72(12):1295-1308.
doi:10.2298/JSC0712295V .

Vucković, Gordana, Tanasković, Slađana, Miodragović, Zoran M., Stanić, V., "High-spin binuclear Co(II) complexes with a pendant octaazamaclocycle and carboxylates" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1295-1308,
https://doi.org/10.2298/JSC0712295V . .

TY  - JOUR
AU  - Vučković, Gordana
AU  - Miodragović, Zoran M.
AU  - Tanasković, Slađana
PY  - 2004
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/552
AB  - Two new Cu(II) complexes with N,N’,N",N’’’-tetrakis(2-pyridylmethyl) -1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides (NCO- or NCSe-) were isolated. Elemental analyses (C, H, N, Cu) corresponded to the formulas [Cu2(NCO)tpmc](ClO4)3. 2CH3CN and [Cu2(NCSe)2 tpmc] (ClO4)2. 2H2O. C2H5OH. The coordination mode of tpmc and these ambidentate pseudohalides, geometries spectral characteristics (VIS, IR) and other properties were compared with those of the previously described [Cu2(NCS)2tpmc] (ClO4)2. Antimicrobial activity towards selected bacteria and yeast was tested and found for the NCSe but not the NCO complex.
AB  - Dobijena su dva nova Cu(II) kompleksa sa N,N’,N’’,N’’’-tetrakis(2-piridilmetil)-1,4,8,11-tetraazacikotetradekanom (tpmc) i pseudohalogenidima (NCO– ili NCSe–). Elementalna analiza (C, H, N Cu) odgovarala je formulama: [Cu2(NCO)tpmc](ClO4)3. 2CH3CN i [Cu2(NCSe)2 tpmc](ClO4)2. 2H2O. C2H5OH. Način koordinacije tpmc-a i ovih ambidentatnih pseudohalogenida, geometrijski raspored, spektralne karakteristike (VIS, IR) i dr. su upoređene sa ranije opisanim [Cu2(NCS)2tpmc](ClO4)2. Antimikrobna aktivnost prema nekim bakterijama i gljivicama je testirana i nađena samo u slučaju NCSe kompleksa.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Preparation and properties of Cu(II) complexes with N,N’,N',N’’’-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides(NCO- orNCSe-): Part II
T1  - Dobijanje i osobine CU(II)kompleksa Sa N,N’,N',N’’’-tetrakis(2-piridilmetil)-1,4,8,11-tetra a za ciklotetradekanom(tpmc)i pseudo halogenidima (NCO- ili NCSe-) - II deo
VL  - 69
IS  - 1
SP  - 17
EP  - 23
DO  - 10.2298/JSC0401017V
ER  - 

@article{
author = "Vučković, Gordana and Miodragović, Zoran M. and Tanasković, Slađana",
year = "2004",
abstract = "Two new Cu(II) complexes with N,N’,N",N’’’-tetrakis(2-pyridylmethyl) -1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides (NCO- or NCSe-) were isolated. Elemental analyses (C, H, N, Cu) corresponded to the formulas [Cu2(NCO)tpmc](ClO4)3. 2CH3CN and [Cu2(NCSe)2 tpmc] (ClO4)2. 2H2O. C2H5OH. The coordination mode of tpmc and these ambidentate pseudohalides, geometries spectral characteristics (VIS, IR) and other properties were compared with those of the previously described [Cu2(NCS)2tpmc] (ClO4)2. Antimicrobial activity towards selected bacteria and yeast was tested and found for the NCSe but not the NCO complex., Dobijena su dva nova Cu(II) kompleksa sa N,N’,N’’,N’’’-tetrakis(2-piridilmetil)-1,4,8,11-tetraazacikotetradekanom (tpmc) i pseudohalogenidima (NCO– ili NCSe–). Elementalna analiza (C, H, N Cu) odgovarala je formulama: [Cu2(NCO)tpmc](ClO4)3. 2CH3CN i [Cu2(NCSe)2 tpmc](ClO4)2. 2H2O. C2H5OH. Način koordinacije tpmc-a i ovih ambidentatnih pseudohalogenida, geometrijski raspored, spektralne karakteristike (VIS, IR) i dr. su upoređene sa ranije opisanim [Cu2(NCS)2tpmc](ClO4)2. Antimikrobna aktivnost prema nekim bakterijama i gljivicama je testirana i nađena samo u slučaju NCSe kompleksa.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Preparation and properties of Cu(II) complexes with N,N’,N',N’’’-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides(NCO- orNCSe-): Part II, Dobijanje i osobine CU(II)kompleksa Sa N,N’,N',N’’’-tetrakis(2-piridilmetil)-1,4,8,11-tetra a za ciklotetradekanom(tpmc)i pseudo halogenidima (NCO- ili NCSe-) - II deo",
volume = "69",
number = "1",
pages = "17-23",
doi = "10.2298/JSC0401017V"
}

Vučković, G., Miodragović, Z. M.,& Tanasković, S.. (2004). Preparation and properties of Cu(II) complexes with N,N’,N',N’’’-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides(NCO- orNCSe-): Part II. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 69(1), 17-23.
https://doi.org/10.2298/JSC0401017V

Vučković G, Miodragović ZM, Tanasković S. Preparation and properties of Cu(II) complexes with N,N’,N',N’’’-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides(NCO- orNCSe-): Part II. in Journal of the Serbian Chemical Society. 2004;69(1):17-23.
doi:10.2298/JSC0401017V .

Vučković, Gordana, Miodragović, Zoran M., Tanasković, Slađana, "Preparation and properties of Cu(II) complexes with N,N’,N',N’’’-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) and pseudohalides(NCO- orNCSe-): Part II" in Journal of the Serbian Chemical Society, 69, no. 1 (2004):17-23,
https://doi.org/10.2298/JSC0401017V . .