Maksimović, Jelena

Link to this page

Authority KeyName Variants
a5e588da-4b8a-4466-a
  • Maksimović, Jelena (10)
Projects

Author's Bibliography

Bray–Liebhafsky oscillatory reaction in a continuous-flow stirred tank reactor as the matrix system for determination of tyrosine

Negrojević, Luka; Lončar, Aleksandar; Maksimović, Jelena; Anić, Slobodan; Čupić, Željko; Kolar-Anić, Ljiljana; Pejić, Nataša

(Springer Science and Business Media B.V., 2022)

TY  - JOUR
AU  - Negrojević, Luka
AU  - Lončar, Aleksandar
AU  - Maksimović, Jelena
AU  - Anić, Slobodan
AU  - Čupić, Željko
AU  - Kolar-Anić, Ljiljana
AU  - Pejić, Nataša
PY  - 2022
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/4022
AB  - A kinetic method for the determination of l-tyrosine (Tyr) by analyte pulse perturbation, caused by different amounts of Tyr, in the Bray–Liebhafsky (BL) oscillatory reaction realized in a continuous-flow stirred tank reactor, is proposed. For such purposes, the BL oscillating reaction was kept in a stable non-equilibrium stationary state close to the bifurcation point and was used as the matrix reaction system. Under optimum reaction conditions, the linear relationship between the kinetic parameters, Δτ2 (the period between first two oscillations that appear after applied perturbation) as well as τend (the time elapsed between the perturbation of the BL reaction by Tyr and the termination of the oscillatory phase) and the Tyr concentrations is obtained over the ranges 1.1 × 10− 6 − 9.2 × 10− 6 mol L− 1 and 1.1 × 10− 6 − 1.4 × 10− 5 mol L− 1, with the limit of detections of 6.6 × 10− 7 mol L− 1 and 6.4 × 10− 7 mol L− 1. The described method that relies on a simple instrumental set-up, has been successfully applied to the determination of Tyr in a dietary supplement. Some aspects of the possible mechanism of Tyr action on the BL oscillator are discussed.
PB  - Springer Science and Business Media B.V.
T2  - Reaction Kinetics, Mechanisms and Catalysis
T1  - Bray–Liebhafsky oscillatory reaction in a continuous-flow stirred tank reactor as the matrix system for determination of tyrosine
DO  - 10.1007/s11144-021-02130-5
ER  - 
@article{
author = "Negrojević, Luka and Lončar, Aleksandar and Maksimović, Jelena and Anić, Slobodan and Čupić, Željko and Kolar-Anić, Ljiljana and Pejić, Nataša",
year = "2022",
abstract = "A kinetic method for the determination of l-tyrosine (Tyr) by analyte pulse perturbation, caused by different amounts of Tyr, in the Bray–Liebhafsky (BL) oscillatory reaction realized in a continuous-flow stirred tank reactor, is proposed. For such purposes, the BL oscillating reaction was kept in a stable non-equilibrium stationary state close to the bifurcation point and was used as the matrix reaction system. Under optimum reaction conditions, the linear relationship between the kinetic parameters, Δτ2 (the period between first two oscillations that appear after applied perturbation) as well as τend (the time elapsed between the perturbation of the BL reaction by Tyr and the termination of the oscillatory phase) and the Tyr concentrations is obtained over the ranges 1.1 × 10− 6 − 9.2 × 10− 6 mol L− 1 and 1.1 × 10− 6 − 1.4 × 10− 5 mol L− 1, with the limit of detections of 6.6 × 10− 7 mol L− 1 and 6.4 × 10− 7 mol L− 1. The described method that relies on a simple instrumental set-up, has been successfully applied to the determination of Tyr in a dietary supplement. Some aspects of the possible mechanism of Tyr action on the BL oscillator are discussed.",
publisher = "Springer Science and Business Media B.V.",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
title = "Bray–Liebhafsky oscillatory reaction in a continuous-flow stirred tank reactor as the matrix system for determination of tyrosine",
doi = "10.1007/s11144-021-02130-5"
}
Negrojević, L., Lončar, A., Maksimović, J., Anić, S., Čupić, Ž., Kolar-Anić, L.,& Pejić, N.. (2022). Bray–Liebhafsky oscillatory reaction in a continuous-flow stirred tank reactor as the matrix system for determination of tyrosine. in Reaction Kinetics, Mechanisms and Catalysis
Springer Science and Business Media B.V...
https://doi.org/10.1007/s11144-021-02130-5
Negrojević L, Lončar A, Maksimović J, Anić S, Čupić Ž, Kolar-Anić L, Pejić N. Bray–Liebhafsky oscillatory reaction in a continuous-flow stirred tank reactor as the matrix system for determination of tyrosine. in Reaction Kinetics, Mechanisms and Catalysis. 2022;.
doi:10.1007/s11144-021-02130-5 .
Negrojević, Luka, Lončar, Aleksandar, Maksimović, Jelena, Anić, Slobodan, Čupić, Željko, Kolar-Anić, Ljiljana, Pejić, Nataša, "Bray–Liebhafsky oscillatory reaction in a continuous-flow stirred tank reactor as the matrix system for determination of tyrosine" in Reaction Kinetics, Mechanisms and Catalysis (2022),
https://doi.org/10.1007/s11144-021-02130-5 . .
1

Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation

Pejić, Nataša; Kolar-Anić, Ljiljana; Maksimović, Jelena; Janković, Marija; Vukojević, Vladana; Anić, Slobodan

(Springer, Dordrecht, 2016)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Kolar-Anić, Ljiljana
AU  - Maksimović, Jelena
AU  - Janković, Marija
AU  - Vukojević, Vladana
AU  - Anić, Slobodan
PY  - 2016
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2528
AB  - The temporal dynamics of the Bray-Liebhafsky reaction (iodate-based catalytic decomposition of hydrogen peroxide in an acidic aqueous solution) was experimentally characterized in a continuous stirred tank reactor by independently varying the temperature and the mixed inflow hydrogen peroxide concentration. When the temperature was the bifurcation parameter, the emergence/disappearance of oscillatory behavior via a supercritical Andronov-Hopf bifurcation was observed for different mixed inflow hydrogen peroxide concentrations. An increase in the mixed inflow hydrogen-peroxide concentration resulted in a shift of the bifurcation point towards higher values of temperature, but did not alter the bifurcation type.
PB  - Springer, Dordrecht
T2  - Records of Natural Products
T1  - Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation
VL  - 118
IS  - 1
SP  - 15
EP  - 26
DO  - 10.1007/s11144-016-0984-y
ER  - 
@article{
author = "Pejić, Nataša and Kolar-Anić, Ljiljana and Maksimović, Jelena and Janković, Marija and Vukojević, Vladana and Anić, Slobodan",
year = "2016",
abstract = "The temporal dynamics of the Bray-Liebhafsky reaction (iodate-based catalytic decomposition of hydrogen peroxide in an acidic aqueous solution) was experimentally characterized in a continuous stirred tank reactor by independently varying the temperature and the mixed inflow hydrogen peroxide concentration. When the temperature was the bifurcation parameter, the emergence/disappearance of oscillatory behavior via a supercritical Andronov-Hopf bifurcation was observed for different mixed inflow hydrogen peroxide concentrations. An increase in the mixed inflow hydrogen-peroxide concentration resulted in a shift of the bifurcation point towards higher values of temperature, but did not alter the bifurcation type.",
publisher = "Springer, Dordrecht",
journal = "Records of Natural Products",
title = "Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation",
volume = "118",
number = "1",
pages = "15-26",
doi = "10.1007/s11144-016-0984-y"
}
Pejić, N., Kolar-Anić, L., Maksimović, J., Janković, M., Vukojević, V.,& Anić, S.. (2016). Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation. in Records of Natural Products
Springer, Dordrecht., 118(1), 15-26.
https://doi.org/10.1007/s11144-016-0984-y
Pejić N, Kolar-Anić L, Maksimović J, Janković M, Vukojević V, Anić S. Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation. in Records of Natural Products. 2016;118(1):15-26.
doi:10.1007/s11144-016-0984-y .
Pejić, Nataša, Kolar-Anić, Ljiljana, Maksimović, Jelena, Janković, Marija, Vukojević, Vladana, Anić, Slobodan, "Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation" in Records of Natural Products, 118, no. 1 (2016):15-26,
https://doi.org/10.1007/s11144-016-0984-y . .
3
9
10
10

Perturbations of the Dushman Reaction with Piroxicam: Experimental and Model Calculations

Pejić, Nataša; Blagojević, Slavica; Sarap, Nataša B.; Maksimović, Jelena; Anić, Slobodan; Čupić, Željko; Kolar-Anić, Ljiljana

(Wiley-VCH Verlag GMBH, Weinheim, 2014)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Blagojević, Slavica
AU  - Sarap, Nataša B.
AU  - Maksimović, Jelena
AU  - Anić, Slobodan
AU  - Čupić, Željko
AU  - Kolar-Anić, Ljiljana
PY  - 2014
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2172
AB  - Perturbation of the BrayLiebhafsky non-oscillating subsystem (mixture of KIO3 and H2SO4), i.e., Dushman reaction (DR), by piroxicam (PX), was observed in an open reactor, i.e., in the continuously fed well-stirred tank reactor (CSTR). Monitoring the response of DR to perturbations by different concentrations of PX allows developing a simple procedure for quantitative determination of this analyte in both bulk drug and pharmaceutical preparation (injection). A tentative perturbation mechanism of PX action on the DR matrix, based on a kinetic scheme that was suggested by Agreda etal., is proposed. The PX reactivity in DR has been generally related to the reaction of PX with hypoiodous acid (HIO) present in the matrix.
PB  - Wiley-VCH Verlag GMBH, Weinheim
T2  - Helvetica Chimica Acta
T1  - Perturbations of the Dushman Reaction with Piroxicam: Experimental and Model Calculations
VL  - 97
IS  - 1
SP  - 47
EP  - 55
DO  - 10.1002/hlca.201300109
ER  - 
@article{
author = "Pejić, Nataša and Blagojević, Slavica and Sarap, Nataša B. and Maksimović, Jelena and Anić, Slobodan and Čupić, Željko and Kolar-Anić, Ljiljana",
year = "2014",
abstract = "Perturbation of the BrayLiebhafsky non-oscillating subsystem (mixture of KIO3 and H2SO4), i.e., Dushman reaction (DR), by piroxicam (PX), was observed in an open reactor, i.e., in the continuously fed well-stirred tank reactor (CSTR). Monitoring the response of DR to perturbations by different concentrations of PX allows developing a simple procedure for quantitative determination of this analyte in both bulk drug and pharmaceutical preparation (injection). A tentative perturbation mechanism of PX action on the DR matrix, based on a kinetic scheme that was suggested by Agreda etal., is proposed. The PX reactivity in DR has been generally related to the reaction of PX with hypoiodous acid (HIO) present in the matrix.",
publisher = "Wiley-VCH Verlag GMBH, Weinheim",
journal = "Helvetica Chimica Acta",
title = "Perturbations of the Dushman Reaction with Piroxicam: Experimental and Model Calculations",
volume = "97",
number = "1",
pages = "47-55",
doi = "10.1002/hlca.201300109"
}
Pejić, N., Blagojević, S., Sarap, N. B., Maksimović, J., Anić, S., Čupić, Ž.,& Kolar-Anić, L.. (2014). Perturbations of the Dushman Reaction with Piroxicam: Experimental and Model Calculations. in Helvetica Chimica Acta
Wiley-VCH Verlag GMBH, Weinheim., 97(1), 47-55.
https://doi.org/10.1002/hlca.201300109
Pejić N, Blagojević S, Sarap NB, Maksimović J, Anić S, Čupić Ž, Kolar-Anić L. Perturbations of the Dushman Reaction with Piroxicam: Experimental and Model Calculations. in Helvetica Chimica Acta. 2014;97(1):47-55.
doi:10.1002/hlca.201300109 .
Pejić, Nataša, Blagojević, Slavica, Sarap, Nataša B., Maksimović, Jelena, Anić, Slobodan, Čupić, Željko, Kolar-Anić, Ljiljana, "Perturbations of the Dushman Reaction with Piroxicam: Experimental and Model Calculations" in Helvetica Chimica Acta, 97, no. 1 (2014):47-55,
https://doi.org/10.1002/hlca.201300109 . .
2
2
2

Pulse perturbation technique for determination of piroxicam in pharmaceuticals using an oscillatory reaction system

Pejić, Nataša; Sarap, Nataša B.; Maksimović, Jelena; Anić, Slobodan; Kolar-Anić, Ljiljana

(Versita, Warsaw, 2013)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Sarap, Nataša B.
AU  - Maksimović, Jelena
AU  - Anić, Slobodan
AU  - Kolar-Anić, Ljiljana
PY  - 2013
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1940
AB  - A simple and reliable novel kinetic method for the determination of piroxicam (PX) was proposed and validated. For quantitative determination of PX, the Bray-Liebhafsky (BL) oscillatory reaction was used in a stable non-equilibrium stationary state close to the bifurcation point. Under the optimized reaction conditions (T = 55.0A degrees C, [H2SO4](0) = 7.60x10(-2) mol L-1, [KIO3](0) = 5.90x10(-2) mol L-1, [H2O2](0) = 1.50x10(-1) mol L-1 and j (0) = 2.95x10(-2) min(-1)), the linear relationship between maximal potential shift Delta E (m) , and PX concentration was obtained in the concentration range 11.2-480.5 A mu g mL(-1) with a detection limit of 9.9 A mu g mL(-1). The method had a rather good sample throughput of 25 samples h(-1) with a precision RSD = 4.7% as well as recoveries RCV a parts per thousand currency sign 104.4%. Applicability of the proposed method to the direct determination of piroxicam in different pharmaceutical formulations (tablets, ampoules and gel) was demonstrated.
PB  - Versita, Warsaw
T2  - Central European Journal of Chemistry
T1  - Pulse perturbation technique for determination of piroxicam in pharmaceuticals using an oscillatory reaction system
VL  - 11
IS  - 2
SP  - 180
EP  - 188
DO  - 10.2478/s11532-012-0146-7
ER  - 
@article{
author = "Pejić, Nataša and Sarap, Nataša B. and Maksimović, Jelena and Anić, Slobodan and Kolar-Anić, Ljiljana",
year = "2013",
abstract = "A simple and reliable novel kinetic method for the determination of piroxicam (PX) was proposed and validated. For quantitative determination of PX, the Bray-Liebhafsky (BL) oscillatory reaction was used in a stable non-equilibrium stationary state close to the bifurcation point. Under the optimized reaction conditions (T = 55.0A degrees C, [H2SO4](0) = 7.60x10(-2) mol L-1, [KIO3](0) = 5.90x10(-2) mol L-1, [H2O2](0) = 1.50x10(-1) mol L-1 and j (0) = 2.95x10(-2) min(-1)), the linear relationship between maximal potential shift Delta E (m) , and PX concentration was obtained in the concentration range 11.2-480.5 A mu g mL(-1) with a detection limit of 9.9 A mu g mL(-1). The method had a rather good sample throughput of 25 samples h(-1) with a precision RSD = 4.7% as well as recoveries RCV a parts per thousand currency sign 104.4%. Applicability of the proposed method to the direct determination of piroxicam in different pharmaceutical formulations (tablets, ampoules and gel) was demonstrated.",
publisher = "Versita, Warsaw",
journal = "Central European Journal of Chemistry",
title = "Pulse perturbation technique for determination of piroxicam in pharmaceuticals using an oscillatory reaction system",
volume = "11",
number = "2",
pages = "180-188",
doi = "10.2478/s11532-012-0146-7"
}
Pejić, N., Sarap, N. B., Maksimović, J., Anić, S.,& Kolar-Anić, L.. (2013). Pulse perturbation technique for determination of piroxicam in pharmaceuticals using an oscillatory reaction system. in Central European Journal of Chemistry
Versita, Warsaw., 11(2), 180-188.
https://doi.org/10.2478/s11532-012-0146-7
Pejić N, Sarap NB, Maksimović J, Anić S, Kolar-Anić L. Pulse perturbation technique for determination of piroxicam in pharmaceuticals using an oscillatory reaction system. in Central European Journal of Chemistry. 2013;11(2):180-188.
doi:10.2478/s11532-012-0146-7 .
Pejić, Nataša, Sarap, Nataša B., Maksimović, Jelena, Anić, Slobodan, Kolar-Anić, Ljiljana, "Pulse perturbation technique for determination of piroxicam in pharmaceuticals using an oscillatory reaction system" in Central European Journal of Chemistry, 11, no. 2 (2013):180-188,
https://doi.org/10.2478/s11532-012-0146-7 . .
5
8
8

Kinetic Analytical Method for Determination of Uric Acid in Human Urine using Analyte Pulse Perturbation Technique

Pejić, Nataša; Maksimović, Jelena; Blagojević, Slavica; Anić, Slobodan; Čupić, Željko; Kolar-Anić, Ljiljana

(Soc Brasileira Quimica, Sao Paulo, 2012)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Maksimović, Jelena
AU  - Blagojević, Slavica
AU  - Anić, Slobodan
AU  - Čupić, Željko
AU  - Kolar-Anić, Ljiljana
PY  - 2012
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1655
AB  - Simple and reliable novel methods for the determination of uric acid (UA) are proposed and validated. For quantitative determination of UA, two matrices were used: the Bray-Liebhafsky (BL) oscillatory reaction in a stable non-equilibrium stationary state close to the bifurcation point (method A) as well as, the BL non-oscillating subsystem (mixture KIO3 and H2SO4), i.e., Dushman reaction (DR) in a steady state (method B). The proposed methods are optimized in a continuously fed well stirred tank reactor (CSTR) and applied with excellent results in the determination of UA in human urine samples. The linear relationship between maximal potential shift Delta E-m, and both the logarithm of the UA concentration (procedure A) and UA concentration (procedure B) is obtained in the concentration range 2.98 x 10(-5)-2.68 x 10(-4) mol L-1 and 2.98 x 10(-5)-3.58 x 10(-4) mol L-1, respectively. The methods have an excellent sample throughput of 30 samples h(-1) (method A) and 7 samples h(-1) (method B) with the sensitivity determined to be 1.1 x 10(-5) mol L-1 (method A) and 8.9 x 10(-6) mol L-1 (method B) as well as the precision RSD  lt = 3.4% for both methods. Some aspects of the possible mechanism of UA action on the BL oscillating and Duschman non-oscillating reaction systems are discussed in detail.
PB  - Soc Brasileira Quimica, Sao Paulo
T2  - Journal of the Brazilian Chemical Society
T1  - Kinetic Analytical Method for Determination of Uric Acid in Human Urine using Analyte Pulse Perturbation Technique
VL  - 23
IS  - 8
SP  - 1450
EP  - 1459
UR  - https://hdl.handle.net/21.15107/rcub_farfar_1655
ER  - 
@article{
author = "Pejić, Nataša and Maksimović, Jelena and Blagojević, Slavica and Anić, Slobodan and Čupić, Željko and Kolar-Anić, Ljiljana",
year = "2012",
abstract = "Simple and reliable novel methods for the determination of uric acid (UA) are proposed and validated. For quantitative determination of UA, two matrices were used: the Bray-Liebhafsky (BL) oscillatory reaction in a stable non-equilibrium stationary state close to the bifurcation point (method A) as well as, the BL non-oscillating subsystem (mixture KIO3 and H2SO4), i.e., Dushman reaction (DR) in a steady state (method B). The proposed methods are optimized in a continuously fed well stirred tank reactor (CSTR) and applied with excellent results in the determination of UA in human urine samples. The linear relationship between maximal potential shift Delta E-m, and both the logarithm of the UA concentration (procedure A) and UA concentration (procedure B) is obtained in the concentration range 2.98 x 10(-5)-2.68 x 10(-4) mol L-1 and 2.98 x 10(-5)-3.58 x 10(-4) mol L-1, respectively. The methods have an excellent sample throughput of 30 samples h(-1) (method A) and 7 samples h(-1) (method B) with the sensitivity determined to be 1.1 x 10(-5) mol L-1 (method A) and 8.9 x 10(-6) mol L-1 (method B) as well as the precision RSD  lt = 3.4% for both methods. Some aspects of the possible mechanism of UA action on the BL oscillating and Duschman non-oscillating reaction systems are discussed in detail.",
publisher = "Soc Brasileira Quimica, Sao Paulo",
journal = "Journal of the Brazilian Chemical Society",
title = "Kinetic Analytical Method for Determination of Uric Acid in Human Urine using Analyte Pulse Perturbation Technique",
volume = "23",
number = "8",
pages = "1450-1459",
url = "https://hdl.handle.net/21.15107/rcub_farfar_1655"
}
Pejić, N., Maksimović, J., Blagojević, S., Anić, S., Čupić, Ž.,& Kolar-Anić, L.. (2012). Kinetic Analytical Method for Determination of Uric Acid in Human Urine using Analyte Pulse Perturbation Technique. in Journal of the Brazilian Chemical Society
Soc Brasileira Quimica, Sao Paulo., 23(8), 1450-1459.
https://hdl.handle.net/21.15107/rcub_farfar_1655
Pejić N, Maksimović J, Blagojević S, Anić S, Čupić Ž, Kolar-Anić L. Kinetic Analytical Method for Determination of Uric Acid in Human Urine using Analyte Pulse Perturbation Technique. in Journal of the Brazilian Chemical Society. 2012;23(8):1450-1459.
https://hdl.handle.net/21.15107/rcub_farfar_1655 .
Pejić, Nataša, Maksimović, Jelena, Blagojević, Slavica, Anić, Slobodan, Čupić, Željko, Kolar-Anić, Ljiljana, "Kinetic Analytical Method for Determination of Uric Acid in Human Urine using Analyte Pulse Perturbation Technique" in Journal of the Brazilian Chemical Society, 23, no. 8 (2012):1450-1459,
https://hdl.handle.net/21.15107/rcub_farfar_1655 .
8
9

Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst

Maksimović, Jelena; Čupić, Željko; Lončarević, D.; Pejić, Nataša; Vasiljević-Radović, D.; Anić, Slobodan

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2011)

TY  - JOUR
AU  - Maksimović, Jelena
AU  - Čupić, Željko
AU  - Lončarević, D.
AU  - Pejić, Nataša
AU  - Vasiljević-Radović, D.
AU  - Anić, Slobodan
PY  - 2011
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1575
AB  - The Bray-Liebhafsky (BL) oscillatory reaction generated in the batch reactor at 62- 68 oC was perturbed by cobalt(II)-nitrate, supported on the macroreticular copolymer of poly-4-vinylpyridine with divinylbenzene (Co-PVPDVB). The kinetic data was analyzed of the complex pathways of the hydrogen peroxide decomposition in the examined BL reaction. The obtained results confirm that the kinetics of the BL reaction in the presence Co-PVPDVB comes partially from the Co-catalyst and partially from the macroreticular copolymer support.
AB  - Oscilatorna reakcija Bray-Liebhafsky (BL) realizovana u zatvorenom reaktoru na temperaturi 62-68 oC je perturbovana sa kobalt(II)nitratom ugrađenim na makroretikularnom kopolimeru poli-4-vinilpiridina sa divinilbenzenom (Co- PVPDVB). Analizirani su kinetički podaci kompleksnih reakcionih puteva razlaganja vodonikperoksida u ispitivanoj BL reakciji. Dobijeni rezultati potvrđuju da je u prisustvu Co-PVPDVB kinetika BL reakcije delimično određena Co-katalizatorom, a delimično makromolekularnim kopolimernim nosačem katalizatora.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst
VL  - 43
IS  - 1
SP  - 55
EP  - 62
DO  - 10.2298/SOS1101055M
ER  - 
@article{
author = "Maksimović, Jelena and Čupić, Željko and Lončarević, D. and Pejić, Nataša and Vasiljević-Radović, D. and Anić, Slobodan",
year = "2011",
abstract = "The Bray-Liebhafsky (BL) oscillatory reaction generated in the batch reactor at 62- 68 oC was perturbed by cobalt(II)-nitrate, supported on the macroreticular copolymer of poly-4-vinylpyridine with divinylbenzene (Co-PVPDVB). The kinetic data was analyzed of the complex pathways of the hydrogen peroxide decomposition in the examined BL reaction. The obtained results confirm that the kinetics of the BL reaction in the presence Co-PVPDVB comes partially from the Co-catalyst and partially from the macroreticular copolymer support., Oscilatorna reakcija Bray-Liebhafsky (BL) realizovana u zatvorenom reaktoru na temperaturi 62-68 oC je perturbovana sa kobalt(II)nitratom ugrađenim na makroretikularnom kopolimeru poli-4-vinilpiridina sa divinilbenzenom (Co- PVPDVB). Analizirani su kinetički podaci kompleksnih reakcionih puteva razlaganja vodonikperoksida u ispitivanoj BL reakciji. Dobijeni rezultati potvrđuju da je u prisustvu Co-PVPDVB kinetika BL reakcije delimično određena Co-katalizatorom, a delimično makromolekularnim kopolimernim nosačem katalizatora.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst",
volume = "43",
number = "1",
pages = "55-62",
doi = "10.2298/SOS1101055M"
}
Maksimović, J., Čupić, Ž., Lončarević, D., Pejić, N., Vasiljević-Radović, D.,& Anić, S.. (2011). Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 43(1), 55-62.
https://doi.org/10.2298/SOS1101055M
Maksimović J, Čupić Ž, Lončarević D, Pejić N, Vasiljević-Radović D, Anić S. Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst. in Science of Sintering. 2011;43(1):55-62.
doi:10.2298/SOS1101055M .
Maksimović, Jelena, Čupić, Željko, Lončarević, D., Pejić, Nataša, Vasiljević-Radović, D., Anić, Slobodan, "Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst" in Science of Sintering, 43, no. 1 (2011):55-62,
https://doi.org/10.2298/SOS1101055M . .
4
6
6

Quantitative Determination of Some Water-Soluble B Vitamins by Kinetic Analytical Method Based on the Perturbation of an Oscillatory Reaction

Maksimović, Jelena; Kolar-Anić, Ljiljana; Anić, Slobodan; Ribić, Dragana D.; Pejić, Nataša

(Soc Brasileira Quimica, Sao Paulo, 2011)

TY  - JOUR
AU  - Maksimović, Jelena
AU  - Kolar-Anić, Ljiljana
AU  - Anić, Slobodan
AU  - Ribić, Dragana D.
AU  - Pejić, Nataša
PY  - 2011
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1536
AB  - A novel procedure for kinetic determination of some water-soluble vitamins of the B-group (thiamine (B-1), riboflavin (B-2), niacin (B-3) and pyridoxine (B-6)) by the concentration perturbations of the Bray-Liebhafsky (BL) oscillatory chemical system involving the catalytic decomposition of hydrogen peroxide in the presence of both hydrogen and iodate ions is proposed and validated. The method uses a Pt electrode for potentiometric monitoring of the concentration perturbations of the BL matrix in a stable non-equilibrium stationary state close to the bifurcation point. The proposed method relies on the linear relationship between maximal potential displacements, Delta E-m, caused by the additional known quantities of a B species. Under the optimal established analytical conditions, linear calibration curves were obtained over the range of 0.01-1.0, 0.016-0.128, 5.0-50.0 and 0.05-2.5 mu mol with the limits of detection of 0.01, 0.018, 2.6 and 0.03 mu mol, as well as analytical throughput of 30, 5, 12 and 20 determinations per hour, for B-1, B-2, B-3 and B-6, respectively. The used technical approach also provides simple, effective and convenient method to assay the pharmaceutical formulations containing B-1 together with other active principles such as nicotinamide and vitamin B-12 as well as B-3.
PB  - Soc Brasileira Quimica, Sao Paulo
T2  - Journal of the Brazilian Chemical Society
T1  - Quantitative Determination of Some Water-Soluble B Vitamins by Kinetic Analytical Method Based on the Perturbation of an Oscillatory Reaction
VL  - 22
IS  - 1
SP  - 38
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_farfar_1536
ER  - 
@article{
author = "Maksimović, Jelena and Kolar-Anić, Ljiljana and Anić, Slobodan and Ribić, Dragana D. and Pejić, Nataša",
year = "2011",
abstract = "A novel procedure for kinetic determination of some water-soluble vitamins of the B-group (thiamine (B-1), riboflavin (B-2), niacin (B-3) and pyridoxine (B-6)) by the concentration perturbations of the Bray-Liebhafsky (BL) oscillatory chemical system involving the catalytic decomposition of hydrogen peroxide in the presence of both hydrogen and iodate ions is proposed and validated. The method uses a Pt electrode for potentiometric monitoring of the concentration perturbations of the BL matrix in a stable non-equilibrium stationary state close to the bifurcation point. The proposed method relies on the linear relationship between maximal potential displacements, Delta E-m, caused by the additional known quantities of a B species. Under the optimal established analytical conditions, linear calibration curves were obtained over the range of 0.01-1.0, 0.016-0.128, 5.0-50.0 and 0.05-2.5 mu mol with the limits of detection of 0.01, 0.018, 2.6 and 0.03 mu mol, as well as analytical throughput of 30, 5, 12 and 20 determinations per hour, for B-1, B-2, B-3 and B-6, respectively. The used technical approach also provides simple, effective and convenient method to assay the pharmaceutical formulations containing B-1 together with other active principles such as nicotinamide and vitamin B-12 as well as B-3.",
publisher = "Soc Brasileira Quimica, Sao Paulo",
journal = "Journal of the Brazilian Chemical Society",
title = "Quantitative Determination of Some Water-Soluble B Vitamins by Kinetic Analytical Method Based on the Perturbation of an Oscillatory Reaction",
volume = "22",
number = "1",
pages = "38-48",
url = "https://hdl.handle.net/21.15107/rcub_farfar_1536"
}
Maksimović, J., Kolar-Anić, L., Anić, S., Ribić, D. D.,& Pejić, N.. (2011). Quantitative Determination of Some Water-Soluble B Vitamins by Kinetic Analytical Method Based on the Perturbation of an Oscillatory Reaction. in Journal of the Brazilian Chemical Society
Soc Brasileira Quimica, Sao Paulo., 22(1), 38-48.
https://hdl.handle.net/21.15107/rcub_farfar_1536
Maksimović J, Kolar-Anić L, Anić S, Ribić DD, Pejić N. Quantitative Determination of Some Water-Soluble B Vitamins by Kinetic Analytical Method Based on the Perturbation of an Oscillatory Reaction. in Journal of the Brazilian Chemical Society. 2011;22(1):38-48.
https://hdl.handle.net/21.15107/rcub_farfar_1536 .
Maksimović, Jelena, Kolar-Anić, Ljiljana, Anić, Slobodan, Ribić, Dragana D., Pejić, Nataša, "Quantitative Determination of Some Water-Soluble B Vitamins by Kinetic Analytical Method Based on the Perturbation of an Oscillatory Reaction" in Journal of the Brazilian Chemical Society, 22, no. 1 (2011):38-48,
https://hdl.handle.net/21.15107/rcub_farfar_1536 .
12
16

Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature

Pejić, Nataša; Vujković, Milica; Maksimović, Jelena; Ivanović, A.; Anić, Slobodan; Čupić, Željko; Kolar-Anić, Ljiljana

(Maik Nauka/Interperiodica/Springer, New York, 2011)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Vujković, Milica
AU  - Maksimović, Jelena
AU  - Ivanović, A.
AU  - Anić, Slobodan
AU  - Čupić, Željko
AU  - Kolar-Anić, Ljiljana
PY  - 2011
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1516
AB  - The non-periodic, periodic and chaotic regimes in the Bray-Liebhafsky (BL) oscillatory reaction observed in a continuously fed well stirred tank reactor (CSTR) under isothermal conditions at various inflow concentrations of the sulfuric acid were experimentally studied. In each series (at any fixed temperature), termination of oscillatory behavior via saddle loop infinite period bifurcation (SNIPER) as well as some kind of the Andronov-Hopf bifurcation is presented. In addition, it was found that an increase of temperature, in different series of experiments resulted in the shift of bifurcation point towards higher values of sulfuric acid concentration.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - SAR and QSAR in Environmental Research
T1  - Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature
VL  - 85
IS  - 13
SP  - 2310
EP  - 2316
DO  - 10.1134/S0036024411130231
ER  - 
@article{
author = "Pejić, Nataša and Vujković, Milica and Maksimović, Jelena and Ivanović, A. and Anić, Slobodan and Čupić, Željko and Kolar-Anić, Ljiljana",
year = "2011",
abstract = "The non-periodic, periodic and chaotic regimes in the Bray-Liebhafsky (BL) oscillatory reaction observed in a continuously fed well stirred tank reactor (CSTR) under isothermal conditions at various inflow concentrations of the sulfuric acid were experimentally studied. In each series (at any fixed temperature), termination of oscillatory behavior via saddle loop infinite period bifurcation (SNIPER) as well as some kind of the Andronov-Hopf bifurcation is presented. In addition, it was found that an increase of temperature, in different series of experiments resulted in the shift of bifurcation point towards higher values of sulfuric acid concentration.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "SAR and QSAR in Environmental Research",
title = "Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature",
volume = "85",
number = "13",
pages = "2310-2316",
doi = "10.1134/S0036024411130231"
}
Pejić, N., Vujković, M., Maksimović, J., Ivanović, A., Anić, S., Čupić, Ž.,& Kolar-Anić, L.. (2011). Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature. in SAR and QSAR in Environmental Research
Maik Nauka/Interperiodica/Springer, New York., 85(13), 2310-2316.
https://doi.org/10.1134/S0036024411130231
Pejić N, Vujković M, Maksimović J, Ivanović A, Anić S, Čupić Ž, Kolar-Anić L. Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature. in SAR and QSAR in Environmental Research. 2011;85(13):2310-2316.
doi:10.1134/S0036024411130231 .
Pejić, Nataša, Vujković, Milica, Maksimović, Jelena, Ivanović, A., Anić, Slobodan, Čupić, Željko, Kolar-Anić, Ljiljana, "Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature" in SAR and QSAR in Environmental Research, 85, no. 13 (2011):2310-2316,
https://doi.org/10.1134/S0036024411130231 . .
9
10
12

Dynamic states of the Bray-Liebhafsky reaction when sulfuric acid is the control parameter

Pejić, Nataša; Maksimović, Jelena; Ribić, Dragana D.; Kolar-Anić, Ljiljana

(Maik Nauka/Interperiodica/Springer, New York, 2009)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Maksimović, Jelena
AU  - Ribić, Dragana D.
AU  - Kolar-Anić, Ljiljana
PY  - 2009
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1259
AB  - Dynamic behavior of hydrogen peroxide decomposition catalyzed by iodate and hydrogen ions (the Bray-Liebhafsky reaction), in a continuous stirred tank reactor is investigated. The experimental results are obtained at one operational point in concentration phase space by varying mixed inflow concentrations of the sulfuric acid. The experimental evidences for the onset and termination of oscillatory behavior via the saddle node infinite period bifurcation as well as some kind of the Andronov-Hopf bifurcation are presented. In addition, the possibility of excitability of a stable steady state by thiamine was observed.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - SAR and QSAR in Environmental Research
T1  - Dynamic states of the Bray-Liebhafsky reaction when sulfuric acid is the control parameter
VL  - 83
IS  - 9
SP  - 1490
EP  - 1495
DO  - 10.1134/S0036024409090131
ER  - 
@article{
author = "Pejić, Nataša and Maksimović, Jelena and Ribić, Dragana D. and Kolar-Anić, Ljiljana",
year = "2009",
abstract = "Dynamic behavior of hydrogen peroxide decomposition catalyzed by iodate and hydrogen ions (the Bray-Liebhafsky reaction), in a continuous stirred tank reactor is investigated. The experimental results are obtained at one operational point in concentration phase space by varying mixed inflow concentrations of the sulfuric acid. The experimental evidences for the onset and termination of oscillatory behavior via the saddle node infinite period bifurcation as well as some kind of the Andronov-Hopf bifurcation are presented. In addition, the possibility of excitability of a stable steady state by thiamine was observed.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "SAR and QSAR in Environmental Research",
title = "Dynamic states of the Bray-Liebhafsky reaction when sulfuric acid is the control parameter",
volume = "83",
number = "9",
pages = "1490-1495",
doi = "10.1134/S0036024409090131"
}
Pejić, N., Maksimović, J., Ribić, D. D.,& Kolar-Anić, L.. (2009). Dynamic states of the Bray-Liebhafsky reaction when sulfuric acid is the control parameter. in SAR and QSAR in Environmental Research
Maik Nauka/Interperiodica/Springer, New York., 83(9), 1490-1495.
https://doi.org/10.1134/S0036024409090131
Pejić N, Maksimović J, Ribić DD, Kolar-Anić L. Dynamic states of the Bray-Liebhafsky reaction when sulfuric acid is the control parameter. in SAR and QSAR in Environmental Research. 2009;83(9):1490-1495.
doi:10.1134/S0036024409090131 .
Pejić, Nataša, Maksimović, Jelena, Ribić, Dragana D., Kolar-Anić, Ljiljana, "Dynamic states of the Bray-Liebhafsky reaction when sulfuric acid is the control parameter" in SAR and QSAR in Environmental Research, 83, no. 9 (2009):1490-1495,
https://doi.org/10.1134/S0036024409090131 . .
11
17
14

Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator

Anić, Slobodan; Maksimović, Jelena; Loncarević, D.; Pejić, Nataša; Čupić, Željko

(Maik Nauka/Interperiodica/Springer, New York, 2009)

TY  - JOUR
AU  - Anić, Slobodan
AU  - Maksimović, Jelena
AU  - Loncarević, D.
AU  - Pejić, Nataša
AU  - Čupić, Željko
PY  - 2009
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1258
AB  - The infuence of poly-4-vinylpyridine-co-divinylbenzene-Co2+ catalyst on the Bray-Liebhafsky (BL) oscillator used as the matrix for establishing catalyst's activity was analyzed. The addition of the catalyst do not change the dynamics of the reaction in the BL matrix, but the periods of the oscillatory evolution as well as the preoscillatory period (tau(1)) and the duration from the beginning of the reaction to the end of the oscillatory state (tau(end)). All experimental results are simulated satisfactory.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - SAR and QSAR in Environmental Research
T1  - Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator
VL  - 83
IS  - 9
SP  - 1468
EP  - 1472
DO  - 10.1134/S003602440909009X
ER  - 
@article{
author = "Anić, Slobodan and Maksimović, Jelena and Loncarević, D. and Pejić, Nataša and Čupić, Željko",
year = "2009",
abstract = "The infuence of poly-4-vinylpyridine-co-divinylbenzene-Co2+ catalyst on the Bray-Liebhafsky (BL) oscillator used as the matrix for establishing catalyst's activity was analyzed. The addition of the catalyst do not change the dynamics of the reaction in the BL matrix, but the periods of the oscillatory evolution as well as the preoscillatory period (tau(1)) and the duration from the beginning of the reaction to the end of the oscillatory state (tau(end)). All experimental results are simulated satisfactory.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "SAR and QSAR in Environmental Research",
title = "Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator",
volume = "83",
number = "9",
pages = "1468-1472",
doi = "10.1134/S003602440909009X"
}
Anić, S., Maksimović, J., Loncarević, D., Pejić, N.,& Čupić, Ž.. (2009). Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator. in SAR and QSAR in Environmental Research
Maik Nauka/Interperiodica/Springer, New York., 83(9), 1468-1472.
https://doi.org/10.1134/S003602440909009X
Anić S, Maksimović J, Loncarević D, Pejić N, Čupić Ž. Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator. in SAR and QSAR in Environmental Research. 2009;83(9):1468-1472.
doi:10.1134/S003602440909009X .
Anić, Slobodan, Maksimović, Jelena, Loncarević, D., Pejić, Nataša, Čupić, Željko, "Activity of polymer supported cobalt catalyst in the Bray-Liebhafsky oscillator" in SAR and QSAR in Environmental Research, 83, no. 9 (2009):1468-1472,
https://doi.org/10.1134/S003602440909009X . .
7
8
10