TY  - JOUR
AU  - Janošević, Aleksandra
AU  - Marjanović, Budimir
AU  - Rakić, Aleksandra
AU  - Ćirić-Marjanović, Gordana
PY  - 2013
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2035
AB  - Recent advances in synthesis, characterization and application of the selected conducting/semiconducting and redox-active oligomers and polymers of arylamines are reviewed. A brief historical background of the selected topics is given. The overview of the preparation, structure and properties of polyaniline, substituted polyanilines, especially those obtained by the oxidative polymerization of p-substituted anilines, poly(1-aminonaphthalene) and its derivatives, carbocyclic and heterocyclic polyaryldiamines such as poly(p-phenylenediamine) and polydiaminoacridines, is presented. The mechanism of formation of polyaniline nanostructures is discussed. Recent approaches to the preparation of one-dimensional polyaniline nanostructures are concisely reviewed, with special attention paid to the template-free falling-pH method. Current and potential future applications of oligo/polyarylamines are briefly discussed.
AB  - U ovom revijalnom radu prikazan je napredak ostvaren u poslednjih nekoliko godina u sintezi, karakterizaciji i primeni nekih provodnih/poluprovodnih i redoks-aktivnih oligomera i polimera arilamina. Dat je kratak prikaz istorijskog razvoja pojedinih oblasti. Predstavljeni su postupci sinteze, struktura i svojstva polianilina, supstituisanih polianilina, posebno onih dobijenih oksidativnom polimerizacijom para-supstituisanih anilina, poli(1-aminonaftalena) i njegovih derivata, karbocikličnih i heterocikličnih poliarildiamina, kao npr. poli(para-fenilendiamina) i polidiaminoakridina. Diskutovan je mehanizam formiranja nanostruktura polianilina. Nedavno razvijeni sintetički postupci za dobijanje jednodimenzionalnih nanostruktura polianilina su koncizno prikazani, a posebna pažnja posvećena je metodama bez templata. Prikazan je i kratak pregled aktuelnih i potencijalnih budućih primena oligo/poliarilamina.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Progress in conducting/semiconducting and redox-active oligomers and polymers of arylamines
T1  - Napredak u istraživanjima provodnih/poluprovodnih i redoks aktivnih oligomera i polimera arilamina
VL  - 78
IS  - 11
SP  - 1809
EP  - 1836
DO  - 10.2298/JSC130809097J
ER  - 

@article{
author = "Janošević, Aleksandra and Marjanović, Budimir and Rakić, Aleksandra and Ćirić-Marjanović, Gordana",
year = "2013",
abstract = "Recent advances in synthesis, characterization and application of the selected conducting/semiconducting and redox-active oligomers and polymers of arylamines are reviewed. A brief historical background of the selected topics is given. The overview of the preparation, structure and properties of polyaniline, substituted polyanilines, especially those obtained by the oxidative polymerization of p-substituted anilines, poly(1-aminonaphthalene) and its derivatives, carbocyclic and heterocyclic polyaryldiamines such as poly(p-phenylenediamine) and polydiaminoacridines, is presented. The mechanism of formation of polyaniline nanostructures is discussed. Recent approaches to the preparation of one-dimensional polyaniline nanostructures are concisely reviewed, with special attention paid to the template-free falling-pH method. Current and potential future applications of oligo/polyarylamines are briefly discussed., U ovom revijalnom radu prikazan je napredak ostvaren u poslednjih nekoliko godina u sintezi, karakterizaciji i primeni nekih provodnih/poluprovodnih i redoks-aktivnih oligomera i polimera arilamina. Dat je kratak prikaz istorijskog razvoja pojedinih oblasti. Predstavljeni su postupci sinteze, struktura i svojstva polianilina, supstituisanih polianilina, posebno onih dobijenih oksidativnom polimerizacijom para-supstituisanih anilina, poli(1-aminonaftalena) i njegovih derivata, karbocikličnih i heterocikličnih poliarildiamina, kao npr. poli(para-fenilendiamina) i polidiaminoakridina. Diskutovan je mehanizam formiranja nanostruktura polianilina. Nedavno razvijeni sintetički postupci za dobijanje jednodimenzionalnih nanostruktura polianilina su koncizno prikazani, a posebna pažnja posvećena je metodama bez templata. Prikazan je i kratak pregled aktuelnih i potencijalnih budućih primena oligo/poliarilamina.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Progress in conducting/semiconducting and redox-active oligomers and polymers of arylamines, Napredak u istraživanjima provodnih/poluprovodnih i redoks aktivnih oligomera i polimera arilamina",
volume = "78",
number = "11",
pages = "1809-1836",
doi = "10.2298/JSC130809097J"
}

Janošević, A., Marjanović, B., Rakić, A.,& Ćirić-Marjanović, G.. (2013). Progress in conducting/semiconducting and redox-active oligomers and polymers of arylamines. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 78(11), 1809-1836.
https://doi.org/10.2298/JSC130809097J

Janošević A, Marjanović B, Rakić A, Ćirić-Marjanović G. Progress in conducting/semiconducting and redox-active oligomers and polymers of arylamines. in Journal of the Serbian Chemical Society. 2013;78(11):1809-1836.
doi:10.2298/JSC130809097J .

Janošević, Aleksandra, Marjanović, Budimir, Rakić, Aleksandra, Ćirić-Marjanović, Gordana, "Progress in conducting/semiconducting and redox-active oligomers and polymers of arylamines" in Journal of the Serbian Chemical Society, 78, no. 11 (2013):1809-1836,
https://doi.org/10.2298/JSC130809097J . .

TY  - JOUR
AU  - Marjanović, Budimir
AU  - Juranić, Ivan O.
AU  - Ćirić-Marjanović, Gordana
AU  - Mojović, M
AU  - Pasti, Igor
AU  - Janošević, Aleksandra
AU  - Trchova, Miroslava
AU  - Holler, P
AU  - Horský, J
PY  - 2012
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1806
AB  - Novel electroactive paramagnetic ethacridine oligomers were synthesized by the oxidation of ethacridine lactate with ammonium peroxydisulfate in acidic aqueous solution. The oxidative coupling of ethacridine was proved by gel permeation chromatography and MALDI-TOF mass spectrometry demonstrating the presence of oligomeric chains. Theoretical study of the mechanism of oxidation of ethacridine has been based on the semi-empirical quantum chemical computations of heat of formation and ionization energy of ethacridine, protonated ethacridine, generated reactive species and reaction intermediates, taking into account influence of pH and solvation effects. It was revealed that the prevalent ethacridine dimers are N(C6)C5 coupled. The influence of oxidant to monomer mole ratio on the molecular structure and the morphology of ethacridine oligomers has been studied by elemental analysis, FTIR, Raman, EPR and UV-Visible spectroscopies, MALDI-TOF mass spectrometry and scanning electron microscopy. Besides unoxidized monomeric units as prevalent, oligoethacridines contain the iminoquinonoid and newly formed fused phenazine units. The electroactivity of ethacridine oligomers was investigated by cyclic voltammetry.
T2  - Reactive and Functional Polymers
T1  - Chemical oxidative polymerization of ethacridine
VL  - 72
IS  - 1
SP  - 25
EP  - 35
DO  - 10.1016/j.reactfunctpolym.2011.10.002
ER  - 

@article{
author = "Marjanović, Budimir and Juranić, Ivan O. and Ćirić-Marjanović, Gordana and Mojović, M and Pasti, Igor and Janošević, Aleksandra and Trchova, Miroslava and Holler, P and Horský, J",
year = "2012",
abstract = "Novel electroactive paramagnetic ethacridine oligomers were synthesized by the oxidation of ethacridine lactate with ammonium peroxydisulfate in acidic aqueous solution. The oxidative coupling of ethacridine was proved by gel permeation chromatography and MALDI-TOF mass spectrometry demonstrating the presence of oligomeric chains. Theoretical study of the mechanism of oxidation of ethacridine has been based on the semi-empirical quantum chemical computations of heat of formation and ionization energy of ethacridine, protonated ethacridine, generated reactive species and reaction intermediates, taking into account influence of pH and solvation effects. It was revealed that the prevalent ethacridine dimers are N(C6)C5 coupled. The influence of oxidant to monomer mole ratio on the molecular structure and the morphology of ethacridine oligomers has been studied by elemental analysis, FTIR, Raman, EPR and UV-Visible spectroscopies, MALDI-TOF mass spectrometry and scanning electron microscopy. Besides unoxidized monomeric units as prevalent, oligoethacridines contain the iminoquinonoid and newly formed fused phenazine units. The electroactivity of ethacridine oligomers was investigated by cyclic voltammetry.",
journal = "Reactive and Functional Polymers",
title = "Chemical oxidative polymerization of ethacridine",
volume = "72",
number = "1",
pages = "25-35",
doi = "10.1016/j.reactfunctpolym.2011.10.002"
}

Marjanović, B., Juranić, I. O., Ćirić-Marjanović, G., Mojović, M., Pasti, I., Janošević, A., Trchova, M., Holler, P.,& Horský, J.. (2012). Chemical oxidative polymerization of ethacridine. in Reactive and Functional Polymers, 72(1), 25-35.
https://doi.org/10.1016/j.reactfunctpolym.2011.10.002

Marjanović B, Juranić IO, Ćirić-Marjanović G, Mojović M, Pasti I, Janošević A, Trchova M, Holler P, Horský J. Chemical oxidative polymerization of ethacridine. in Reactive and Functional Polymers. 2012;72(1):25-35.
doi:10.1016/j.reactfunctpolym.2011.10.002 .

Marjanović, Budimir, Juranić, Ivan O., Ćirić-Marjanović, Gordana, Mojović, M, Pasti, Igor, Janošević, Aleksandra, Trchova, Miroslava, Holler, P, Horský, J, "Chemical oxidative polymerization of ethacridine" in Reactive and Functional Polymers, 72, no. 1 (2012):25-35,
https://doi.org/10.1016/j.reactfunctpolym.2011.10.002 . .

TY  - JOUR
AU  - Janošević, Aleksandra
AU  - Ćirić-Marjanović, Gordana
AU  - Sljukić-Paunković, Biljana
AU  - Pasti, Igor
AU  - Trifunović, Snežana
AU  - Marjanović, Budimir
AU  - Stejskal, Jaroslav
PY  - 2012
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1755
AB  - The oxidation of aniline with ammonium peroxydisulfate (APS) in aqueous solution of the plant-derived polyphenol, tannic acid, is reported. The effect of initial mole ratios [tannic acid]/[aniline] and [APS]/[aniline] on molecular structure, morphology, conductivity, and electroactivity of synthesized materials (PANI-TA) was investigated by UV-Vis, FTIR, Raman and EPR spectroscopies, scanning and transmission electron microscopies (SEM and TEM), conductivity measurements, and cyclic voltammetry, respectively. PANI-TA nanorods with the average diameter of 70-100 nm and conductivity of 1 x 10(-3) S cm(-1) were synthesized at [tannic acid]/[aniline] = 0.01 and [APS]/[aniline] = 1, while nonconductive, solid microspheres were obtained at [tannic acid]/[aniline] = 0.1 and [APS)[aniline] = 2. The mechanism of the early stages of simultaneous oxidation of aniline and tannic acid has been computationally studied by the RM1/COSMO method.
PB  - Elsevier Science Sa, Lausanne
T2  - Synthetic Metals
T1  - Simultaneous oxidation of aniline and tannic acid with peroxydisulfate: Self-assembly of oxidation products from nanorods to microspheres
VL  - 162
IS  - 9-10
SP  - 843
EP  - 856
DO  - 10.1016/j.synthmet.2012.03.009
ER  - 

@article{
author = "Janošević, Aleksandra and Ćirić-Marjanović, Gordana and Sljukić-Paunković, Biljana and Pasti, Igor and Trifunović, Snežana and Marjanović, Budimir and Stejskal, Jaroslav",
year = "2012",
abstract = "The oxidation of aniline with ammonium peroxydisulfate (APS) in aqueous solution of the plant-derived polyphenol, tannic acid, is reported. The effect of initial mole ratios [tannic acid]/[aniline] and [APS]/[aniline] on molecular structure, morphology, conductivity, and electroactivity of synthesized materials (PANI-TA) was investigated by UV-Vis, FTIR, Raman and EPR spectroscopies, scanning and transmission electron microscopies (SEM and TEM), conductivity measurements, and cyclic voltammetry, respectively. PANI-TA nanorods with the average diameter of 70-100 nm and conductivity of 1 x 10(-3) S cm(-1) were synthesized at [tannic acid]/[aniline] = 0.01 and [APS]/[aniline] = 1, while nonconductive, solid microspheres were obtained at [tannic acid]/[aniline] = 0.1 and [APS)[aniline] = 2. The mechanism of the early stages of simultaneous oxidation of aniline and tannic acid has been computationally studied by the RM1/COSMO method.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Synthetic Metals",
title = "Simultaneous oxidation of aniline and tannic acid with peroxydisulfate: Self-assembly of oxidation products from nanorods to microspheres",
volume = "162",
number = "9-10",
pages = "843-856",
doi = "10.1016/j.synthmet.2012.03.009"
}

Janošević, A., Ćirić-Marjanović, G., Sljukić-Paunković, B., Pasti, I., Trifunović, S., Marjanović, B.,& Stejskal, J.. (2012). Simultaneous oxidation of aniline and tannic acid with peroxydisulfate: Self-assembly of oxidation products from nanorods to microspheres. in Synthetic Metals
Elsevier Science Sa, Lausanne., 162(9-10), 843-856.
https://doi.org/10.1016/j.synthmet.2012.03.009

Janošević A, Ćirić-Marjanović G, Sljukić-Paunković B, Pasti I, Trifunović S, Marjanović B, Stejskal J. Simultaneous oxidation of aniline and tannic acid with peroxydisulfate: Self-assembly of oxidation products from nanorods to microspheres. in Synthetic Metals. 2012;162(9-10):843-856.
doi:10.1016/j.synthmet.2012.03.009 .

Janošević, Aleksandra, Ćirić-Marjanović, Gordana, Sljukić-Paunković, Biljana, Pasti, Igor, Trifunović, Snežana, Marjanović, Budimir, Stejskal, Jaroslav, "Simultaneous oxidation of aniline and tannic acid with peroxydisulfate: Self-assembly of oxidation products from nanorods to microspheres" in Synthetic Metals, 162, no. 9-10 (2012):843-856,
https://doi.org/10.1016/j.synthmet.2012.03.009 . .

TY  - JOUR
AU  - Janošević, Aleksandra
AU  - Ćirić-Marjanović, Gordana
AU  - Marjanović, Budimir
AU  - Trchova, Miroslava
AU  - Stejskal, Jaroslav
PY  - 2010
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1361
AB  - Self-assembled polyaniline nanorods were synthesized by the oxidation of aniline with ammonium peroxydisulfate in an aqueous solution in the presence of 3,5-dinitrosalicylic acid, using the template-free falling-pH method. The effects of the mole ratio of 3,5-dinitrosalicylic acid to aniline, i.e., of starting pH, monomer concentration, and reaction time on the yield of polymerization, molecular-weight distribution, molecular structure, morphology, and conductivity of the prepared polyanilines have been studied by gelpermeation chromatography. elemental analysis, FTIR and Raman spectroscopies, scanning and transmission electron microscopies, and conductivity measurements. The weight-average molecular weights and polydispersity index were in the range 36,400-54,900 and 3.7-7.6, respectively. Synthesized polyaniline nanorods have a diameter of 25-280 nm and a length of 0.2-1.31 mu m, and conductivities in the range (1.2-4.6) x 10(-2) S cm(-1). The formation mechanism of self-assembled polyaniline nanorods has been discussed.
PB  - Elsevier Science BV, Amsterdam
T2  - Materials Letters
T1  - 3,5-Dinitrosalicylic acid-assisted synthesis of self-assembled polyaniline nanorods
VL  - 64
IS  - 21
SP  - 2337
EP  - 2340
DO  - 10.1016/j.matlet.2010.07.041
ER  - 

@article{
author = "Janošević, Aleksandra and Ćirić-Marjanović, Gordana and Marjanović, Budimir and Trchova, Miroslava and Stejskal, Jaroslav",
year = "2010",
abstract = "Self-assembled polyaniline nanorods were synthesized by the oxidation of aniline with ammonium peroxydisulfate in an aqueous solution in the presence of 3,5-dinitrosalicylic acid, using the template-free falling-pH method. The effects of the mole ratio of 3,5-dinitrosalicylic acid to aniline, i.e., of starting pH, monomer concentration, and reaction time on the yield of polymerization, molecular-weight distribution, molecular structure, morphology, and conductivity of the prepared polyanilines have been studied by gelpermeation chromatography. elemental analysis, FTIR and Raman spectroscopies, scanning and transmission electron microscopies, and conductivity measurements. The weight-average molecular weights and polydispersity index were in the range 36,400-54,900 and 3.7-7.6, respectively. Synthesized polyaniline nanorods have a diameter of 25-280 nm and a length of 0.2-1.31 mu m, and conductivities in the range (1.2-4.6) x 10(-2) S cm(-1). The formation mechanism of self-assembled polyaniline nanorods has been discussed.",
publisher = "Elsevier Science BV, Amsterdam",
journal = "Materials Letters",
title = "3,5-Dinitrosalicylic acid-assisted synthesis of self-assembled polyaniline nanorods",
volume = "64",
number = "21",
pages = "2337-2340",
doi = "10.1016/j.matlet.2010.07.041"
}

Janošević, A., Ćirić-Marjanović, G., Marjanović, B., Trchova, M.,& Stejskal, J.. (2010). 3,5-Dinitrosalicylic acid-assisted synthesis of self-assembled polyaniline nanorods. in Materials Letters
Elsevier Science BV, Amsterdam., 64(21), 2337-2340.
https://doi.org/10.1016/j.matlet.2010.07.041

Janošević A, Ćirić-Marjanović G, Marjanović B, Trchova M, Stejskal J. 3,5-Dinitrosalicylic acid-assisted synthesis of self-assembled polyaniline nanorods. in Materials Letters. 2010;64(21):2337-2340.
doi:10.1016/j.matlet.2010.07.041 .

Janošević, Aleksandra, Ćirić-Marjanović, Gordana, Marjanović, Budimir, Trchova, Miroslava, Stejskal, Jaroslav, "3,5-Dinitrosalicylic acid-assisted synthesis of self-assembled polyaniline nanorods" in Materials Letters, 64, no. 21 (2010):2337-2340,
https://doi.org/10.1016/j.matlet.2010.07.041 . .