Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes

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Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (en)
Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (sr)
Nanostrukturni funkcionalni i kompozitni materijali u katalitičkim i sorpcionim procesima (sr_RS)
Authors

Publications

The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents

Troter, Dragan Z.; Todorović, Zoran B.; Đokić-Stojanović, Dušica R.; Đorđević, Biljana S.; Todorović, Vanja; Konstantinović, Sandra S.; Veljković, Vlada B.

(Srpsko hemijsko društvo, Beograd, 2017)

TY  - JOUR
AU  - Troter, Dragan Z.
AU  - Todorović, Zoran B.
AU  - Đokić-Stojanović, Dušica R.
AU  - Đorđević, Biljana S.
AU  - Todorović, Vanja
AU  - Konstantinović, Sandra S.
AU  - Veljković, Vlada B.
PY  - 2017
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2851
AB  - This paper reports the physicochemical (density, dynamic viscosity, electrical conductivity and refractive index) and the thermodynamic (thermal expansion coefficient, molecular volume, lattice energy and heat capacity) properties of several choline chloride (ChCl) based deep eutectic solvents (DESs), with 1:2 mole ratio, respectively:ChCl:propylene glycol, ChCl:1,3-dimethyl-urea and ChCl:thiourea, at atmospheric pressure as a function of temperature over the range of 293.15-363.15 K. Their properties were also compared with those of some already characterized ChCl-based DESs, namely ChCl:ethylene glycol, ChCl:glycerol and ChCl:urea (1:2 mole ratio). Density, viscosity and refractive index of all DESs decrease with the increasing temperature while the electrical conductivity increases. Viscosity and conductivity of the tested DESs were fitted by both Arrhenius-type and Vogel-Tamman-Fulcher equations. The changes of molar enthalpy, entropy and Gibbs energy of activation, determined using the Eyring theory, demonstrated the interactional factor as predominant over the structural factor for all DES systems. The fractional Walden rule, used to correlate molar conductivity and viscosity, showed an excellent linear behaviour. It was shown that ChCl:propylene glycol DES had properties similar to ChCl:ethylene glycol and ChCl:glycerol DESs. However, the properties (density, viscosity and electrical conductivity) of ChCl:1,3-dimethylurea and ChCl::thiourea DESs were inferior to those of the ChCl:urea DES.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents
VL  - 82
IS  - 9
SP  - 1039
EP  - 1052
DO  - 10.2298/JSC170225065T
ER  - 
@article{
author = "Troter, Dragan Z. and Todorović, Zoran B. and Đokić-Stojanović, Dušica R. and Đorđević, Biljana S. and Todorović, Vanja and Konstantinović, Sandra S. and Veljković, Vlada B.",
year = "2017",
abstract = "This paper reports the physicochemical (density, dynamic viscosity, electrical conductivity and refractive index) and the thermodynamic (thermal expansion coefficient, molecular volume, lattice energy and heat capacity) properties of several choline chloride (ChCl) based deep eutectic solvents (DESs), with 1:2 mole ratio, respectively:ChCl:propylene glycol, ChCl:1,3-dimethyl-urea and ChCl:thiourea, at atmospheric pressure as a function of temperature over the range of 293.15-363.15 K. Their properties were also compared with those of some already characterized ChCl-based DESs, namely ChCl:ethylene glycol, ChCl:glycerol and ChCl:urea (1:2 mole ratio). Density, viscosity and refractive index of all DESs decrease with the increasing temperature while the electrical conductivity increases. Viscosity and conductivity of the tested DESs were fitted by both Arrhenius-type and Vogel-Tamman-Fulcher equations. The changes of molar enthalpy, entropy and Gibbs energy of activation, determined using the Eyring theory, demonstrated the interactional factor as predominant over the structural factor for all DES systems. The fractional Walden rule, used to correlate molar conductivity and viscosity, showed an excellent linear behaviour. It was shown that ChCl:propylene glycol DES had properties similar to ChCl:ethylene glycol and ChCl:glycerol DESs. However, the properties (density, viscosity and electrical conductivity) of ChCl:1,3-dimethylurea and ChCl::thiourea DESs were inferior to those of the ChCl:urea DES.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents",
volume = "82",
number = "9",
pages = "1039-1052",
doi = "10.2298/JSC170225065T"
}
Troter, D. Z., Todorović, Z. B., Đokić-Stojanović, D. R., Đorđević, B. S., Todorović, V., Konstantinović, S. S.,& Veljković, V. B.. (2017). The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(9), 1039-1052.
https://doi.org/10.2298/JSC170225065T
Troter DZ, Todorović ZB, Đokić-Stojanović DR, Đorđević BS, Todorović V, Konstantinović SS, Veljković VB. The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents. in Journal of the Serbian Chemical Society. 2017;82(9):1039-1052.
doi:10.2298/JSC170225065T .
Troter, Dragan Z., Todorović, Zoran B., Đokić-Stojanović, Dušica R., Đorđević, Biljana S., Todorović, Vanja, Konstantinović, Sandra S., Veljković, Vlada B., "The physicochemical and thermodynamic properties of the choline chloride-based deep eutectic solvents" in Journal of the Serbian Chemical Society, 82, no. 9 (2017):1039-1052,
https://doi.org/10.2298/JSC170225065T . .
49
37
49

Heterogeneously catalysed ethanolysis of sunflower oil in the presence of propylene glycol, ethyl acetate and diethyl ether as cosolvents

Đokić-Stojanović, Dušica R.; Todorović, Zoran B.; Troter, Dragan Z.; Todorović, Vanja; Đorđević, Biljana S.; Stamenković, Olivera S.; Veljković, Vlada B.

(Univerzitet u Nišu - Tehnološki fakultet, Leskovac, 2016)

TY  - JOUR
AU  - Đokić-Stojanović, Dušica R.
AU  - Todorović, Zoran B.
AU  - Troter, Dragan Z.
AU  - Todorović, Vanja
AU  - Đorđević, Biljana S.
AU  - Stamenković, Olivera S.
AU  - Veljković, Vlada B.
PY  - 2016
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2531
AB  - A heterogeneous reaction process using propylene glycol (PEG), ethyl acetate and diethyl ether as cosolvents for the transesterification of sunflower oil with ethanol in the presence of calcium oxide as a catalyst has been developed. Significant results were obtained with propylene glycol as a cosolvent. Under determined reaction conditions (CaO concentration, based on the oil weight 1.3736 mol∙dm-3; temperature 70°C; and ethanol-to-oil molar ratio 12:1), the conversion of sunflower oil to fatty acid ethyl esters (FAEE) exceeded 98% after 120 min, which was 2 times faster than transesterification of sunflower oil without a cosolvent. After initially enhanced ethanolysis, after 180 min ethyl acetate and diethyl ether negatively influenced the reaction rate and the FAEE yield.
AB  - U radu je opisana heterogena transesterifikacija suncokretovog ulja sa etanolom i kalcijum oksidom kao katalizatorom u prisustvu polietilen glikola (PEG), etil acetata i dietil etra kao kosolvenata. Najpovoljniji rezultati su dobijeni sa polietilen glikolom kao kosolventom gde je, pod određenim reakcionim uslovima (koncentracija CaO, računata u odnosu na masu ulja 1.3736 mol∙dm-3, temperatura 70°C i molarni odnos etanol:ulje 12:1), konverzija suncokretovog ulja u etil estre masnih kiselina (FAEE) dostigla vrednost od 98% nakon 120 minuta, što je 2 puta brže od transesterifikacije suncokretovog ulja bez prisustva kosolventa. Etil acetat i dietil etar poboljšavaju reakciju etanolize na početku, ali, kako reakcija napreduje, posle 180 minuta, njihovo prisustvo u reakcionoj smeši negativno utiče na brzinu reakcije i prinos etil estrara masnih kiselina (FAEE).
PB  - Univerzitet u Nišu - Tehnološki fakultet, Leskovac
T2  - Advanced Technologies
T1  - Heterogeneously catalysed ethanolysis of sunflower oil in the presence of propylene glycol, ethyl acetate and diethyl ether as cosolvents
T1  - Heterogeno katalizovana etanoliza suncokretovog ulja u prisustvu polietilen glikola, etil acetata i dietil etra kao kosolvenata
VL  - 5
IS  - 1
SP  - 66
EP  - 72
DO  - 10.5937/savteh1601066D
ER  - 
@article{
author = "Đokić-Stojanović, Dušica R. and Todorović, Zoran B. and Troter, Dragan Z. and Todorović, Vanja and Đorđević, Biljana S. and Stamenković, Olivera S. and Veljković, Vlada B.",
year = "2016",
abstract = "A heterogeneous reaction process using propylene glycol (PEG), ethyl acetate and diethyl ether as cosolvents for the transesterification of sunflower oil with ethanol in the presence of calcium oxide as a catalyst has been developed. Significant results were obtained with propylene glycol as a cosolvent. Under determined reaction conditions (CaO concentration, based on the oil weight 1.3736 mol∙dm-3; temperature 70°C; and ethanol-to-oil molar ratio 12:1), the conversion of sunflower oil to fatty acid ethyl esters (FAEE) exceeded 98% after 120 min, which was 2 times faster than transesterification of sunflower oil without a cosolvent. After initially enhanced ethanolysis, after 180 min ethyl acetate and diethyl ether negatively influenced the reaction rate and the FAEE yield., U radu je opisana heterogena transesterifikacija suncokretovog ulja sa etanolom i kalcijum oksidom kao katalizatorom u prisustvu polietilen glikola (PEG), etil acetata i dietil etra kao kosolvenata. Najpovoljniji rezultati su dobijeni sa polietilen glikolom kao kosolventom gde je, pod određenim reakcionim uslovima (koncentracija CaO, računata u odnosu na masu ulja 1.3736 mol∙dm-3, temperatura 70°C i molarni odnos etanol:ulje 12:1), konverzija suncokretovog ulja u etil estre masnih kiselina (FAEE) dostigla vrednost od 98% nakon 120 minuta, što je 2 puta brže od transesterifikacije suncokretovog ulja bez prisustva kosolventa. Etil acetat i dietil etar poboljšavaju reakciju etanolize na početku, ali, kako reakcija napreduje, posle 180 minuta, njihovo prisustvo u reakcionoj smeši negativno utiče na brzinu reakcije i prinos etil estrara masnih kiselina (FAEE).",
publisher = "Univerzitet u Nišu - Tehnološki fakultet, Leskovac",
journal = "Advanced Technologies",
title = "Heterogeneously catalysed ethanolysis of sunflower oil in the presence of propylene glycol, ethyl acetate and diethyl ether as cosolvents, Heterogeno katalizovana etanoliza suncokretovog ulja u prisustvu polietilen glikola, etil acetata i dietil etra kao kosolvenata",
volume = "5",
number = "1",
pages = "66-72",
doi = "10.5937/savteh1601066D"
}
Đokić-Stojanović, D. R., Todorović, Z. B., Troter, D. Z., Todorović, V., Đorđević, B. S., Stamenković, O. S.,& Veljković, V. B.. (2016). Heterogeneously catalysed ethanolysis of sunflower oil in the presence of propylene glycol, ethyl acetate and diethyl ether as cosolvents. in Advanced Technologies
Univerzitet u Nišu - Tehnološki fakultet, Leskovac., 5(1), 66-72.
https://doi.org/10.5937/savteh1601066D
Đokić-Stojanović DR, Todorović ZB, Troter DZ, Todorović V, Đorđević BS, Stamenković OS, Veljković VB. Heterogeneously catalysed ethanolysis of sunflower oil in the presence of propylene glycol, ethyl acetate and diethyl ether as cosolvents. in Advanced Technologies. 2016;5(1):66-72.
doi:10.5937/savteh1601066D .
Đokić-Stojanović, Dušica R., Todorović, Zoran B., Troter, Dragan Z., Todorović, Vanja, Đorđević, Biljana S., Stamenković, Olivera S., Veljković, Vlada B., "Heterogeneously catalysed ethanolysis of sunflower oil in the presence of propylene glycol, ethyl acetate and diethyl ether as cosolvents" in Advanced Technologies, 5, no. 1 (2016):66-72,
https://doi.org/10.5937/savteh1601066D . .

The assessment and distribution of heavy metals in surface sediments from the reservoir 'Barje': Serbia

Todorović, Zoran B.; Ranđelović, Ljiljana M.; Marjanović, Jelena Z.; Todorović, Vanja; Cakić, Milorad; Cvetković, Olga G.

(Univerzitet u Nišu - Tehnološki fakultet, Leskovac, 2014)

TY  - JOUR
AU  - Todorović, Zoran B.
AU  - Ranđelović, Ljiljana M.
AU  - Marjanović, Jelena Z.
AU  - Todorović, Vanja
AU  - Cakić, Milorad
AU  - Cvetković, Olga G.
PY  - 2014
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2119
AB  - In this study, the nature of the association of heavy metals (Fe, Co, Ni, Cu, Cd, Pb, Mn, and Zn) in sediments of the recent reservoir 'Barje' (Leskovac, Serbia) was investigated. The aim was to make the identification of their substrates, as well as to define the external factors (hydrological and anthropogenic affecting their distribution) which will contribute to a better understanding of the interactions that take place in the reservoir and predict the mobility of the investigated heavy metals. Chemical distribution of heavy metals was tested by using the method of sequential extraction and by data processing using statistical methods such as correlation, cluster and factor analysis. Based on the obtained results it can be concluded that major substrates of heavy metals are in the residual immobile fraction (Fe, Zn and Ni). Since the accumulation has a small organic substance content, Fe and Mn oxides are the most important binding substrates of heavy metals. Although it was determined that lead and cadmium are of the carbonate nature, their concentrations in the reservoir are negligible.
AB  - Cilj ovog rada je da se ispitivanjem prirode asocijacija teških metala (Fe, Co, Ni, Cu, Cd, Pb, Mn, Zn) izvrši identifikacija njihovih supstrata u akumulaciji 'Barje' (Leskovac, Srbija), kao i da se definišu spoljni faktori (hidrološki i antropogeni koji utiču na njihovu raspodelu) što će doprineti boljem razumevanju interakcija koje se odigravaju u akumulaciji i prognozu mobilnosti na osnovu toga. Hemijska raspodela teških metala ispitana je korišćenjem metode sekvencijalne ekstrakcije i obradom dobijenih podataka statističkim metodama kao što su korelaciona, klaster i faktorska analiza. Na osnovu dobijenih rezultata može se zaključiti da se većina teških metala nalazi u rezidualnoj nepokretnoj frakciji (Fe, Zn i Ni). Zato što je u akumulaciji mali sadržaj organske supstance oksidi gvožđa i mangana su najznačajniji supstrati za vezivanje teških metala. Iako je utvrđeno da je olovo i kadmijum karbonatne prirode njihove koncentracije u akumulaciji su zanemarljivo male.
PB  - Univerzitet u Nišu - Tehnološki fakultet, Leskovac
T2  - Savremene tehnologije
T1  - The assessment and distribution of heavy metals in surface sediments from the reservoir 'Barje': Serbia
T1  - Procena sadržaja i raspodele teških metala u površinskom sedimentu akumulacije 'Barje' - Srbija
VL  - 3
IS  - 2
SP  - 85
EP  - 95
DO  - 10.5937/savteh1402085T
ER  - 
@article{
author = "Todorović, Zoran B. and Ranđelović, Ljiljana M. and Marjanović, Jelena Z. and Todorović, Vanja and Cakić, Milorad and Cvetković, Olga G.",
year = "2014",
abstract = "In this study, the nature of the association of heavy metals (Fe, Co, Ni, Cu, Cd, Pb, Mn, and Zn) in sediments of the recent reservoir 'Barje' (Leskovac, Serbia) was investigated. The aim was to make the identification of their substrates, as well as to define the external factors (hydrological and anthropogenic affecting their distribution) which will contribute to a better understanding of the interactions that take place in the reservoir and predict the mobility of the investigated heavy metals. Chemical distribution of heavy metals was tested by using the method of sequential extraction and by data processing using statistical methods such as correlation, cluster and factor analysis. Based on the obtained results it can be concluded that major substrates of heavy metals are in the residual immobile fraction (Fe, Zn and Ni). Since the accumulation has a small organic substance content, Fe and Mn oxides are the most important binding substrates of heavy metals. Although it was determined that lead and cadmium are of the carbonate nature, their concentrations in the reservoir are negligible., Cilj ovog rada je da se ispitivanjem prirode asocijacija teških metala (Fe, Co, Ni, Cu, Cd, Pb, Mn, Zn) izvrši identifikacija njihovih supstrata u akumulaciji 'Barje' (Leskovac, Srbija), kao i da se definišu spoljni faktori (hidrološki i antropogeni koji utiču na njihovu raspodelu) što će doprineti boljem razumevanju interakcija koje se odigravaju u akumulaciji i prognozu mobilnosti na osnovu toga. Hemijska raspodela teških metala ispitana je korišćenjem metode sekvencijalne ekstrakcije i obradom dobijenih podataka statističkim metodama kao što su korelaciona, klaster i faktorska analiza. Na osnovu dobijenih rezultata može se zaključiti da se većina teških metala nalazi u rezidualnoj nepokretnoj frakciji (Fe, Zn i Ni). Zato što je u akumulaciji mali sadržaj organske supstance oksidi gvožđa i mangana su najznačajniji supstrati za vezivanje teških metala. Iako je utvrđeno da je olovo i kadmijum karbonatne prirode njihove koncentracije u akumulaciji su zanemarljivo male.",
publisher = "Univerzitet u Nišu - Tehnološki fakultet, Leskovac",
journal = "Savremene tehnologije",
title = "The assessment and distribution of heavy metals in surface sediments from the reservoir 'Barje': Serbia, Procena sadržaja i raspodele teških metala u površinskom sedimentu akumulacije 'Barje' - Srbija",
volume = "3",
number = "2",
pages = "85-95",
doi = "10.5937/savteh1402085T"
}
Todorović, Z. B., Ranđelović, L. M., Marjanović, J. Z., Todorović, V., Cakić, M.,& Cvetković, O. G.. (2014). The assessment and distribution of heavy metals in surface sediments from the reservoir 'Barje': Serbia. in Savremene tehnologije
Univerzitet u Nišu - Tehnološki fakultet, Leskovac., 3(2), 85-95.
https://doi.org/10.5937/savteh1402085T
Todorović ZB, Ranđelović LM, Marjanović JZ, Todorović V, Cakić M, Cvetković OG. The assessment and distribution of heavy metals in surface sediments from the reservoir 'Barje': Serbia. in Savremene tehnologije. 2014;3(2):85-95.
doi:10.5937/savteh1402085T .
Todorović, Zoran B., Ranđelović, Ljiljana M., Marjanović, Jelena Z., Todorović, Vanja, Cakić, Milorad, Cvetković, Olga G., "The assessment and distribution of heavy metals in surface sediments from the reservoir 'Barje': Serbia" in Savremene tehnologije, 3, no. 2 (2014):85-95,
https://doi.org/10.5937/savteh1402085T . .
3

Numerical study on Bray-Liebhafsky oscillatory reaction: Bifurcations

Stanković, Branislav; Čupić, Željko; Pejić, Nataša; Kolar-Anić, Ljiljana

(L and H Scientific Publishing, LLC, 2013)

TY  - JOUR
AU  - Stanković, Branislav
AU  - Čupić, Željko
AU  - Pejić, Nataša
AU  - Kolar-Anić, Ljiljana
PY  - 2013
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2031
AB  - The time series obtained by numerical simulations of the model of the Bray-Liebhafsky oscillatory reaction is analyzed under the continuously fed well stirred tank reactor (CSTR) conditions, with the aim to find bifurcation points in which system of Bray- Liebhafsky oscillatory reaction transforms from stable to unstable state and vice versa. Types of bifurcation points, supercritical and subcritical Andronov-Hopf bifurcation and saddle-loop bifurcation are determined from characteristic scaling laws.
PB  - L and H Scientific Publishing, LLC
T2  - Journal of Applied Nonlinear Dynamics
T1  - Numerical study on Bray-Liebhafsky oscillatory reaction: Bifurcations
VL  - 2
IS  - 3
SP  - 285
EP  - 301
DO  - 10.5890/JAND.2013.08.004
ER  - 
@article{
author = "Stanković, Branislav and Čupić, Željko and Pejić, Nataša and Kolar-Anić, Ljiljana",
year = "2013",
abstract = "The time series obtained by numerical simulations of the model of the Bray-Liebhafsky oscillatory reaction is analyzed under the continuously fed well stirred tank reactor (CSTR) conditions, with the aim to find bifurcation points in which system of Bray- Liebhafsky oscillatory reaction transforms from stable to unstable state and vice versa. Types of bifurcation points, supercritical and subcritical Andronov-Hopf bifurcation and saddle-loop bifurcation are determined from characteristic scaling laws.",
publisher = "L and H Scientific Publishing, LLC",
journal = "Journal of Applied Nonlinear Dynamics",
title = "Numerical study on Bray-Liebhafsky oscillatory reaction: Bifurcations",
volume = "2",
number = "3",
pages = "285-301",
doi = "10.5890/JAND.2013.08.004"
}
Stanković, B., Čupić, Ž., Pejić, N.,& Kolar-Anić, L.. (2013). Numerical study on Bray-Liebhafsky oscillatory reaction: Bifurcations. in Journal of Applied Nonlinear Dynamics
L and H Scientific Publishing, LLC., 2(3), 285-301.
https://doi.org/10.5890/JAND.2013.08.004
Stanković B, Čupić Ž, Pejić N, Kolar-Anić L. Numerical study on Bray-Liebhafsky oscillatory reaction: Bifurcations. in Journal of Applied Nonlinear Dynamics. 2013;2(3):285-301.
doi:10.5890/JAND.2013.08.004 .
Stanković, Branislav, Čupić, Željko, Pejić, Nataša, Kolar-Anić, Ljiljana, "Numerical study on Bray-Liebhafsky oscillatory reaction: Bifurcations" in Journal of Applied Nonlinear Dynamics, 2, no. 3 (2013):285-301,
https://doi.org/10.5890/JAND.2013.08.004 . .
2
3

Analytical applications of oscillatory chemical reactions: Determination of some pharmaceutically and biologically important compounds

Pejić, Nataša; Anić, Slobodan; Kolar-Anić, Ljiljana

(Savez hemijskih inženjera, Beograd, 2012)

TY  - JOUR
AU  - Pejić, Nataša
AU  - Anić, Slobodan
AU  - Kolar-Anić, Ljiljana
PY  - 2012
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1770
AB  - Novel analytical methods for quantitive determination of analytes based on perturbations of oscillatory chemical reactions realized under open reactor conditions (continuosly fed well stirred tank reactor, CSTR), have been developed in the past twenty years. The proposed kinetic methods are generally based on the ability of the analyzed substances to change the kinetics of the chemical reactions matrix. The unambiguous correlation of quantitative characteristics of perturbations, and the amount (concentration) of analyte expressed as a regression equation, or its graphics (calibration curve), enable the determination of the unknown analyte concentration. Attention is given to the development of these methods because of their simple experimental procedures, broad range of linear regression (10-7-10-4 mol L-1) and low limits of detection of analytes (10-6-10-8 mol L-1, in some cases even lower than 10-12 mol L-1). Therefore, their application is very convenient for routine analysis of various inorganic and organic compounds as well as gases. This review summarizes progress made in the past 5 years on quantitative determination of pharmaceutically and biologically important compounds.
AB  - U poslednjih dvadesetak godina razvijene su brojne analitičke primene oscilatornih hemijskih reakcija realizovanih u otvorenom reaktoru. Predložene kinetičke metode se zasnivaju na sposobnosti analiziranih supstancija da menjaju kinetičke parametre hemijskih reakcija, pri čemu eksperimentalno dobijeni signal odražava reakcionu brzinu koja zavisi od koncentracije ispitivanog analita. Razvoju ovih metoda poklanja se sve veća pažnja zbog jednostavne eksperimentalne procedure, velikog linearnog opsega regresione jednačine (10-7-10-4 mol L-1) i niskog limita detekcije (10-6-10-8 mol L-1, u nekim slučajevima, ? 10-12 mol L-1), a njihovo korišćenje je vrlo pogodno za rutinske analize različitih neorganskih i organskih jedinjenja, kao i gasova. Ovaj rad ima za cilj da dâ kratki pregled primene takozvane pulsne perturbacione tehnike za kvantitativna određivanja nekih farmaceutski i biološki važnih jedinjenja u periodu od druge polovine 2005. godine do prve polovine 2011. godine.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Analytical applications of oscillatory chemical reactions: Determination of some pharmaceutically and biologically important compounds
T1  - Analitičke primene oscilatornih hemijskih reakcija - određivanje nekih farmaceutskih i biološki važnih jedinjenja
VL  - 66
IS  - 2
SP  - 153
EP  - 164
DO  - 10.2298/HEMIND110912081P
ER  - 
@article{
author = "Pejić, Nataša and Anić, Slobodan and Kolar-Anić, Ljiljana",
year = "2012",
abstract = "Novel analytical methods for quantitive determination of analytes based on perturbations of oscillatory chemical reactions realized under open reactor conditions (continuosly fed well stirred tank reactor, CSTR), have been developed in the past twenty years. The proposed kinetic methods are generally based on the ability of the analyzed substances to change the kinetics of the chemical reactions matrix. The unambiguous correlation of quantitative characteristics of perturbations, and the amount (concentration) of analyte expressed as a regression equation, or its graphics (calibration curve), enable the determination of the unknown analyte concentration. Attention is given to the development of these methods because of their simple experimental procedures, broad range of linear regression (10-7-10-4 mol L-1) and low limits of detection of analytes (10-6-10-8 mol L-1, in some cases even lower than 10-12 mol L-1). Therefore, their application is very convenient for routine analysis of various inorganic and organic compounds as well as gases. This review summarizes progress made in the past 5 years on quantitative determination of pharmaceutically and biologically important compounds., U poslednjih dvadesetak godina razvijene su brojne analitičke primene oscilatornih hemijskih reakcija realizovanih u otvorenom reaktoru. Predložene kinetičke metode se zasnivaju na sposobnosti analiziranih supstancija da menjaju kinetičke parametre hemijskih reakcija, pri čemu eksperimentalno dobijeni signal odražava reakcionu brzinu koja zavisi od koncentracije ispitivanog analita. Razvoju ovih metoda poklanja se sve veća pažnja zbog jednostavne eksperimentalne procedure, velikog linearnog opsega regresione jednačine (10-7-10-4 mol L-1) i niskog limita detekcije (10-6-10-8 mol L-1, u nekim slučajevima, ? 10-12 mol L-1), a njihovo korišćenje je vrlo pogodno za rutinske analize različitih neorganskih i organskih jedinjenja, kao i gasova. Ovaj rad ima za cilj da dâ kratki pregled primene takozvane pulsne perturbacione tehnike za kvantitativna određivanja nekih farmaceutski i biološki važnih jedinjenja u periodu od druge polovine 2005. godine do prve polovine 2011. godine.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Analytical applications of oscillatory chemical reactions: Determination of some pharmaceutically and biologically important compounds, Analitičke primene oscilatornih hemijskih reakcija - određivanje nekih farmaceutskih i biološki važnih jedinjenja",
volume = "66",
number = "2",
pages = "153-164",
doi = "10.2298/HEMIND110912081P"
}
Pejić, N., Anić, S.,& Kolar-Anić, L.. (2012). Analytical applications of oscillatory chemical reactions: Determination of some pharmaceutically and biologically important compounds. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 66(2), 153-164.
https://doi.org/10.2298/HEMIND110912081P
Pejić N, Anić S, Kolar-Anić L. Analytical applications of oscillatory chemical reactions: Determination of some pharmaceutically and biologically important compounds. in Hemijska industrija. 2012;66(2):153-164.
doi:10.2298/HEMIND110912081P .
Pejić, Nataša, Anić, Slobodan, Kolar-Anić, Ljiljana, "Analytical applications of oscillatory chemical reactions: Determination of some pharmaceutically and biologically important compounds" in Hemijska industrija, 66, no. 2 (2012):153-164,
https://doi.org/10.2298/HEMIND110912081P . .
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Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst

Maksimović, Jelena; Čupić, Željko; Lončarević, D.; Pejić, Nataša; Vasiljević-Radović, D.; Anić, Slobodan

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2011)

TY  - JOUR
AU  - Maksimović, Jelena
AU  - Čupić, Željko
AU  - Lončarević, D.
AU  - Pejić, Nataša
AU  - Vasiljević-Radović, D.
AU  - Anić, Slobodan
PY  - 2011
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1575
AB  - The Bray-Liebhafsky (BL) oscillatory reaction generated in the batch reactor at 62- 68 oC was perturbed by cobalt(II)-nitrate, supported on the macroreticular copolymer of poly-4-vinylpyridine with divinylbenzene (Co-PVPDVB). The kinetic data was analyzed of the complex pathways of the hydrogen peroxide decomposition in the examined BL reaction. The obtained results confirm that the kinetics of the BL reaction in the presence Co-PVPDVB comes partially from the Co-catalyst and partially from the macroreticular copolymer support.
AB  - Oscilatorna reakcija Bray-Liebhafsky (BL) realizovana u zatvorenom reaktoru na temperaturi 62-68 oC je perturbovana sa kobalt(II)nitratom ugrađenim na makroretikularnom kopolimeru poli-4-vinilpiridina sa divinilbenzenom (Co- PVPDVB). Analizirani su kinetički podaci kompleksnih reakcionih puteva razlaganja vodonikperoksida u ispitivanoj BL reakciji. Dobijeni rezultati potvrđuju da je u prisustvu Co-PVPDVB kinetika BL reakcije delimično određena Co-katalizatorom, a delimično makromolekularnim kopolimernim nosačem katalizatora.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst
VL  - 43
IS  - 1
SP  - 55
EP  - 62
DO  - 10.2298/SOS1101055M
ER  - 
@article{
author = "Maksimović, Jelena and Čupić, Željko and Lončarević, D. and Pejić, Nataša and Vasiljević-Radović, D. and Anić, Slobodan",
year = "2011",
abstract = "The Bray-Liebhafsky (BL) oscillatory reaction generated in the batch reactor at 62- 68 oC was perturbed by cobalt(II)-nitrate, supported on the macroreticular copolymer of poly-4-vinylpyridine with divinylbenzene (Co-PVPDVB). The kinetic data was analyzed of the complex pathways of the hydrogen peroxide decomposition in the examined BL reaction. The obtained results confirm that the kinetics of the BL reaction in the presence Co-PVPDVB comes partially from the Co-catalyst and partially from the macroreticular copolymer support., Oscilatorna reakcija Bray-Liebhafsky (BL) realizovana u zatvorenom reaktoru na temperaturi 62-68 oC je perturbovana sa kobalt(II)nitratom ugrađenim na makroretikularnom kopolimeru poli-4-vinilpiridina sa divinilbenzenom (Co- PVPDVB). Analizirani su kinetički podaci kompleksnih reakcionih puteva razlaganja vodonikperoksida u ispitivanoj BL reakciji. Dobijeni rezultati potvrđuju da je u prisustvu Co-PVPDVB kinetika BL reakcije delimično određena Co-katalizatorom, a delimično makromolekularnim kopolimernim nosačem katalizatora.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst",
volume = "43",
number = "1",
pages = "55-62",
doi = "10.2298/SOS1101055M"
}
Maksimović, J., Čupić, Ž., Lončarević, D., Pejić, N., Vasiljević-Radović, D.,& Anić, S.. (2011). Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 43(1), 55-62.
https://doi.org/10.2298/SOS1101055M
Maksimović J, Čupić Ž, Lončarević D, Pejić N, Vasiljević-Radović D, Anić S. Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst. in Science of Sintering. 2011;43(1):55-62.
doi:10.2298/SOS1101055M .
Maksimović, Jelena, Čupić, Željko, Lončarević, D., Pejić, Nataša, Vasiljević-Radović, D., Anić, Slobodan, "Kinetics of the Bray-Liebhafsky oscillatory reaction perturbed by polymer supported cobalt catalyst" in Science of Sintering, 43, no. 1 (2011):55-62,
https://doi.org/10.2298/SOS1101055M . .
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