German Federal Ministry of Education and Research IWINDOR 040

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German Federal Ministry of Education and Research IWINDOR 040

Authors

Publications

Resistive gas sensors based on the composites of nanostructured carbonized polyaniline and Nafion

Pasti, Igor; Janošević-Ležaić, Aleksandra; Ćirić-Marjanović, Gordana; Mirsky, Vladimir M.

(Springer, New York, 2016)

TY  - JOUR
AU  - Pasti, Igor
AU  - Janošević-Ležaić, Aleksandra
AU  - Ćirić-Marjanović, Gordana
AU  - Mirsky, Vladimir M.
PY  - 2016
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2735
AB  - Due to constant necessity to have reliable and sensitive gas sensors in many contemporary technologies, there is a permanent need for development of new sensing platforms with good sensing properties. Here, we demonstrate a novel type of resistive gas sensors based on carbonized polyaniline/Nafion composites. The sensing mechanism of such sensors is based on the sorption of gases by the composites which induce Nafion swelling and decreasing of conductivity. Chemosensitive properties can be tuned by the (i) choice of carbon materials with different conductivities, (ii) Nafion content in the composite, and (iii) thickness of the composite layer. We have shown that the sensors respond to water, acetone, ethanol, and methanol vapors. For the last two cases, we have achieved high sensitivity, fast response, wide concentration range, and good recovery. The use of simultaneous two- and four-point techniques for these sensors provides an internal control of the sensor integrity.
PB  - Springer, New York
T2  - Journal of Solid State Electrochemistry
T1  - Resistive gas sensors based on the composites of nanostructured carbonized polyaniline and Nafion
VL  - 20
IS  - 11
SP  - 3061
EP  - 3069
DO  - 10.1007/s10008-016-3344-y
ER  - 
@article{
author = "Pasti, Igor and Janošević-Ležaić, Aleksandra and Ćirić-Marjanović, Gordana and Mirsky, Vladimir M.",
year = "2016",
abstract = "Due to constant necessity to have reliable and sensitive gas sensors in many contemporary technologies, there is a permanent need for development of new sensing platforms with good sensing properties. Here, we demonstrate a novel type of resistive gas sensors based on carbonized polyaniline/Nafion composites. The sensing mechanism of such sensors is based on the sorption of gases by the composites which induce Nafion swelling and decreasing of conductivity. Chemosensitive properties can be tuned by the (i) choice of carbon materials with different conductivities, (ii) Nafion content in the composite, and (iii) thickness of the composite layer. We have shown that the sensors respond to water, acetone, ethanol, and methanol vapors. For the last two cases, we have achieved high sensitivity, fast response, wide concentration range, and good recovery. The use of simultaneous two- and four-point techniques for these sensors provides an internal control of the sensor integrity.",
publisher = "Springer, New York",
journal = "Journal of Solid State Electrochemistry",
title = "Resistive gas sensors based on the composites of nanostructured carbonized polyaniline and Nafion",
volume = "20",
number = "11",
pages = "3061-3069",
doi = "10.1007/s10008-016-3344-y"
}
Pasti, I., Janošević-Ležaić, A., Ćirić-Marjanović, G.,& Mirsky, V. M.. (2016). Resistive gas sensors based on the composites of nanostructured carbonized polyaniline and Nafion. in Journal of Solid State Electrochemistry
Springer, New York., 20(11), 3061-3069.
https://doi.org/10.1007/s10008-016-3344-y
Pasti I, Janošević-Ležaić A, Ćirić-Marjanović G, Mirsky VM. Resistive gas sensors based on the composites of nanostructured carbonized polyaniline and Nafion. in Journal of Solid State Electrochemistry. 2016;20(11):3061-3069.
doi:10.1007/s10008-016-3344-y .
Pasti, Igor, Janošević-Ležaić, Aleksandra, Ćirić-Marjanović, Gordana, Mirsky, Vladimir M., "Resistive gas sensors based on the composites of nanostructured carbonized polyaniline and Nafion" in Journal of Solid State Electrochemistry, 20, no. 11 (2016):3061-3069,
https://doi.org/10.1007/s10008-016-3344-y . .
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Influence of synthetic conditions on the structure and electrical properties of nanofibrous polyanilines and their nanofibrous carbonized forms

Janošević-Ležaić, Aleksandra; Bajuk-Bogdanović, Danica; Radoicić, Marija; Mirsky, Vladimir M.; Ćirić-Marjanović, Gordana

(Elsevier Science Sa, Lausanne, 2016)

TY  - JOUR
AU  - Janošević-Ležaić, Aleksandra
AU  - Bajuk-Bogdanović, Danica
AU  - Radoicić, Marija
AU  - Mirsky, Vladimir M.
AU  - Ćirić-Marjanović, Gordana
PY  - 2016
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2596
AB  - Nanofibrous polyanilines (PANIs) were synthesized by several oxidative polymerization pathways that have in common the presence of excess oxidant(s) (ammonium peroxydisulfate and its mixture with hydrogen peroxide), the absence of added acid, and the absence of external template (self-assembly process). Conducting forms of the synthesized PANI nanofibers (re)doped with various acids were further used as precursors for carbonization process to obtain nanofibrous carbonaceous materials (Carb-PANIs). Morphology, molecular structure, surface properties and electrical characteristics of PANI nanofibrous precursors and their carbonized counterparts were studied by scanning electron microscopy, Raman spectroscopy, by measurements of zeta-potential and determination of isoelectric points, as well as by measurements of electrical conductivity.
PB  - Elsevier Science Sa, Lausanne
T2  - Synthetic Metals
T1  - Influence of synthetic conditions on the structure and electrical properties of nanofibrous polyanilines and their nanofibrous carbonized forms
VL  - 214
SP  - 35
EP  - 44
DO  - 10.1016/j.synthmet.2016.01.015
ER  - 
@article{
author = "Janošević-Ležaić, Aleksandra and Bajuk-Bogdanović, Danica and Radoicić, Marija and Mirsky, Vladimir M. and Ćirić-Marjanović, Gordana",
year = "2016",
abstract = "Nanofibrous polyanilines (PANIs) were synthesized by several oxidative polymerization pathways that have in common the presence of excess oxidant(s) (ammonium peroxydisulfate and its mixture with hydrogen peroxide), the absence of added acid, and the absence of external template (self-assembly process). Conducting forms of the synthesized PANI nanofibers (re)doped with various acids were further used as precursors for carbonization process to obtain nanofibrous carbonaceous materials (Carb-PANIs). Morphology, molecular structure, surface properties and electrical characteristics of PANI nanofibrous precursors and their carbonized counterparts were studied by scanning electron microscopy, Raman spectroscopy, by measurements of zeta-potential and determination of isoelectric points, as well as by measurements of electrical conductivity.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Synthetic Metals",
title = "Influence of synthetic conditions on the structure and electrical properties of nanofibrous polyanilines and their nanofibrous carbonized forms",
volume = "214",
pages = "35-44",
doi = "10.1016/j.synthmet.2016.01.015"
}
Janošević-Ležaić, A., Bajuk-Bogdanović, D., Radoicić, M., Mirsky, V. M.,& Ćirić-Marjanović, G.. (2016). Influence of synthetic conditions on the structure and electrical properties of nanofibrous polyanilines and their nanofibrous carbonized forms. in Synthetic Metals
Elsevier Science Sa, Lausanne., 214, 35-44.
https://doi.org/10.1016/j.synthmet.2016.01.015
Janošević-Ležaić A, Bajuk-Bogdanović D, Radoicić M, Mirsky VM, Ćirić-Marjanović G. Influence of synthetic conditions on the structure and electrical properties of nanofibrous polyanilines and their nanofibrous carbonized forms. in Synthetic Metals. 2016;214:35-44.
doi:10.1016/j.synthmet.2016.01.015 .
Janošević-Ležaić, Aleksandra, Bajuk-Bogdanović, Danica, Radoicić, Marija, Mirsky, Vladimir M., Ćirić-Marjanović, Gordana, "Influence of synthetic conditions on the structure and electrical properties of nanofibrous polyanilines and their nanofibrous carbonized forms" in Synthetic Metals, 214 (2016):35-44,
https://doi.org/10.1016/j.synthmet.2016.01.015 . .
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