Приказ основних података о документу
Spectrophotometric investigation of the uranyl-phenylephrine system
Spektrofotometrijsko ispitivanje uranil-fenilefrin sistema
dc.creator | Pavun, Leposava | |
dc.creator | Malešev, Dušan | |
dc.creator | Veselinović, Dragan S. | |
dc.date.accessioned | 2019-09-02T11:11:38Z | |
dc.date.available | 2019-09-02T11:11:38Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://farfar.pharmacy.bg.ac.rs/handle/123456789/1001 | |
dc.description.abstract | Using spectrophotometric methods and pH-metric measurements, it was found that the uranyl ion and phenylephrine form a 1:2 complex in the pH region 2.50-4.25 with two absorption maxima at 314.2 nm and 340.6 nm. The thermodynamic stability constant at I = 0 and T=298 K (room temperature) of the UO2(II)-phenylephrine complex, UO2(C9H12O2N)2, is log 0 β 2= 14.0 and ΔG2= -79.6 kJ mol-1. A linear dependence of the absorbance at 340.6 nm on the concentration of phenylephrine was obtained in the range from 0.0025 mol dm-3 to 0.0245 mol dm-3 using a solution of 0.025 mol dm-3 UO2(NO3)2 at pH = 3.90 and I = 0.075 mol dm-3. The measurement error was 2.1%. . | en |
dc.description.abstract | Primenom spektrofotometrijskih metoda i pH-metrijskih merenja utvrđeno je da UO2(II)-jon i fenilefrin grade 1:2 kompleks u oblasti rN 2,50 - 4,25 sa dva apsorpciona maksimuma na 314,2 nm i 340,6 nm. Termodinamička konstanta stabilnosti kompleksa UO2(II)-fenilefrin, UO2(C9H12O2N)2, na I = 0 i na sobnoj temperaturi (25°C) iznosi log 0 β 2 = 14,0, a ΔG2= = -79,6 kJ mol-1. Linearna zavisnost apsorbancije od koncentracije fenilefrina u vodenom rastvoru UO2(NO3)2 koncentracije 0,025 mol dm-3 na 340,6 nm dobijena je u intervalu 0,0025-0,0245 mol dm-3 na pH 3,90 i I = 0,075 mol dm-3. Greška merenja iznosi 2.1%. . | sr |
dc.publisher | Srpsko hemijsko društvo, Beograd | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | complex | en |
dc.subject | uranyl ion | en |
dc.subject | phenylephrine | en |
dc.subject | thermodynamic stability constant | en |
dc.title | Spectrophotometric investigation of the uranyl-phenylephrine system | en |
dc.title | Spektrofotometrijsko ispitivanje uranil-fenilefrin sistema | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Малешев, Душан; Веселиновић, Драган С.; Павун, Лепосава; Спектрофотометријско испитивање уранил-фенилефрин система; Спектрофотометријско испитивање уранил-фенилефрин система; | |
dc.citation.volume | 72 | |
dc.citation.issue | 8-9 | |
dc.citation.spage | 799 | |
dc.citation.epage | 807 | |
dc.citation.other | 72(8-9): 799-807 | |
dc.citation.rank | M23 | |
dc.identifier.wos | 000249768600007 | |
dc.identifier.doi | 10.2298/JSC0709799P | |
dc.identifier.scopus | 2-s2.0-34548381393 | |
dc.identifier.fulltext | https://farfar.pharmacy.bg.ac.rs//bitstream/id/2321/999.pdf | |
dc.type.version | publishedVersion |