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A useful synthetic equivalent of an acetone enolate

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2009
Authors
Maslak, Veselin
Tokić-Vujošević, Zorana
Ferjancić, Zorana
Saičić, Radomir N.
Article (Published version)
Metadata
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Abstract
2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.
Keywords:
Allylation / Aldehydes / Indium / Zinc / Aldol reaction / Water
Source:
Tetrahedron-Asymmetry, 2009, 50, 48, 6709-6711
Publisher:
  • Pergamon-Elsevier Science Ltd, Oxford
Projects:
  • Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (RS-142021)

DOI: 10.1016/j.tetlet.2009.09.113

ISSN: 0040-4039

WoS: 000271410800025

Scopus: 2-s2.0-70349992636
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URI
http://farfar.pharmacy.bg.ac.rs/handle/123456789/1204
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  • Radovi istraživača / Researchers’ publications
Institution
Pharmacy

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