2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.
TY - JOUR
AU - Maslak, Veselin
AU - Tokić-Vujošević, Zorana
AU - Ferjancić, Zorana
AU - Saičić, Radomir N.
PY - 2009
UR - http://farfar.pharmacy.bg.ac.rs/handle/123456789/1204
AB - 2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Tetrahedron-Asymmetry
T1 - A useful synthetic equivalent of an acetone enolate
VL - 50
IS - 48
SP - 6709
EP - 6711
DO - 10.1016/j.tetlet.2009.09.113
UR - conv_2248
ER -
@article{
author = "Maslak, Veselin and Tokić-Vujošević, Zorana and Ferjancić, Zorana and Saičić, Radomir N.",
year = "2009",
abstract = "2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Tetrahedron-Asymmetry",
title = "A useful synthetic equivalent of an acetone enolate",
volume = "50",
number = "48",
pages = "6709-6711",
doi = "10.1016/j.tetlet.2009.09.113",
url = "conv_2248"
}
Maslak, V., Tokić-Vujošević, Z., Ferjancić, Z.,& Saičić, R. N.. (2009). A useful synthetic equivalent of an acetone enolate. in Tetrahedron-Asymmetry
Pergamon-Elsevier Science Ltd, Oxford., 50(48), 6709-6711.
https://doi.org/10.1016/j.tetlet.2009.09.113
conv_2248
Maslak V, Tokić-Vujošević Z, Ferjancić Z, Saičić RN. A useful synthetic equivalent of an acetone enolate. in Tetrahedron-Asymmetry. 2009;50(48):6709-6711.
doi:10.1016/j.tetlet.2009.09.113
conv_2248 .
Maslak, Veselin, Tokić-Vujošević, Zorana, Ferjancić, Zorana, Saičić, Radomir N., "A useful synthetic equivalent of an acetone enolate" in Tetrahedron-Asymmetry, 50, no. 48 (2009):6709-6711,
https://doi.org/10.1016/j.tetlet.2009.09.113 .,
conv_2248 .
