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Palladium-catalysed synthesis of allyl acetates from allenes

Authorized Users Only
2010
Authors
Husinec, Suren
Jadranin, Milka
Marković, Rade
Petković, Miloš
Savić, Vladimir
Todorović, Nina
Article (Published version)
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Abstract
Allyl acetates were synthesised from allenes utilising methodology based on the general reactivity of pi-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc)(2)/PPh(3) as the catalytic system afforded allyl acetates in moderate to good yields. Monosubstituted allenes, depending on their structure, produced either a separable mixture of two regioisomeric products or a single regioisomer. As allylic acetates can be easily hydrolysed, the methodology is applicable for the synthesis of allyl alcohols as well.
Source:
Tetrahedron-Asymmetry, 2010, 51, 31, 4066-4068
Publisher:
  • Pergamon-Elsevier Science Ltd, Oxford
Projects:
  • Sinteza, kvantitativni odnosi između strukture/osobina i aktivnosti, fizičko-hemijska karakterizacija i analiza farmakološki aktivnih supstanci (RS-142071)

DOI: 10.1016/j.tetlet.2010.05.136

ISSN: 0040-4039

WoS: 000280053600018

Scopus: 2-s2.0-77954031310
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11
URI
http://farfar.pharmacy.bg.ac.rs/handle/123456789/1382
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  • Radovi istraživača / Researchers’ publications
Institution
Pharmacy

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