Indium promoted allyiation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords and-alpha,beta-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions Into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldois.
TY - JOUR
AU - Bigović, Miljan
AU - Maslak, Veselin
AU - Tokić-Vujošević, Zorana
AU - Divjaković, Vladimir
AU - Saičić, Radomir N.
PY - 2011
UR - http://farfar.pharmacy.bg.ac.rs/handle/123456789/1482
AB - Indium promoted allyiation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords and-alpha,beta-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions Into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldois.
PB - Amer Chemical Soc, Washington
T2 - Organic Letters
T1 - A Useful Synthetic Equivalent of a Hydroxyacetone Enolate
VL - 13
IS - 17
SP - 4720
EP - 4723
DO - 10.1021/ol2019357
ER -
@article{
author = "Bigović, Miljan and Maslak, Veselin and Tokić-Vujošević, Zorana and Divjaković, Vladimir and Saičić, Radomir N.",
year = "2011",
url = "http://farfar.pharmacy.bg.ac.rs/handle/123456789/1482",
abstract = "Indium promoted allyiation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords and-alpha,beta-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions Into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldois.",
publisher = "Amer Chemical Soc, Washington",
journal = "Organic Letters",
title = "A Useful Synthetic Equivalent of a Hydroxyacetone Enolate",
volume = "13",
number = "17",
pages = "4720-4723",
doi = "10.1021/ol2019357"
}
Bigović, M., Maslak, V., Tokić-Vujošević, Z., Divjaković, V.,& Saičić, R. N. (2011). A Useful Synthetic Equivalent of a Hydroxyacetone Enolate.
Organic Letters
Amer Chemical Soc, Washington., 13(17), 4720-4723.
https://doi.org/10.1021/ol2019357
Bigović M, Maslak V, Tokić-Vujošević Z, Divjaković V, Saičić RN. A Useful Synthetic Equivalent of a Hydroxyacetone Enolate. Organic Letters. 2011;13(17):4720-4723
Bigović Miljan, Maslak Veselin, Tokić-Vujošević Zorana, Divjaković Vladimir, Saičić Radomir N., "A Useful Synthetic Equivalent of a Hydroxyacetone Enolate" Organic Letters, 13, no. 17 (2011):4720-4723,
https://doi.org/10.1021/ol2019357 .
