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A Useful Synthetic Equivalent of a Hydroxyacetone Enolate

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2011
Authors
Bigović, Miljan
Maslak, Veselin
Tokić-Vujošević, Zorana
Divjaković, Vladimir
Saičić, Radomir N.
Article (Published version)
Metadata
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Abstract
Indium promoted allyiation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords and-alpha,beta-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions Into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldois.
Source:
Organic Letters, 2011, 13, 17, 4720-4723
Publisher:
  • Amer Chemical Soc, Washington
Projects:
  • The development of new synthetic methods and their application in the synthesis of natural products and biologically active molecules (RS-172027)

DOI: 10.1021/ol2019357

ISSN: 1523-7060

PubMed: 21815664

WoS: 000294242600062

Scopus: 2-s2.0-80052215702
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URI
http://farfar.pharmacy.bg.ac.rs/handle/123456789/1482
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  • Radovi istraživača / Researchers’ publications
Institution
Pharmacy

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