pH-metric investigation of the system containing palladium(II) ion and obidoxime chloride
Apstrakt
The formation of a complex between palladium (II) chloride obidoxime chloride has been studied by means of pH-metric measurements. Thee mean value of the real stability constant of the complex in aqueous medium of ionic strengths 0.55 M and 1.0 M (KCl) at 298 K was log K-S = 6.72. This value was close to that (log K-S = 6.63) obtained previously by spectrophotometric methods but after appropriate correction with respect to the corresponding value of the first acidic constant of obidoxime chloride which was also determined under the same experimental conditions. The participation of only one oxime group in obidoxime-Pd(II) complex formation has been established, whose acidity significantly increases with coordination to palladium (II) ion. The pH-metric studies confirmed previously defined components ratio (1:1) in the complex by spectrophotometric methods.
Ključne reči:
Obidoxime chloride / Palladium (II) complex / Stability constantIzvor:
Bulletin of Electrochemistry, 1997, 13, 2, 83-87Izdavač:
- Central Electrochem Res Inst, Karaikkudi
Institucija/grupa
PharmacyTY - JOUR AU - Karljiković-Rajić, Katarina AU - Rajković, MB PY - 1997 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/160 AB - The formation of a complex between palladium (II) chloride obidoxime chloride has been studied by means of pH-metric measurements. Thee mean value of the real stability constant of the complex in aqueous medium of ionic strengths 0.55 M and 1.0 M (KCl) at 298 K was log K-S = 6.72. This value was close to that (log K-S = 6.63) obtained previously by spectrophotometric methods but after appropriate correction with respect to the corresponding value of the first acidic constant of obidoxime chloride which was also determined under the same experimental conditions. The participation of only one oxime group in obidoxime-Pd(II) complex formation has been established, whose acidity significantly increases with coordination to palladium (II) ion. The pH-metric studies confirmed previously defined components ratio (1:1) in the complex by spectrophotometric methods. PB - Central Electrochem Res Inst, Karaikkudi T2 - Bulletin of Electrochemistry T1 - pH-metric investigation of the system containing palladium(II) ion and obidoxime chloride VL - 13 IS - 2 SP - 83 EP - 87 UR - https://hdl.handle.net/21.15107/rcub_farfar_160 ER -
@article{ author = "Karljiković-Rajić, Katarina and Rajković, MB", year = "1997", abstract = "The formation of a complex between palladium (II) chloride obidoxime chloride has been studied by means of pH-metric measurements. Thee mean value of the real stability constant of the complex in aqueous medium of ionic strengths 0.55 M and 1.0 M (KCl) at 298 K was log K-S = 6.72. This value was close to that (log K-S = 6.63) obtained previously by spectrophotometric methods but after appropriate correction with respect to the corresponding value of the first acidic constant of obidoxime chloride which was also determined under the same experimental conditions. The participation of only one oxime group in obidoxime-Pd(II) complex formation has been established, whose acidity significantly increases with coordination to palladium (II) ion. The pH-metric studies confirmed previously defined components ratio (1:1) in the complex by spectrophotometric methods.", publisher = "Central Electrochem Res Inst, Karaikkudi", journal = "Bulletin of Electrochemistry", title = "pH-metric investigation of the system containing palladium(II) ion and obidoxime chloride", volume = "13", number = "2", pages = "83-87", url = "https://hdl.handle.net/21.15107/rcub_farfar_160" }
Karljiković-Rajić, K.,& Rajković, M.. (1997). pH-metric investigation of the system containing palladium(II) ion and obidoxime chloride. in Bulletin of Electrochemistry Central Electrochem Res Inst, Karaikkudi., 13(2), 83-87. https://hdl.handle.net/21.15107/rcub_farfar_160
Karljiković-Rajić K, Rajković M. pH-metric investigation of the system containing palladium(II) ion and obidoxime chloride. in Bulletin of Electrochemistry. 1997;13(2):83-87. https://hdl.handle.net/21.15107/rcub_farfar_160 .
Karljiković-Rajić, Katarina, Rajković, MB, "pH-metric investigation of the system containing palladium(II) ion and obidoxime chloride" in Bulletin of Electrochemistry, 13, no. 2 (1997):83-87, https://hdl.handle.net/21.15107/rcub_farfar_160 .