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dc.creatorKarljiković-Rajić, Katarina
dc.creatorRajković, MB
dc.date.accessioned2019-09-02T10:50:00Z
dc.date.available2019-09-02T10:50:00Z
dc.date.issued1997
dc.identifier.issn0256-1654
dc.identifier.urihttp://farfar.pharmacy.bg.ac.rs/handle/123456789/160
dc.description.abstractThe formation of a complex between palladium (II) chloride obidoxime chloride has been studied by means of pH-metric measurements. Thee mean value of the real stability constant of the complex in aqueous medium of ionic strengths 0.55 M and 1.0 M (KCl) at 298 K was log K-S = 6.72. This value was close to that (log K-S = 6.63) obtained previously by spectrophotometric methods but after appropriate correction with respect to the corresponding value of the first acidic constant of obidoxime chloride which was also determined under the same experimental conditions. The participation of only one oxime group in obidoxime-Pd(II) complex formation has been established, whose acidity significantly increases with coordination to palladium (II) ion. The pH-metric studies confirmed previously defined components ratio (1:1) in the complex by spectrophotometric methods.en
dc.publisherCentral Electrochem Res Inst, Karaikkudi
dc.rightsrestrictedAccess
dc.sourceBulletin of Electrochemistry
dc.subjectObidoxime chlorideen
dc.subjectPalladium (II) complexen
dc.subjectStability constanten
dc.titlepH-metric investigation of the system containing palladium(II) ion and obidoxime chlorideen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractРајковић, МБ; Карљиковић-Рајић, Катарина;
dc.citation.volume13
dc.citation.issue2
dc.citation.spage83
dc.citation.epage87
dc.citation.other13(2): 83-87
dc.identifier.wosA1997WN20900008
dc.identifier.scopus2-s2.0-0642309189
dc.identifier.rcubconv_4487
dc.type.versionpublishedVersion


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