Synthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienes
Само за регистроване кориснике
2012
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
pi-Allylpalladium intermediates are known to participate efficiently in transformations involving nucleophilic species. Exploring these processes, we have developed a method for the preparation of allyl acetates via palladium-catalysed functionalisation of allenes and 1,3-dienes. Reactions of aryl iodides with either of these two classes of compounds and excess sodium acetate in the presence of Pd(OAc) (2) and Ph3P as the catalytic system afforded the respective allyl acetates in moderate to good yields. The scope of this process has been investigated. The described method is an addition to the synthetic repertoire for the preparation of allyl acetates, and may be useful, in particular, for the synthesis of structurally complex compounds of this type.
Кључне речи:
allyl acetates / palladium catalysis / allenes / dienes / synthesisИзвор:
Synthesis, 2012, 44, 3, 399-408Издавач:
- Georg Thieme Verlag Kg, Stuttgart
Финансирање / пројекти:
- Компјутерско дизајнирање, синтеза и биолошка евалуација нових хетероцикличних једињења као селективних инхибитора туморогенезе (RS-MESTD-Basic Research (BR or ON)-172009)
DOI: 10.1055/s-0031-1289658
ISSN: 0039-7881
WoS: 000300255100013
Scopus: 2-s2.0-84856231784
Институција/група
PharmacyTY - JOUR AU - Husinec, Suren AU - Petković, Miloš AU - Savić, Vladimir AU - Simić, Milena PY - 2012 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1724 AB - pi-Allylpalladium intermediates are known to participate efficiently in transformations involving nucleophilic species. Exploring these processes, we have developed a method for the preparation of allyl acetates via palladium-catalysed functionalisation of allenes and 1,3-dienes. Reactions of aryl iodides with either of these two classes of compounds and excess sodium acetate in the presence of Pd(OAc) (2) and Ph3P as the catalytic system afforded the respective allyl acetates in moderate to good yields. The scope of this process has been investigated. The described method is an addition to the synthetic repertoire for the preparation of allyl acetates, and may be useful, in particular, for the synthesis of structurally complex compounds of this type. PB - Georg Thieme Verlag Kg, Stuttgart T2 - Synthesis T1 - Synthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienes VL - 44 IS - 3 SP - 399 EP - 408 DO - 10.1055/s-0031-1289658 ER -
@article{ author = "Husinec, Suren and Petković, Miloš and Savić, Vladimir and Simić, Milena", year = "2012", abstract = "pi-Allylpalladium intermediates are known to participate efficiently in transformations involving nucleophilic species. Exploring these processes, we have developed a method for the preparation of allyl acetates via palladium-catalysed functionalisation of allenes and 1,3-dienes. Reactions of aryl iodides with either of these two classes of compounds and excess sodium acetate in the presence of Pd(OAc) (2) and Ph3P as the catalytic system afforded the respective allyl acetates in moderate to good yields. The scope of this process has been investigated. The described method is an addition to the synthetic repertoire for the preparation of allyl acetates, and may be useful, in particular, for the synthesis of structurally complex compounds of this type.", publisher = "Georg Thieme Verlag Kg, Stuttgart", journal = "Synthesis", title = "Synthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienes", volume = "44", number = "3", pages = "399-408", doi = "10.1055/s-0031-1289658" }
Husinec, S., Petković, M., Savić, V.,& Simić, M.. (2012). Synthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienes. in Synthesis Georg Thieme Verlag Kg, Stuttgart., 44(3), 399-408. https://doi.org/10.1055/s-0031-1289658
Husinec S, Petković M, Savić V, Simić M. Synthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienes. in Synthesis. 2012;44(3):399-408. doi:10.1055/s-0031-1289658 .
Husinec, Suren, Petković, Miloš, Savić, Vladimir, Simić, Milena, "Synthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienes" in Synthesis, 44, no. 3 (2012):399-408, https://doi.org/10.1055/s-0031-1289658 . .