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dc.creatorJanošević, Aleksandra
dc.creatorĆirić-Marjanović, Gordana
dc.creatorSljukić-Paunković, Biljana
dc.creatorPasti, Igor
dc.creatorTrifunović, Snežana
dc.creatorMarjanović, Budimir
dc.creatorStejskal, Jaroslav
dc.date.accessioned2019-09-02T11:30:15Z
dc.date.available2019-09-02T11:30:15Z
dc.date.issued2012
dc.identifier.issn0379-6779
dc.identifier.urihttp://farfar.pharmacy.bg.ac.rs/handle/123456789/1755
dc.description.abstractThe oxidation of aniline with ammonium peroxydisulfate (APS) in aqueous solution of the plant-derived polyphenol, tannic acid, is reported. The effect of initial mole ratios [tannic acid]/[aniline] and [APS]/[aniline] on molecular structure, morphology, conductivity, and electroactivity of synthesized materials (PANI-TA) was investigated by UV-Vis, FTIR, Raman and EPR spectroscopies, scanning and transmission electron microscopies (SEM and TEM), conductivity measurements, and cyclic voltammetry, respectively. PANI-TA nanorods with the average diameter of 70-100 nm and conductivity of 1 x 10(-3) S cm(-1) were synthesized at [tannic acid]/[aniline] = 0.01 and [APS]/[aniline] = 1, while nonconductive, solid microspheres were obtained at [tannic acid]/[aniline] = 0.1 and [APS)[aniline] = 2. The mechanism of the early stages of simultaneous oxidation of aniline and tannic acid has been computationally studied by the RM1/COSMO method.en
dc.publisherElsevier Science Sa, Lausanne
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172043/RS//
dc.rightsrestrictedAccess
dc.sourceSynthetic Metals
dc.subjectCopolymerizationen
dc.subjectAnilineen
dc.subjectTannic aciden
dc.subjectPolyanilineen
dc.subjectNanorodsen
dc.subjectMicrospheresen
dc.titleSimultaneous oxidation of aniline and tannic acid with peroxydisulfate: Self-assembly of oxidation products from nanorods to microspheresen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМарјановић, Будимир; Ћирић-Марјановић, Гордана; Пасти, Игор; Јаношевић, Aлександра; Стејскал, Јарослав; Трифуновић, Снежана; Сљукић-Паунковић, Биљана;
dc.citation.volume162
dc.citation.issue9-10
dc.citation.spage843
dc.citation.epage856
dc.citation.other162(9-10): 843-856
dc.citation.rankM21
dc.identifier.wos000304740400017
dc.identifier.doi10.1016/j.synthmet.2012.03.009
dc.identifier.scopus2-s2.0-84859931754
dc.identifier.rcubconv_2639
dc.type.versionpublishedVersion


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