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Spectrophotometric investigation of the uranil(II)-hesperidin complex in 70% methanol

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Authors
Kuntić, Vesna
Kosanić, M
Malešev, Dušan
Radović, Z
Mioč, Ubavka B.
Article (Published version)
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Abstract
The composition and stability constant of the UO2(II)-hesperidin complex were determined by suitable spectrophotometric methods and pH-metric measurements. II was found that the uranil ion and hesperidin form a 1:2 complex in which the uranil ion is linked to the hesperidin molecule through the carbonyl and the 5-hydroxyl group. The relative stability constant, log K-2, ranged from 5.77 at pH 4.0 to 7.00 at pH 6.0. The conditions for the spectrophotometric determination of hesperidin, by means of reaction of the complex formation reaction, were investigated. Beer's law was obeyed up to 2.0x10(-5) mol dm(-3) hesperidin.
Keywords:
Complex / Hesperidin / Spectrophotometric methods / Uranilnitrate
Source:
Journal of the Serbian Chemical Society, 1998, 63, 7, 565-572
Publisher:
  • Srpsko hemijsko društvo, Beograd

ISSN: 0352-5139

WoS: 000074807300009

Scopus: 2-s2.0-0040115540
[ Google Scholar ]
8
7
Handle
https://hdl.handle.net/21.15107/rcub_farfar_176
URI
https://farfar.pharmacy.bg.ac.rs/handle/123456789/176
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Pharmacy
TY  - JOUR
AU  - Kuntić, Vesna
AU  - Kosanić, M
AU  - Malešev, Dušan
AU  - Radović, Z
AU  - Mioč, Ubavka B.
PY  - 1998
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/176
AB  - The composition and stability constant of the UO2(II)-hesperidin complex were determined by suitable spectrophotometric methods and pH-metric measurements. II was found that the uranil ion and hesperidin form a 1:2 complex in which the uranil ion is linked to the hesperidin molecule through the carbonyl and the 5-hydroxyl group. The relative stability constant, log K-2, ranged from 5.77 at pH 4.0 to 7.00 at pH 6.0. The conditions for the spectrophotometric determination of hesperidin, by means of reaction of the complex formation reaction, were investigated. Beer's law was obeyed up to 2.0x10(-5) mol dm(-3) hesperidin.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Spectrophotometric investigation of the uranil(II)-hesperidin complex in 70% methanol
VL  - 63
IS  - 7
SP  - 565
EP  - 572
UR  - https://hdl.handle.net/21.15107/rcub_farfar_176
ER  - 
@article{
author = "Kuntić, Vesna and Kosanić, M and Malešev, Dušan and Radović, Z and Mioč, Ubavka B.",
year = "1998",
abstract = "The composition and stability constant of the UO2(II)-hesperidin complex were determined by suitable spectrophotometric methods and pH-metric measurements. II was found that the uranil ion and hesperidin form a 1:2 complex in which the uranil ion is linked to the hesperidin molecule through the carbonyl and the 5-hydroxyl group. The relative stability constant, log K-2, ranged from 5.77 at pH 4.0 to 7.00 at pH 6.0. The conditions for the spectrophotometric determination of hesperidin, by means of reaction of the complex formation reaction, were investigated. Beer's law was obeyed up to 2.0x10(-5) mol dm(-3) hesperidin.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Spectrophotometric investigation of the uranil(II)-hesperidin complex in 70% methanol",
volume = "63",
number = "7",
pages = "565-572",
url = "https://hdl.handle.net/21.15107/rcub_farfar_176"
}
Kuntić, V., Kosanić, M., Malešev, D., Radović, Z.,& Mioč, U. B.. (1998). Spectrophotometric investigation of the uranil(II)-hesperidin complex in 70% methanol. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 63(7), 565-572.
https://hdl.handle.net/21.15107/rcub_farfar_176
Kuntić V, Kosanić M, Malešev D, Radović Z, Mioč UB. Spectrophotometric investigation of the uranil(II)-hesperidin complex in 70% methanol. in Journal of the Serbian Chemical Society. 1998;63(7):565-572.
https://hdl.handle.net/21.15107/rcub_farfar_176 .
Kuntić, Vesna, Kosanić, M, Malešev, Dušan, Radović, Z, Mioč, Ubavka B., "Spectrophotometric investigation of the uranil(II)-hesperidin complex in 70% methanol" in Journal of the Serbian Chemical Society, 63, no. 7 (1998):565-572,
https://hdl.handle.net/21.15107/rcub_farfar_176 .

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