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A chemometrics as a powerful tool in the elucidation of the role of metals in the biosynthesis of volatile organic compounds in Hungarian thyme samples
The volatile fraction of the leaves of Thymus pannonicus All. (Lamiaceae) was analyzed by headspace extraction followed by GC-FID and GC-MS analysis. The different headspace profiles were recognized, with citral and with monoterpene hydrocarbons as dominant compounds. In addition, the determination of Cr, Co, Ni, Mo, Cu, Zn, Mn, Fe, Mg, Ca, K and Na was conducted by spectroscopic techniques (FAAS, GFAAS and ICP-OES). In order to evaluate the relationship between volatile organic compounds and metals, a chemometrics approach was applied. The data obtained by analysis of the headspace and elemental content were subjected to correlation analysis, factor analysis, principal component analysis and cluster analysis. A number of significant correlations of metals with plant volatiles were found. Correlation of Zn with citral, Mn with oxygenated monoterpenes and Mg with beta-bourbonene, could be explained by involvement of metals in the biosynthesis of volatile organic compounds.
TY - JOUR
AU - Arsenijević, Jelena
AU - Marković, Jelena
AU - Šoštarić, Ivan
AU - Ražić, Slavica
PY - 2013
UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1843
AB - The volatile fraction of the leaves of Thymus pannonicus All. (Lamiaceae) was analyzed by headspace extraction followed by GC-FID and GC-MS analysis. The different headspace profiles were recognized, with citral and with monoterpene hydrocarbons as dominant compounds. In addition, the determination of Cr, Co, Ni, Mo, Cu, Zn, Mn, Fe, Mg, Ca, K and Na was conducted by spectroscopic techniques (FAAS, GFAAS and ICP-OES). In order to evaluate the relationship between volatile organic compounds and metals, a chemometrics approach was applied. The data obtained by analysis of the headspace and elemental content were subjected to correlation analysis, factor analysis, principal component analysis and cluster analysis. A number of significant correlations of metals with plant volatiles were found. Correlation of Zn with citral, Mn with oxygenated monoterpenes and Mg with beta-bourbonene, could be explained by involvement of metals in the biosynthesis of volatile organic compounds.
PB - Elsevier France-Editions Scientifiques Medicales Elsevier, Paris
T2 - Plant Physiology and Biochemistry
T1 - A chemometrics as a powerful tool in the elucidation of the role of metals in the biosynthesis of volatile organic compounds in Hungarian thyme samples
VL - 71
SP - 298
EP - 306
DO - 10.1016/j.plaphy.2013.08.002
ER -
@article{
author = "Arsenijević, Jelena and Marković, Jelena and Šoštarić, Ivan and Ražić, Slavica",
year = "2013",
abstract = "The volatile fraction of the leaves of Thymus pannonicus All. (Lamiaceae) was analyzed by headspace extraction followed by GC-FID and GC-MS analysis. The different headspace profiles were recognized, with citral and with monoterpene hydrocarbons as dominant compounds. In addition, the determination of Cr, Co, Ni, Mo, Cu, Zn, Mn, Fe, Mg, Ca, K and Na was conducted by spectroscopic techniques (FAAS, GFAAS and ICP-OES). In order to evaluate the relationship between volatile organic compounds and metals, a chemometrics approach was applied. The data obtained by analysis of the headspace and elemental content were subjected to correlation analysis, factor analysis, principal component analysis and cluster analysis. A number of significant correlations of metals with plant volatiles were found. Correlation of Zn with citral, Mn with oxygenated monoterpenes and Mg with beta-bourbonene, could be explained by involvement of metals in the biosynthesis of volatile organic compounds.",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Paris",
journal = "Plant Physiology and Biochemistry",
title = "A chemometrics as a powerful tool in the elucidation of the role of metals in the biosynthesis of volatile organic compounds in Hungarian thyme samples",
volume = "71",
pages = "298-306",
doi = "10.1016/j.plaphy.2013.08.002"
}
Arsenijević, J., Marković, J., Šoštarić, I.,& Ražić, S.. (2013). A chemometrics as a powerful tool in the elucidation of the role of metals in the biosynthesis of volatile organic compounds in Hungarian thyme samples. in Plant Physiology and Biochemistry
Elsevier France-Editions Scientifiques Medicales Elsevier, Paris., 71, 298-306.
https://doi.org/10.1016/j.plaphy.2013.08.002
Arsenijević J, Marković J, Šoštarić I, Ražić S. A chemometrics as a powerful tool in the elucidation of the role of metals in the biosynthesis of volatile organic compounds in Hungarian thyme samples. in Plant Physiology and Biochemistry. 2013;71:298-306.
doi:10.1016/j.plaphy.2013.08.002 .
Arsenijević, Jelena, Marković, Jelena, Šoštarić, Ivan, Ražić, Slavica, "A chemometrics as a powerful tool in the elucidation of the role of metals in the biosynthesis of volatile organic compounds in Hungarian thyme samples" in Plant Physiology and Biochemistry, 71 (2013):298-306,
https://doi.org/10.1016/j.plaphy.2013.08.002 . .
