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dc.creatorTasić, Gordana
dc.creatorSimić, Milena
dc.creatorPopović, Stanimir
dc.creatorHusinec, Suren
dc.creatorMaslak, Veselin
dc.creatorSavić, Vladimir
dc.date.accessioned2019-09-02T11:35:42Z
dc.date.available2019-09-02T11:35:42Z
dc.date.issued2013
dc.identifier.issn0040-4039
dc.identifier.urihttps://farfar.pharmacy.bg.ac.rs/handle/123456789/1973
dc.description.abstractDouble bond migration in N-allylindoles has been investigated as a method to access N-vinyl derivatives of this heterocycle. The optimal reaction conditions employed t-BuOK or NaH in DMSO as the solvent at room temperature to afford the products in yields ranging from 51 to 99%. Although in some cases a high degree of stereoselectivity was observed, preferential formation of either the Z- or E-isomer was not predictable. The developed methodology was employed in the synthesis of (+/-)-debromoarborescidine B.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172009/RS//
dc.rightsrestrictedAccess
dc.sourceTetrahedron-Asymmetry
dc.subjectN-Vinylindolesen
dc.subjectIsomerisationen
dc.subjectBaseen
dc.subjectDebromoarborescidine Ben
dc.titleIndirect N-vinylation of indoles via isomerisation of N-allyl derivatives: synthesis of (+/-)-debromoarborescidine Ben
dc.typearticle
dc.rights.licenseARR
dcterms.abstractТасић, Гордана; Хусинец, Сурен; Симић, Милена; Савић, Владимир; Маслак, Веселин; Поповић, Станимир;
dc.citation.volume54
dc.citation.issue34
dc.citation.spage4536
dc.citation.epage4539
dc.citation.other54(34): 4536-4539
dc.citation.rankM22
dc.identifier.wos000322608000011
dc.identifier.doi10.1016/j.tetlet.2013.06.069
dc.identifier.scopus2-s2.0-84880293280
dc.type.versionpublishedVersion


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