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Progress in conducting/semiconducting and redox-active oligomers and polymers of arylamines

Napredak u istraživanjima provodnih/poluprovodnih i redoks aktivnih oligomera i polimera arilamina

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2013
2033.pdf (591.7Kb)
Authors
Janošević, Aleksandra
Marjanović, Budimir
Rakić, Aleksandra
Ćirić-Marjanović, Gordana
Review (Published version)
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Abstract
Recent advances in synthesis, characterization and application of the selected conducting/semiconducting and redox-active oligomers and polymers of arylamines are reviewed. A brief historical background of the selected topics is given. The overview of the preparation, structure and properties of polyaniline, substituted polyanilines, especially those obtained by the oxidative polymerization of p-substituted anilines, poly(1-aminonaphthalene) and its derivatives, carbocyclic and heterocyclic polyaryldiamines such as poly(p-phenylenediamine) and polydiaminoacridines, is presented. The mechanism of formation of polyaniline nanostructures is discussed. Recent approaches to the preparation of one-dimensional polyaniline nanostructures are concisely reviewed, with special attention paid to the template-free falling-pH method. Current and potential future applications of oligo/polyarylamines are briefly discussed.
U ovom revijalnom radu prikazan je napredak ostvaren u poslednjih nekoliko godina u sintezi, karakterizaciji i primeni nekih provodnih/poluprovodnih i redoks-aktivnih oligomera i polimera arilamina. Dat je kratak prikaz istorijskog razvoja pojedinih oblasti. Predstavljeni su postupci sinteze, struktura i svojstva polianilina, supstituisanih polianilina, posebno onih dobijenih oksidativnom polimerizacijom para-supstituisanih anilina, poli(1-aminonaftalena) i njegovih derivata, karbocikličnih i heterocikličnih poliarildiamina, kao npr. poli(para-fenilendiamina) i polidiaminoakridina. Diskutovan je mehanizam formiranja nanostruktura polianilina. Nedavno razvijeni sintetički postupci za dobijanje jednodimenzionalnih nanostruktura polianilina su koncizno prikazani, a posebna pažnja posvećena je metodama bez templata. Prikazan je i kratak pregled aktuelnih i potencijalnih budućih primena oligo/poliarilamina.
Keywords:
polymer / oligomer / oxidative polymerization / arylamine / polyaniline / nanostructure
Source:
Journal of the Serbian Chemical Society, 2013, 78, 11, 1809-1836
Publisher:
  • Srpsko hemijsko društvo, Beograd
Projects:
  • Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications (RS-172043)

DOI: 10.2298/JSC130809097J

ISSN: 0352-5139

WoS: 000329265400014

Scopus: 2-s2.0-84888081848
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URI
http://farfar.pharmacy.bg.ac.rs/handle/123456789/2035
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  • Radovi istraživača / Researchers’ publications
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Pharmacy

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