Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent
Нема приказа
Аутори
Adaila, KawtherMilenković, Milica
Bacchi, Alessia
Cantoni, Giulia
Swart, Marcel
Gruden-Pavlović, Maja
Milenković, Marina
Cobeljić, Božidar
Todorović, Tamara
Anđelković, Katarina
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.
Кључне речи:
Pd(II) complex / Co(III) complex / Derivative of 2-(diphenylphosphino)benzaldehyde / X-ray structure / DFT calculationsИзвор:
Journal of Coordination Chemistry, 2014, 67, 22, 3633-3648Издавач:
- Taylor & Francis Ltd, Abingdon
Финансирање / пројекти:
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-MESTD-Basic Research (BR or ON)-172055)
- MICINN (Ministry of Science and Innovation, Spain)
- ICREA
Напомена:
- Peer-reviewed manuscript: http://farfar.pharmacy.bg.ac.rs/handle/123456789/3436
DOI: 10.1080/00958972.2014.972389
ISSN: 0095-8972
WoS: 000344865100006
Scopus: 2-s2.0-84941043906
Институција/група
PharmacyTY - JOUR AU - Adaila, Kawther AU - Milenković, Milica AU - Bacchi, Alessia AU - Cantoni, Giulia AU - Swart, Marcel AU - Gruden-Pavlović, Maja AU - Milenković, Marina AU - Cobeljić, Božidar AU - Todorović, Tamara AU - Anđelković, Katarina PY - 2014 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2134 AB - Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent VL - 67 IS - 22 SP - 3633 EP - 3648 DO - 10.1080/00958972.2014.972389 ER -
@article{ author = "Adaila, Kawther and Milenković, Milica and Bacchi, Alessia and Cantoni, Giulia and Swart, Marcel and Gruden-Pavlović, Maja and Milenković, Marina and Cobeljić, Božidar and Todorović, Tamara and Anđelković, Katarina", year = "2014", abstract = "Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent", volume = "67", number = "22", pages = "3633-3648", doi = "10.1080/00958972.2014.972389" }
Adaila, K., Milenković, M., Bacchi, A., Cantoni, G., Swart, M., Gruden-Pavlović, M., Milenković, M., Cobeljić, B., Todorović, T.,& Anđelković, K.. (2014). Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 67(22), 3633-3648. https://doi.org/10.1080/00958972.2014.972389
Adaila K, Milenković M, Bacchi A, Cantoni G, Swart M, Gruden-Pavlović M, Milenković M, Cobeljić B, Todorović T, Anđelković K. Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent. in Journal of Coordination Chemistry. 2014;67(22):3633-3648. doi:10.1080/00958972.2014.972389 .
Adaila, Kawther, Milenković, Milica, Bacchi, Alessia, Cantoni, Giulia, Swart, Marcel, Gruden-Pavlović, Maja, Milenković, Marina, Cobeljić, Božidar, Todorović, Tamara, Anđelković, Katarina, "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent" in Journal of Coordination Chemistry, 67, no. 22 (2014):3633-3648, https://doi.org/10.1080/00958972.2014.972389 . .