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dc.creatorAdaila, Kawther
dc.creatorMilenković, Milica
dc.creatorBacchi, Alessia
dc.creatorCantoni, Giulia
dc.creatorSwart, Marcel
dc.creatorGruden-Pavlović, Maja
dc.creatorMilenković, Marina
dc.creatorCobeljić, Božidar
dc.creatorTodorović, Tamara
dc.creatorAnđelković, Katarina
dc.date.accessioned2019-09-02T11:39:54Z
dc.date.available2019-09-02T11:39:54Z
dc.date.issued2014
dc.identifier.issn0095-8972
dc.identifier.urihttp://farfar.pharmacy.bg.ac.rs/handle/123456789/2134
dc.description.abstractComplexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.en
dc.publisherTaylor & Francis Ltd, Abingdon
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS//
dc.relationMICINN (Ministry of Science and Innovation, Spain)
dc.relationICREA
dc.rightsrestrictedAccess
dc.sourceJournal of Coordination Chemistry
dc.subjectPd(II) complexen
dc.subjectCo(III) complexen
dc.subjectDerivative of 2-(diphenylphosphino)benzaldehydeen
dc.subjectX-ray structureen
dc.subjectDFT calculationsen
dc.titleSynthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagenten
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЦобељић, Божидар; Aнделковић, Катарина; Цантони, Гиулиа; Миленковић, Марина; Груден-Павловић, Маја; Сwарт, Марцел; Тодоровић, Тамара; Баццхи, Aлессиа; Миленковић, Милица; Aдаила, Каwтхер;
dc.citation.volume67
dc.citation.issue22
dc.citation.spage3633
dc.citation.epage3648
dc.citation.other67(22): 3633-3648
dc.citation.rankM22
dc.description.otherPeer-reviewed manuscript: [http://farfar.pharmacy.bg.ac.rs/handle/123456789/3436]
dc.identifier.wos000344865100006
dc.identifier.doi10.1080/00958972.2014.972389
dc.identifier.scopus2-s2.0-84941043906
dc.identifier.rcubconv_3197
dc.type.versionpublishedVersion


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