The temporal dynamics of the Bray-Liebhafsky reaction (iodate-based catalytic decomposition of hydrogen peroxide in an acidic aqueous solution) was experimentally characterized in a continuous stirred tank reactor by independently varying the temperature and the mixed inflow hydrogen peroxide concentration. When the temperature was the bifurcation parameter, the emergence/disappearance of oscillatory behavior via a supercritical Andronov-Hopf bifurcation was observed for different mixed inflow hydrogen peroxide concentrations. An increase in the mixed inflow hydrogen-peroxide concentration resulted in a shift of the bifurcation point towards higher values of temperature, but did not alter the bifurcation type.
TY - JOUR
AU - Pejić, Nataša
AU - Kolar-Anić, Ljiljana
AU - Maksimović, Jelena
AU - Janković, Marija
AU - Vukojević, Vladana
AU - Anić, Slobodan
PY - 2016
UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2528
AB - The temporal dynamics of the Bray-Liebhafsky reaction (iodate-based catalytic decomposition of hydrogen peroxide in an acidic aqueous solution) was experimentally characterized in a continuous stirred tank reactor by independently varying the temperature and the mixed inflow hydrogen peroxide concentration. When the temperature was the bifurcation parameter, the emergence/disappearance of oscillatory behavior via a supercritical Andronov-Hopf bifurcation was observed for different mixed inflow hydrogen peroxide concentrations. An increase in the mixed inflow hydrogen-peroxide concentration resulted in a shift of the bifurcation point towards higher values of temperature, but did not alter the bifurcation type.
PB - Springer, Dordrecht
T2 - Records of Natural Products
T1 - Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation
VL - 118
IS - 1
SP - 15
EP - 26
DO - 10.1007/s11144-016-0984-y
ER -
@article{
author = "Pejić, Nataša and Kolar-Anić, Ljiljana and Maksimović, Jelena and Janković, Marija and Vukojević, Vladana and Anić, Slobodan",
year = "2016",
abstract = "The temporal dynamics of the Bray-Liebhafsky reaction (iodate-based catalytic decomposition of hydrogen peroxide in an acidic aqueous solution) was experimentally characterized in a continuous stirred tank reactor by independently varying the temperature and the mixed inflow hydrogen peroxide concentration. When the temperature was the bifurcation parameter, the emergence/disappearance of oscillatory behavior via a supercritical Andronov-Hopf bifurcation was observed for different mixed inflow hydrogen peroxide concentrations. An increase in the mixed inflow hydrogen-peroxide concentration resulted in a shift of the bifurcation point towards higher values of temperature, but did not alter the bifurcation type.",
publisher = "Springer, Dordrecht",
journal = "Records of Natural Products",
title = "Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation",
volume = "118",
number = "1",
pages = "15-26",
doi = "10.1007/s11144-016-0984-y"
}
Pejić, N., Kolar-Anić, L., Maksimović, J., Janković, M., Vukojević, V.,& Anić, S.. (2016). Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation. in Records of Natural Products
Springer, Dordrecht., 118(1), 15-26.
https://doi.org/10.1007/s11144-016-0984-y
Pejić N, Kolar-Anić L, Maksimović J, Janković M, Vukojević V, Anić S. Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation. in Records of Natural Products. 2016;118(1):15-26.
doi:10.1007/s11144-016-0984-y .
Pejić, Nataša, Kolar-Anić, Ljiljana, Maksimović, Jelena, Janković, Marija, Vukojević, Vladana, Anić, Slobodan, "Dynamic transitions in the Bray-Liebhafsky oscillating reaction. Effect of hydrogen peroxide and temperature on bifurcation" in Records of Natural Products, 118, no. 1 (2016):15-26,
https://doi.org/10.1007/s11144-016-0984-y . .
