In this paper local processes and structural phase transformations of the copper salt of 12-tungstophosphoric acid are investigated. The structural phase transformations were followed through bands, characteristic for the host lattice, in the IR and Raman spectra. The results of these investigations, as well as those of XRPD analysis and impedance measurements as a function of temperature show that some local processes provoke the change in the secondary structure of the Keggin anions.
U ovom radu ispitivani su lokalni procesi i strukturne fazne transformacije soli bakra 12-volframfosforne kiseline. Strukturne fazne transformacije praćene su preko traka karakterističnih za kristalnu rešetku u infracrvenim i ramanskim spektrima. Rezultati ovih ispitivanja, kao i oni dobiveni rendgeno-strukturnom analizom i iz impedansnih merenja, odnosno provodljivost u funkciji temperature, pokazuju da je fazna transformacija vezana za promene lokalne strukture, tj. sekundarne strukture Keginovih anjona. PR Projekat Ministarstva nauke Republike Srbije.
TY - JOUR
AU - Mioč, Ubavka B.
AU - Todorović, Marija R.
AU - Uskoković-Marković, Snežana
AU - Nedić, Zoran P.
AU - Stamenković, Vojislav
AU - Čajkovski, Tamara
PY - 2000
UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/262
AB - In this paper local processes and structural phase transformations of the copper salt of 12-tungstophosphoric acid are investigated. The structural phase transformations were followed through bands, characteristic for the host lattice, in the IR and Raman spectra. The results of these investigations, as well as those of XRPD analysis and impedance measurements as a function of temperature show that some local processes provoke the change in the secondary structure of the Keggin anions.
AB - U ovom radu ispitivani su lokalni procesi i strukturne fazne transformacije soli bakra 12-volframfosforne kiseline. Strukturne fazne transformacije praćene su preko traka karakterističnih za kristalnu rešetku u infracrvenim i ramanskim spektrima. Rezultati ovih ispitivanja, kao i oni dobiveni rendgeno-strukturnom analizom i iz impedansnih merenja, odnosno provodljivost u funkciji temperature, pokazuju da je fazna transformacija vezana za promene lokalne strukture, tj. sekundarne strukture Keginovih anjona. PR Projekat Ministarstva nauke Republike Srbije.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - Structural modifications of Cu(II) 12-tungstophosphoric acid salt studied by IR and Raman spectroscopy
T1 - IR i ramanska ispitivanja strukturnih modifikacija bakarne soli 12-volframfosforne kiseline
VL - 65
IS - 5-6
SP - 407
EP - 415
UR - https://hdl.handle.net/21.15107/rcub_vinar_6292
ER -
@article{
author = "Mioč, Ubavka B. and Todorović, Marija R. and Uskoković-Marković, Snežana and Nedić, Zoran P. and Stamenković, Vojislav and Čajkovski, Tamara",
year = "2000",
abstract = "In this paper local processes and structural phase transformations of the copper salt of 12-tungstophosphoric acid are investigated. The structural phase transformations were followed through bands, characteristic for the host lattice, in the IR and Raman spectra. The results of these investigations, as well as those of XRPD analysis and impedance measurements as a function of temperature show that some local processes provoke the change in the secondary structure of the Keggin anions., U ovom radu ispitivani su lokalni procesi i strukturne fazne transformacije soli bakra 12-volframfosforne kiseline. Strukturne fazne transformacije praćene su preko traka karakterističnih za kristalnu rešetku u infracrvenim i ramanskim spektrima. Rezultati ovih ispitivanja, kao i oni dobiveni rendgeno-strukturnom analizom i iz impedansnih merenja, odnosno provodljivost u funkciji temperature, pokazuju da je fazna transformacija vezana za promene lokalne strukture, tj. sekundarne strukture Keginovih anjona. PR Projekat Ministarstva nauke Republike Srbije.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Structural modifications of Cu(II) 12-tungstophosphoric acid salt studied by IR and Raman spectroscopy, IR i ramanska ispitivanja strukturnih modifikacija bakarne soli 12-volframfosforne kiseline",
volume = "65",
number = "5-6",
pages = "407-415",
url = "https://hdl.handle.net/21.15107/rcub_vinar_6292"
}
Mioč, U. B., Todorović, M. R., Uskoković-Marković, S., Nedić, Z. P., Stamenković, V.,& Čajkovski, T.. (2000). Structural modifications of Cu(II) 12-tungstophosphoric acid salt studied by IR and Raman spectroscopy. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 65(5-6), 407-415.
https://hdl.handle.net/21.15107/rcub_vinar_6292
Mioč UB, Todorović MR, Uskoković-Marković S, Nedić ZP, Stamenković V, Čajkovski T. Structural modifications of Cu(II) 12-tungstophosphoric acid salt studied by IR and Raman spectroscopy. in Journal of the Serbian Chemical Society. 2000;65(5-6):407-415.
https://hdl.handle.net/21.15107/rcub_vinar_6292 .
Mioč, Ubavka B., Todorović, Marija R., Uskoković-Marković, Snežana, Nedić, Zoran P., Stamenković, Vojislav, Čajkovski, Tamara, "Structural modifications of Cu(II) 12-tungstophosphoric acid salt studied by IR and Raman spectroscopy" in Journal of the Serbian Chemical Society, 65, no. 5-6 (2000):407-415,
https://hdl.handle.net/21.15107/rcub_vinar_6292 .
