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dc.creatorKarljiković-Rajić, Katarina
dc.creatorStanković, B
dc.creatorKorićanac, Zagorka
dc.date.accessioned2019-09-02T10:46:38Z
dc.date.available2019-09-02T10:46:38Z
dc.date.issued1987
dc.identifier.issn0365-6233
dc.identifier.urihttp://farfar.pharmacy.bg.ac.rs/handle/123456789/27
dc.description.abstractThe polarographic behavior of 1‐[2‐phenyl‐2‐(hydroxyimino)ethyl]‐6‐methylquinolinium chloride has been investigated. The pH of the Britton‐Robinson buffer, used as supporting electrolyte, influences the position of the half‐wave potential which shifts towards more negative values with increasing pH. Well defined, diffusively controlled cathodic waves were observed in acid medium for the overall irreversible reduction of the azomethine group to a primary amino group. A single four‐electron reduction is obtained and a mechanism has been proposed for the reduction. The ratio id/c remains constant and allows a rapid and reproducible determination of the compound (CV = 0.54–2.10 %).en
dc.rightsrestrictedAccess
dc.sourceArchiv der Pharmazie
dc.titleReduction and Determination of 1‐[2‐Phenyl‐2‐(hydroxyimino)‐ethyl]‐6‐methylquinolinium Chloride on the Dropping Mercury Electrodeen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСтанковић, Б; Корићанац, Загорка; Карљиковић-Рајић, Катарина;
dc.citation.volume320
dc.citation.issue11
dc.citation.spage1095
dc.citation.epage1099
dc.citation.other320(11): 1095-1099
dc.citation.rankM23
dc.identifier.doi10.1002/ardp.198700015
dc.identifier.scopus2-s2.0-27644545205
dc.identifier.rcubconv_5739
dc.type.versionpublishedVersion


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