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Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
Source:
Journal of Coordination Chemistry, 2017, 70, 14, 2425-2435
TY - JOUR
AU - Romanović, Mima C.
AU - Cobeljić, Božidar
AU - Pevec, Andrej
AU - Turel, Iztok
AU - Anđelković, Katarina
AU - Milenković, Marina
AU - Radanović, Dušanka
AU - Belošević, Svetlana
AU - Milenković, Milica
PY - 2017
UR - http://farfar.pharmacy.bg.ac.rs/handle/123456789/2809
AB - Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
PB - Taylor & Francis Ltd, Abingdon
T2 - Journal of Coordination Chemistry
T1 - Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
VL - 70
IS - 14
SP - 2425
EP - 2435
DO - 10.1080/00958972.2017.1343945
ER -
@article{
author = "Romanović, Mima C. and Cobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Anđelković, Katarina and Milenković, Marina and Radanović, Dušanka and Belošević, Svetlana and Milenković, Milica",
year = "2017",
url = "http://farfar.pharmacy.bg.ac.rs/handle/123456789/2809",
abstract = "Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent",
volume = "70",
number = "14",
pages = "2425-2435",
doi = "10.1080/00958972.2017.1343945"
}
Romanović, M. C., Cobeljić, B., Pevec, A., Turel, I., Anđelković, K., Milenković, M., Radanović, D., Belošević, S.,& Milenković, M. (2017). Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent.
Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 70(14), 2425-2435.
https://doi.org/10.1080/00958972.2017.1343945
Romanović MC, Cobeljić B, Pevec A, Turel I, Anđelković K, Milenković M, Radanović D, Belošević S, Milenković M. Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. Journal of Coordination Chemistry. 2017;70(14):2425-2435
Romanović Mima C., Cobeljić Božidar, Pevec Andrej, Turel Iztok, Anđelković Katarina, Milenković Marina, Radanović Dušanka, Belošević Svetlana, Milenković Milica, "Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" Journal of Coordination Chemistry, 70, no. 14 (2017):2425-2435,
https://doi.org/10.1080/00958972.2017.1343945 .
