Pd-catalysed arylation-acetoxylation cascade, a previously reported methodology, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and ss-carboline-derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, the described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.
Source:
Journal of the Serbian Chemical Society, 2017, 82, 12, 1335-1341
TY - JOUR
AU - Simić, Milena
AU - Petković, Miloš
AU - Jovanović, Predrag
AU - Tasić, Gordana
AU - Savić, Vladimir
PY - 2017
UR - http://farfar.pharmacy.bg.ac.rs/handle/123456789/2842
AB - Pd-catalysed arylation-acetoxylation cascade, a previously reported methodology, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and ss-carboline-derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, the described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade
VL - 82
IS - 12
SP - 1335
EP - 1341
DO - 10.2298/JSC170317046S
ER -
@article{
author = "Simić, Milena and Petković, Miloš and Jovanović, Predrag and Tasić, Gordana and Savić, Vladimir",
year = "2017",
url = "http://farfar.pharmacy.bg.ac.rs/handle/123456789/2842",
abstract = "Pd-catalysed arylation-acetoxylation cascade, a previously reported methodology, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and ss-carboline-derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, the described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade",
volume = "82",
number = "12",
pages = "1335-1341",
doi = "10.2298/JSC170317046S"
}
Simić M, Petković M, Jovanović P, Tasić G, Savić V. Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade. Journal of the Serbian Chemical Society. 2017;82(12):1335-1341
Simić, M., Petković, M., Jovanović, P., Tasić, G.,& Savić, V. (2017). Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade.
Journal of the Serbian Chemical SocietySrpsko hemijsko društvo, Beograd., 82(12), 1335-1341.
https://doi.org/10.2298/JSC170317046S
Simić Milena, Petković Miloš, Jovanović Predrag, Tasić Gordana, Savić Vladimir, "Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade" 82, no. 12 (2017):1335-1341,
https://doi.org/10.2298/JSC170317046S .
