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Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade

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2017
2840.pdf (962.6Kb)
Authors
Simić, Milena
Petković, Miloš
Jovanović, Predrag
Tasić, Gordana
Savić, Vladimir
Article (Published version)
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Abstract
Pd-catalysed arylation-acetoxylation cascade, a previously reported methodology, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and ss-carboline-derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, the described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.
Source:
Journal of the Serbian Chemical Society, 2017, 82, 12, 1335-1341
Publisher:
  • Srpsko hemijsko društvo, Beograd
Funding / projects:
  • Computational design, synthesis and biological evaluation of new heterocyclic compounds as selective tumorogenesis inhibitors (RS-172009)

DOI: 10.2298/JSC170317046S

ISSN: 0352-5139

WoS: 000419391700001

Scopus: 2-s2.0-85040055713
[ Google Scholar ]
2
2
URI
https://farfar.pharmacy.bg.ac.rs/handle/123456789/2842
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Pharmacy
TY  - JOUR
AU  - Simić, Milena
AU  - Petković, Miloš
AU  - Jovanović, Predrag
AU  - Tasić, Gordana
AU  - Savić, Vladimir
PY  - 2017
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2842
AB  - Pd-catalysed arylation-acetoxylation cascade, a previously reported methodology, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and ss-carboline-derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, the described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade
VL  - 82
IS  - 12
SP  - 1335
EP  - 1341
DO  - 10.2298/JSC170317046S
UR  - conv_4029
ER  - 
@article{
author = "Simić, Milena and Petković, Miloš and Jovanović, Predrag and Tasić, Gordana and Savić, Vladimir",
year = "2017",
abstract = "Pd-catalysed arylation-acetoxylation cascade, a previously reported methodology, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and ss-carboline-derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, the described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade",
volume = "82",
number = "12",
pages = "1335-1341",
doi = "10.2298/JSC170317046S",
url = "conv_4029"
}
Simić, M., Petković, M., Jovanović, P., Tasić, G.,& Savić, V.. (2017). Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(12), 1335-1341.
https://doi.org/10.2298/JSC170317046S
conv_4029
Simić M, Petković M, Jovanović P, Tasić G, Savić V. Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade. in Journal of the Serbian Chemical Society. 2017;82(12):1335-1341.
doi:10.2298/JSC170317046S
conv_4029 .
Simić, Milena, Petković, Miloš, Jovanović, Predrag, Tasić, Gordana, Savić, Vladimir, "Synthesis of substituted allyl acetates from heterocyclic dienes by a Pd-promoted arylation-acetoxylation cascade" in Journal of the Serbian Chemical Society, 82, no. 12 (2017):1335-1341,
https://doi.org/10.2298/JSC170317046S .,
conv_4029 .

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