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Enzymatic oligomerization and polymerization of arylamines: state of the art and perspectives

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2017
2936.pdf (2.954Mb)
Аутори
Ćirić-Marjanović, Gordana
Milojević-Rakić, Maja
Janošević-Ležaić, Aleksandra
Luginbuhl, Sandra
Walde, Peter
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документу
Апстракт
The literature concerning the oxidative oligomerization and polymerization of various arylamines, e.g., aniline, substituted anilines, aminonaphthalene and its derivatives, catalyzed by oxidoreductases, such as laccases and peroxidases, in aqueous, organic, and mixed aqueous organic monophasic or biphasic media, is reviewed. An overview of template-free as well as template-assisted enzymatic syntheses of oligomers and polymers of arylamines is given. Special attention is paid to mechanistic aspects of these biocatalytic processes. Because of the nontoxicity of oxidoreductases and their high catalytic efficiency, as well as high selectivity of enzymatic oligomerizations/polymerizations under mild conditions-using mainly water as a solvent and often resulting in minimal byproduct formation-enzymatic oligomerizations and polymerizations of arylamines are environmentally friendly and significantly contribute to a "green'' chemistry of conducting and redox-active oligomers and polymers. Cur...rent and potential future applications of enzymatic polymerization processes and enzymatically synthesized oligo/polyarylamines are discussed.

Извор:
Chemical Papers, 2017, 71, 2, 199-242
Издавач:
  • Springer International Publishing Ag, Cham
Финансирање / пројекти:
  • Swiss National Science Foundation (SCOPES Joint Research Project) - IZ73Z0_152457

DOI: 10.1007/s11696-016-0094-3

ISSN: 0366-6352

PubMed: 28775395

WoS: 000394523000004

Scopus: 2-s2.0-85006515744
[ Google Scholar ]
49
38
URI
https://farfar.pharmacy.bg.ac.rs/handle/123456789/2938
Колекције
  • Radovi istraživača / Researchers’ publications
Институција/група
Pharmacy
TY  - JOUR
AU  - Ćirić-Marjanović, Gordana
AU  - Milojević-Rakić, Maja
AU  - Janošević-Ležaić, Aleksandra
AU  - Luginbuhl, Sandra
AU  - Walde, Peter
PY  - 2017
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2938
AB  - The literature concerning the oxidative oligomerization and polymerization of various arylamines, e.g., aniline, substituted anilines, aminonaphthalene and its derivatives, catalyzed by oxidoreductases, such as laccases and peroxidases, in aqueous, organic, and mixed aqueous organic monophasic or biphasic media, is reviewed. An overview of template-free as well as template-assisted enzymatic syntheses of oligomers and polymers of arylamines is given. Special attention is paid to mechanistic aspects of these biocatalytic processes. Because of the nontoxicity of oxidoreductases and their high catalytic efficiency, as well as high selectivity of enzymatic oligomerizations/polymerizations under mild conditions-using mainly water as a solvent and often resulting in minimal byproduct formation-enzymatic oligomerizations and polymerizations of arylamines are environmentally friendly and significantly contribute to a "green'' chemistry of conducting and redox-active oligomers and polymers. Current and potential future applications of enzymatic polymerization processes and enzymatically synthesized oligo/polyarylamines are discussed.
PB  - Springer International Publishing Ag, Cham
T2  - Chemical Papers
T1  - Enzymatic oligomerization and polymerization of arylamines: state of the art and perspectives
VL  - 71
IS  - 2
SP  - 199
EP  - 242
DO  - 10.1007/s11696-016-0094-3
ER  - 
@article{
author = "Ćirić-Marjanović, Gordana and Milojević-Rakić, Maja and Janošević-Ležaić, Aleksandra and Luginbuhl, Sandra and Walde, Peter",
year = "2017",
abstract = "The literature concerning the oxidative oligomerization and polymerization of various arylamines, e.g., aniline, substituted anilines, aminonaphthalene and its derivatives, catalyzed by oxidoreductases, such as laccases and peroxidases, in aqueous, organic, and mixed aqueous organic monophasic or biphasic media, is reviewed. An overview of template-free as well as template-assisted enzymatic syntheses of oligomers and polymers of arylamines is given. Special attention is paid to mechanistic aspects of these biocatalytic processes. Because of the nontoxicity of oxidoreductases and their high catalytic efficiency, as well as high selectivity of enzymatic oligomerizations/polymerizations under mild conditions-using mainly water as a solvent and often resulting in minimal byproduct formation-enzymatic oligomerizations and polymerizations of arylamines are environmentally friendly and significantly contribute to a "green'' chemistry of conducting and redox-active oligomers and polymers. Current and potential future applications of enzymatic polymerization processes and enzymatically synthesized oligo/polyarylamines are discussed.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Chemical Papers",
title = "Enzymatic oligomerization and polymerization of arylamines: state of the art and perspectives",
volume = "71",
number = "2",
pages = "199-242",
doi = "10.1007/s11696-016-0094-3"
}
Ćirić-Marjanović, G., Milojević-Rakić, M., Janošević-Ležaić, A., Luginbuhl, S.,& Walde, P.. (2017). Enzymatic oligomerization and polymerization of arylamines: state of the art and perspectives. in Chemical Papers
Springer International Publishing Ag, Cham., 71(2), 199-242.
https://doi.org/10.1007/s11696-016-0094-3
Ćirić-Marjanović G, Milojević-Rakić M, Janošević-Ležaić A, Luginbuhl S, Walde P. Enzymatic oligomerization and polymerization of arylamines: state of the art and perspectives. in Chemical Papers. 2017;71(2):199-242.
doi:10.1007/s11696-016-0094-3 .
Ćirić-Marjanović, Gordana, Milojević-Rakić, Maja, Janošević-Ležaić, Aleksandra, Luginbuhl, Sandra, Walde, Peter, "Enzymatic oligomerization and polymerization of arylamines: state of the art and perspectives" in Chemical Papers, 71, no. 2 (2017):199-242,
https://doi.org/10.1007/s11696-016-0094-3 . .

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