The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
Keywords:
hydrazone / X-ray structure / magnetic properties / pseudohalides
Source:
Journal of the Serbian Chemical Society, 2018, 83, 12, 1327-1337
TY - JOUR
AU - Cobeljić, Božidar
AU - Pevec, Andrej
AU - Jaglicić, Zvonko
AU - Milenković, Milica
AU - Turel, Iztok
AU - Radanović, Dušanka
AU - Milenković, Marina
AU - Anđelković, Katarina
PY - 2018
UR - http://farfar.pharmacy.bg.ac.rs/handle/123456789/3129
AB - The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex
VL - 83
IS - 12
SP - 1327
EP - 1337
DO - 10.2298/JSC180828079C
ER -
@article{
author = "Cobeljić, Božidar and Pevec, Andrej and Jaglicić, Zvonko and Milenković, Milica and Turel, Iztok and Radanović, Dušanka and Milenković, Marina and Anđelković, Katarina",
year = "2018",
url = "http://farfar.pharmacy.bg.ac.rs/handle/123456789/3129",
abstract = "The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex",
volume = "83",
number = "12",
pages = "1327-1337",
doi = "10.2298/JSC180828079C"
}
Cobeljić, B., Pevec, A., Jaglicić, Z., Milenković, M., Turel, I., Radanović, D., Milenković, M.,& Anđelković, K. (2018). Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex.
Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 83(12), 1327-1337.
https://doi.org/10.2298/JSC180828079C
Cobeljić B, Pevec A, Jaglicić Z, Milenković M, Turel I, Radanović D, Milenković M, Anđelković K. Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. Journal of the Serbian Chemical Society. 2018;83(12):1327-1337
Cobeljić Božidar, Pevec Andrej, Jaglicić Zvonko, Milenković Milica, Turel Iztok, Radanović Dušanka, Milenković Marina, Anđelković Katarina, "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex" Journal of the Serbian Chemical Society, 83, no. 12 (2018):1327-1337,
https://doi.org/10.2298/JSC180828079C .
