Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex
2018
Аутори
Cobeljić, BožidarPevec, Andrej
Jaglicić, Zvonko
Milenković, Milica
Turel, Iztok
Radanović, Dušanka
Milenković, Marina
Anđelković, Katarina
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
Кључне речи:
hydrazone / X-ray structure / magnetic properties / pseudohalidesИзвор:
Journal of the Serbian Chemical Society, 2018, 83, 12, 1327-1337Издавач:
- Srpsko hemijsko društvo, Beograd
Финансирање / пројекти:
DOI: 10.2298/JSC180828079C
ISSN: 0352-5139
WoS: 000454508900004
Scopus: 2-s2.0-85059303962
Институција/група
PharmacyTY - JOUR AU - Cobeljić, Božidar AU - Pevec, Andrej AU - Jaglicić, Zvonko AU - Milenković, Milica AU - Turel, Iztok AU - Radanović, Dušanka AU - Milenković, Marina AU - Anđelković, Katarina PY - 2018 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/3129 AB - The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs. PB - Srpsko hemijsko društvo, Beograd T2 - Journal of the Serbian Chemical Society T1 - Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex VL - 83 IS - 12 SP - 1327 EP - 1337 DO - 10.2298/JSC180828079C ER -
@article{ author = "Cobeljić, Božidar and Pevec, Andrej and Jaglicić, Zvonko and Milenković, Milica and Turel, Iztok and Radanović, Dušanka and Milenković, Marina and Anđelković, Katarina", year = "2018", abstract = "The isothiocyanato Fe(III) complex with (E)-N, N, N-trimethyl-2-oxo- 2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.", publisher = "Srpsko hemijsko društvo, Beograd", journal = "Journal of the Serbian Chemical Society", title = "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex", volume = "83", number = "12", pages = "1327-1337", doi = "10.2298/JSC180828079C" }
Cobeljić, B., Pevec, A., Jaglicić, Z., Milenković, M., Turel, I., Radanović, D., Milenković, M.,& Anđelković, K.. (2018). Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. in Journal of the Serbian Chemical Society Srpsko hemijsko društvo, Beograd., 83(12), 1327-1337. https://doi.org/10.2298/JSC180828079C
Cobeljić B, Pevec A, Jaglicić Z, Milenković M, Turel I, Radanović D, Milenković M, Anđelković K. Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex. in Journal of the Serbian Chemical Society. 2018;83(12):1327-1337. doi:10.2298/JSC180828079C .
Cobeljić, Božidar, Pevec, Andrej, Jaglicić, Zvonko, Milenković, Milica, Turel, Iztok, Radanović, Dušanka, Milenković, Marina, Anđelković, Katarina, "Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard's T hydrazone complex" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1327-1337, https://doi.org/10.2298/JSC180828079C . .