Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
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AuthorsRomanović, Mima C.
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Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
Source:Journal of Coordination Chemistry, 2017, 70, 14, 2425-2435
- Taylor & Francis Ltd, Abingdon
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
- This is peer-reviewed version of the following article: Romanović, M. Č.; Čobeljić, B.; Pevec, A.; Turel, I.; Anđelković, K.; Milenković, M.; Radanović, D.; Belošević, S.; Milenković, M. R. Synthesis, Crystal Structures and Antimicrobial Activity of Azido and Isocyanato Zn(II) Complexes with the Condensation Product of 2-Quinolinecarboxaldehyde and Girard’s T Reagent. J. Coord. Chem. 2017, 70 (14), 2425–2435. https://doi.org/10.1080/00958972.2017.1343945