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Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .
Izvor:
Journal of Coordination Chemistry, 2017, 70, 21, 3702-3714
This is peer-reviewed version of the following article: Romanović, M. Č.; Čobeljić, B.; Pevec, A.; Turel, I.; Grubišić, S.; Radanović, D.; Anđelković, K.; Milenković, M.; Milenković, M. R. Synthesis, Characterization, DFT Calculations and Antimicrobial Activity of Cd(II) Complexes with the Condensation Product of 2-Quinolinecarboxaldehyde and Girard’s T Reagent. J. Coord. Chem. 2017, 70 (21), 3702–3714. https://doi.org/10.1080/00958972.2017.1405262
TY - JOUR
AU - Romanović, Mima C.
AU - Cobeljić, Božidar
AU - Pevec, Andrej
AU - Turel, Iztok
AU - Grubisić, Sonja
AU - Radanović, Dušanka
AU - Anđelković, Katarina
AU - Milenković, Marina
AU - Milenković, Milica
PY - 2017
UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/3425
AB - The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .
PB - Taylor & Francis Ltd, Abingdon
T2 - Journal of Coordination Chemistry
T1 - Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
VL - 70
IS - 21
SP - 3702
EP - 3714
DO - 10.1080/00958972.2017.1405262
ER -
@article{
author = "Romanović, Mima C. and Cobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Grubisić, Sonja and Radanović, Dušanka and Anđelković, Katarina and Milenković, Marina and Milenković, Milica",
year = "2017",
abstract = "The chloro (1) and isocyanato (2) Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been synthesized and characterized by elemental analysis, IR, and NMR spectroscopy. The crystal structure of chloro Cd(II) complex (1) was determined. In 1 and 2, coordination surrounding of Cd(II) consists of deprotonated hydrazone ligand coordinated through NNO-donor atoms and two monodentates at the rest of the coordination places. Quantum chemical calculations of the molecular structures and the relative stabilities of linkage isomers of the Cd(II) complex showed that the isomer with N-Cd-N coordination of OCN- is the most stable. The investigated Cd(II) complexes showed lower activity than standard antimicrobial drugs. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent",
volume = "70",
number = "21",
pages = "3702-3714",
doi = "10.1080/00958972.2017.1405262"
}
Romanović, M. C., Cobeljić, B., Pevec, A., Turel, I., Grubisić, S., Radanović, D., Anđelković, K., Milenković, M.,& Milenković, M.. (2017). Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 70(21), 3702-3714.
https://doi.org/10.1080/00958972.2017.1405262
Romanović MC, Cobeljić B, Pevec A, Turel I, Grubisić S, Radanović D, Anđelković K, Milenković M, Milenković M. Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Journal of Coordination Chemistry. 2017;70(21):3702-3714.
doi:10.1080/00958972.2017.1405262 .
Romanović, Mima C., Cobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Grubisić, Sonja, Radanović, Dušanka, Anđelković, Katarina, Milenković, Marina, Milenković, Milica, "Synthesis, characterization, DFT calculations and antimicrobial activity of Cd(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Journal of Coordination Chemistry, 70, no. 21 (2017):3702-3714,
https://doi.org/10.1080/00958972.2017.1405262 . .
