MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination
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2022
Authors
Milojević-Rakić, Maja
Popadić, Daliborka
Janošević-Ležaić, Aleksandra

Jevremović, Anka

Nedić-Vasiljević, Bojana

Uskoković-Marković, Snežana

Bajuk-Bogdanović, Danica

Article (Published version)

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Ecotoxicity caused by neonicotinoid pesticides is largely due to oxidative stress on non-target species. Due to the fact that reactive radical species reach the environment, materials intended for pesticide removal should be applicable for the simultaneous removal of reactive radicals, as well. This work uses the spectroscopic, adsorptive and antioxidant responses from MFI, FAU and BEA zeolites as descriptors of their potential environmental importance. Different network structures and Si/Al ratios were correlated with excellent zeolite adsorption properties, as over 200 mg g1 of investigated neonicotinoids, acetamiprid and imidacloprid, was achieved in one cycle. Additionally, after two regeneration steps, over 450 mg g1 adsorbed pesticides were retained, in three adsorption cycles. Overall the best results were detected for the FAU zeotype in both tested applications, insecticide adsorption and radical-scavenging performance, with and without insecticides present. The proposed mechan...ism for adsorption relies on kinetic investigation, isotherm modelling and spectroscopic post-adsorption analysis and targets zeolite hydroxyl/siloxane groups as active sites for insecticide adsorption via hydrogen bonding. Neat, welldefined zeolite structures enable their prospective application in ecotoxic species removal.
Source:
Environmental science. Processes & impacts, 2022, 24, 2, 265-276Publisher:
- The Royal Society of Chemistry
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-200146)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200161 (University of Belgrade, Faculty of Pharmacy) (RS-200161)
DOI: 10.1039/d1em00437a
ISSN: 2050-7887
WoS: 000743164500001
Scopus: 2-s2.0-85125211909
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Institution/Community
PharmacyTY - JOUR AU - Milojević-Rakić, Maja AU - Popadić, Daliborka AU - Janošević-Ležaić, Aleksandra AU - Jevremović, Anka AU - Nedić-Vasiljević, Bojana AU - Uskoković-Marković, Snežana AU - Bajuk-Bogdanović, Danica PY - 2022 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/4062 AB - Ecotoxicity caused by neonicotinoid pesticides is largely due to oxidative stress on non-target species. Due to the fact that reactive radical species reach the environment, materials intended for pesticide removal should be applicable for the simultaneous removal of reactive radicals, as well. This work uses the spectroscopic, adsorptive and antioxidant responses from MFI, FAU and BEA zeolites as descriptors of their potential environmental importance. Different network structures and Si/Al ratios were correlated with excellent zeolite adsorption properties, as over 200 mg g1 of investigated neonicotinoids, acetamiprid and imidacloprid, was achieved in one cycle. Additionally, after two regeneration steps, over 450 mg g1 adsorbed pesticides were retained, in three adsorption cycles. Overall the best results were detected for the FAU zeotype in both tested applications, insecticide adsorption and radical-scavenging performance, with and without insecticides present. The proposed mechanism for adsorption relies on kinetic investigation, isotherm modelling and spectroscopic post-adsorption analysis and targets zeolite hydroxyl/siloxane groups as active sites for insecticide adsorption via hydrogen bonding. Neat, welldefined zeolite structures enable their prospective application in ecotoxic species removal. PB - The Royal Society of Chemistry T2 - Environmental science. Processes & impacts T1 - MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination VL - 24 IS - 2 SP - 265 EP - 276 DO - 10.1039/d1em00437a ER -
@article{ author = "Milojević-Rakić, Maja and Popadić, Daliborka and Janošević-Ležaić, Aleksandra and Jevremović, Anka and Nedić-Vasiljević, Bojana and Uskoković-Marković, Snežana and Bajuk-Bogdanović, Danica", year = "2022", abstract = "Ecotoxicity caused by neonicotinoid pesticides is largely due to oxidative stress on non-target species. Due to the fact that reactive radical species reach the environment, materials intended for pesticide removal should be applicable for the simultaneous removal of reactive radicals, as well. This work uses the spectroscopic, adsorptive and antioxidant responses from MFI, FAU and BEA zeolites as descriptors of their potential environmental importance. Different network structures and Si/Al ratios were correlated with excellent zeolite adsorption properties, as over 200 mg g1 of investigated neonicotinoids, acetamiprid and imidacloprid, was achieved in one cycle. Additionally, after two regeneration steps, over 450 mg g1 adsorbed pesticides were retained, in three adsorption cycles. Overall the best results were detected for the FAU zeotype in both tested applications, insecticide adsorption and radical-scavenging performance, with and without insecticides present. The proposed mechanism for adsorption relies on kinetic investigation, isotherm modelling and spectroscopic post-adsorption analysis and targets zeolite hydroxyl/siloxane groups as active sites for insecticide adsorption via hydrogen bonding. Neat, welldefined zeolite structures enable their prospective application in ecotoxic species removal.", publisher = "The Royal Society of Chemistry", journal = "Environmental science. Processes & impacts", title = "MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination", volume = "24", number = "2", pages = "265-276", doi = "10.1039/d1em00437a" }
Milojević-Rakić, M., Popadić, D., Janošević-Ležaić, A., Jevremović, A., Nedić-Vasiljević, B., Uskoković-Marković, S.,& Bajuk-Bogdanović, D.. (2022). MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination. in Environmental science. Processes & impacts The Royal Society of Chemistry., 24(2), 265-276. https://doi.org/10.1039/d1em00437a
Milojević-Rakić M, Popadić D, Janošević-Ležaić A, Jevremović A, Nedić-Vasiljević B, Uskoković-Marković S, Bajuk-Bogdanović D. MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination. in Environmental science. Processes & impacts. 2022;24(2):265-276. doi:10.1039/d1em00437a .
Milojević-Rakić, Maja, Popadić, Daliborka, Janošević-Ležaić, Aleksandra, Jevremović, Anka, Nedić-Vasiljević, Bojana, Uskoković-Marković, Snežana, Bajuk-Bogdanović, Danica, "MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination" in Environmental science. Processes & impacts, 24, no. 2 (2022):265-276, https://doi.org/10.1039/d1em00437a . .