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New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands

Authorized Users Only
2022
Authors
Antonijević Nikolić, Mirjana
Dražić, Branka
Tanasković, Slađana
Conference object (Published version)
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Abstract
Two new bridged dinuclear Cu(II) compounds of tpmc (N,N',N'',N'''-tetrakis(2-pyridylmethyl)- 1,4,8,11-tetraazacyclotetradecane) and co-ligands L-leucine or L-isoleucine have been synthesized and characterized. The complexes were prepared in the reaction [Cutpmc](ClO4)4∙6H2O and aminocarboxylates. The complexes were characterized by elemental analysis (C, H, and N), molar electrical conductivity and spectral methods (UV/vis and FTIR). The analytical data of the complexes show the formation of binuclear complexes with the proposed formula [Cu2(L)tpmc](ClO4)4, L=L- leucine (1) and L=L-isoleucine (2). The spectroscopic data suggested that the tpmc is coordinated to Cu(II) through eight N donors and amino carboxylate ligands via their carboxylate ion moieties.
Source:
PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia, 2022, II, 519-522
Publisher:
  • Society of Physical Chemists of Serbia
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200161 (University of Belgrade, Faculty of Pharmacy) (RS-200161)

ISBN: 978-53-82475-43-9

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_farfar_4374
URI
https://farfar.pharmacy.bg.ac.rs/handle/123456789/4374
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Pharmacy
TY  - CONF
AU  - Antonijević Nikolić, Mirjana
AU  - Dražić, Branka
AU  - Tanasković, Slađana
PY  - 2022
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/4374
AB  - Two new bridged dinuclear Cu(II) compounds of tpmc (N,N',N'',N'''-tetrakis(2-pyridylmethyl)-
1,4,8,11-tetraazacyclotetradecane) and co-ligands L-leucine or L-isoleucine have been synthesized
and characterized. The complexes were prepared in the reaction [Cutpmc](ClO4)4∙6H2O and
aminocarboxylates. The complexes were characterized by elemental analysis (C, H, and N), molar
electrical conductivity and spectral methods (UV/vis and FTIR). The analytical data of the complexes
show the formation of binuclear complexes with the proposed formula [Cu2(L)tpmc](ClO4)4, L=L-
leucine (1) and L=L-isoleucine (2). The spectroscopic data suggested that the tpmc is coordinated to
Cu(II) through eight N donors and amino carboxylate ligands via their carboxylate ion moieties.
PB  - Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia
T1  - New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands
VL  - II
SP  - 519
EP  - 522
UR  - https://hdl.handle.net/21.15107/rcub_farfar_4374
ER  - 
@conference{
author = "Antonijević Nikolić, Mirjana and Dražić, Branka and Tanasković, Slađana",
year = "2022",
abstract = "Two new bridged dinuclear Cu(II) compounds of tpmc (N,N',N'',N'''-tetrakis(2-pyridylmethyl)-
1,4,8,11-tetraazacyclotetradecane) and co-ligands L-leucine or L-isoleucine have been synthesized
and characterized. The complexes were prepared in the reaction [Cutpmc](ClO4)4∙6H2O and
aminocarboxylates. The complexes were characterized by elemental analysis (C, H, and N), molar
electrical conductivity and spectral methods (UV/vis and FTIR). The analytical data of the complexes
show the formation of binuclear complexes with the proposed formula [Cu2(L)tpmc](ClO4)4, L=L-
leucine (1) and L=L-isoleucine (2). The spectroscopic data suggested that the tpmc is coordinated to
Cu(II) through eight N donors and amino carboxylate ligands via their carboxylate ion moieties.",
publisher = "Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia",
title = "New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands",
volume = "II",
pages = "519-522",
url = "https://hdl.handle.net/21.15107/rcub_farfar_4374"
}
Antonijević Nikolić, M., Dražić, B.,& Tanasković, S.. (2022). New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands. in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia
Society of Physical Chemists of Serbia., II, 519-522.
https://hdl.handle.net/21.15107/rcub_farfar_4374
Antonijević Nikolić M, Dražić B, Tanasković S. New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands. in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia. 2022;II:519-522.
https://hdl.handle.net/21.15107/rcub_farfar_4374 .
Antonijević Nikolić, Mirjana, Dražić, Branka, Tanasković, Slađana, "New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands" in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia, II (2022):519-522,
https://hdl.handle.net/21.15107/rcub_farfar_4374 .

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