Two new bridged dinuclear Cu(II) compounds of tpmc (N,N',N'',N'''-tetrakis(2-pyridylmethyl)-
1,4,8,11-tetraazacyclotetradecane) and co-ligands L-leucine or L-isoleucine have been synthesized
and characterized. The complexes were prepared in the reaction [Cutpmc](ClO4)4∙6H2O and
aminocarboxylates. The complexes were characterized by elemental analysis (C, H, and N), molar
electrical conductivity and spectral methods (UV/vis and FTIR). The analytical data of the complexes
show the formation of binuclear complexes with the proposed formula [Cu2(L)tpmc](ClO4)4, L=L-
leucine (1) and L=L-isoleucine (2). The spectroscopic data suggested that the tpmc is coordinated to
Cu(II) through eight N donors and amino carboxylate ligands via their carboxylate ion moieties.
Source:
PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia, 2022, II, 519-522
TY - CONF
AU - Antonijević Nikolić, Mirjana
AU - Dražić, Branka
AU - Tanasković, Slađana
PY - 2022
UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/4374
AB - Two new bridged dinuclear Cu(II) compounds of tpmc (N,N',N'',N'''-tetrakis(2-pyridylmethyl)-
1,4,8,11-tetraazacyclotetradecane) and co-ligands L-leucine or L-isoleucine have been synthesized
and characterized. The complexes were prepared in the reaction [Cutpmc](ClO4)4∙6H2O and
aminocarboxylates. The complexes were characterized by elemental analysis (C, H, and N), molar
electrical conductivity and spectral methods (UV/vis and FTIR). The analytical data of the complexes
show the formation of binuclear complexes with the proposed formula [Cu2(L)tpmc](ClO4)4, L=L-
leucine (1) and L=L-isoleucine (2). The spectroscopic data suggested that the tpmc is coordinated to
Cu(II) through eight N donors and amino carboxylate ligands via their carboxylate ion moieties.
PB - Society of Physical Chemists of Serbia
C3 - PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia
T1 - New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands
VL - II
SP - 519
EP - 522
UR - https://hdl.handle.net/21.15107/rcub_farfar_4374
ER -
@conference{
author = "Antonijević Nikolić, Mirjana and Dražić, Branka and Tanasković, Slađana",
year = "2022",
abstract = "Two new bridged dinuclear Cu(II) compounds of tpmc (N,N',N'',N'''-tetrakis(2-pyridylmethyl)-
1,4,8,11-tetraazacyclotetradecane) and co-ligands L-leucine or L-isoleucine have been synthesized
and characterized. The complexes were prepared in the reaction [Cutpmc](ClO4)4∙6H2O and
aminocarboxylates. The complexes were characterized by elemental analysis (C, H, and N), molar
electrical conductivity and spectral methods (UV/vis and FTIR). The analytical data of the complexes
show the formation of binuclear complexes with the proposed formula [Cu2(L)tpmc](ClO4)4, L=L-
leucine (1) and L=L-isoleucine (2). The spectroscopic data suggested that the tpmc is coordinated to
Cu(II) through eight N donors and amino carboxylate ligands via their carboxylate ion moieties.",
publisher = "Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia",
title = "New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands",
volume = "II",
pages = "519-522",
url = "https://hdl.handle.net/21.15107/rcub_farfar_4374"
}
Antonijević Nikolić, M., Dražić, B.,& Tanasković, S.. (2022). New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands. in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia
Society of Physical Chemists of Serbia., II, 519-522.
https://hdl.handle.net/21.15107/rcub_farfar_4374
Antonijević Nikolić M, Dražić B, Tanasković S. New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands. in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia. 2022;II:519-522.
https://hdl.handle.net/21.15107/rcub_farfar_4374 .
Antonijević Nikolić, Mirjana, Dražić, Branka, Tanasković, Slađana, "New macrocyclic Cu(II) complexes with leucine/isoleucine co-ligands" in PHYSICAL CHEMISTRY 2022, 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Proceedings, September 26-30, 2022 Belgrade, Serbia, II (2022):519-522,
https://hdl.handle.net/21.15107/rcub_farfar_4374 .
