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Thermodynamic stability constants of complexes of Fe(III)-ion with orciprenaline and phenylephrine
Termodinamičke konstante stabilnosti kompleksa Fe(III)-jona sa orciprenalinom i fenilefrinom
dc.creator | Pavun, Leposava | |
dc.creator | Malešev, Dušan | |
dc.creator | Veselinović, Dragan S. | |
dc.date.accessioned | 2019-09-02T10:57:23Z | |
dc.date.available | 2019-09-02T10:57:23Z | |
dc.date.issued | 2003 | |
dc.identifier.issn | 0004-1963 | |
dc.identifier.uri | https://farfar.pharmacy.bg.ac.rs/handle/123456789/449 | |
dc.description.abstract | The concentration stability constants of Fe(III)-orciprenaline complex and Fe(III)-phenylephrine complex were calculated for three different ionic strengths, by modificated Bjerrum's method. The values of thermodynamic stability constants are determined from curve log β = f (I1/2), as interception at ordinate. From the determined thermodynamic stability constants logβ10 =8,28 and logβ02 = 16,24 of the complexes investigated, the values of the ∆G10= - 46,87 kJ/mol and, AG° = -92,76 kJ/mol were calculated for Fe(III)-orciprenaline and Fe(III)- phenylephrine complexes respectively. | en |
dc.description.abstract | Za komplekse Fe(III)-fenilefrin i Fe(III)-orciprenalin određene su vrednosti koncentracionih konstanti stabilnosti na tri jonske jačine (0,024; 0,050 0,075 mol/dm3). Na osnovu ovih vrednosti izračunate su termodinamičke konstante stabilnosti ovih kompleksa ekstrapolacijom dijagrama logβn=f(I) na vrednost I=0. Dobijena vrednost za kompleks Fe(III)-fenilefrin je logβ0 2 = 16,24, a za kompleks Fe(III)-orciprenalin ona iznosi logβ10= 8,28. Izračunate su promene standardne Gibbsove energije za reakciju stvaranja kompleksa: ∆G1°= -46,87 kJ/mol za Fe(III)- orciprenalin i ∆G°2 = -92,76 kJ/mol za Fe(III)-fenilefrin. | sr |
dc.publisher | Savez farmaceutskih udruženja Srbije, Beograd | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-sa/4.0/ | |
dc.source | Arhiv za farmaciju | |
dc.subject | complex | en |
dc.subject | Fe(III)- ion | en |
dc.subject | phenylephrine | en |
dc.subject | orciprenaline | en |
dc.subject | thermodynamic stability constant | en |
dc.subject | kompleks | sr |
dc.subject | Fe(III) jon | sr |
dc.subject | fenilefrin | sr |
dc.subject | orciprenalin | sr |
dc.subject | termodinamička konstanta stabilnosti | sr |
dc.title | Thermodynamic stability constants of complexes of Fe(III)-ion with orciprenaline and phenylephrine | en |
dc.title | Termodinamičke konstante stabilnosti kompleksa Fe(III)-jona sa orciprenalinom i fenilefrinom | sr |
dc.type | article | |
dc.rights.license | BY-SA | |
dcterms.abstract | Малешев, Душан; Павун, Лепосава; Веселиновић, Драган С.; Термодинамичке константе стабилности комплекса Фе(ИИИ)-јона са орципреналином и фенилефрином; Термодинамичке константе стабилности комплекса Фе(ИИИ)-јона са орципреналином и фенилефрином; | |
dc.citation.volume | 53 | |
dc.citation.issue | 1-2 | |
dc.citation.spage | 27 | |
dc.citation.epage | 36 | |
dc.citation.other | 53(1-2): 27-36 | |
dc.identifier.fulltext | https://farfar.pharmacy.bg.ac.rs//bitstream/id/1979/447.pdf | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_farfar_449 | |
dc.type.version | publishedVersion |