Theoretical and empirical models in hydrophilic interaction liquid chromatography
Samo za registrovane korisnike
2014
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Hydrophilic interaction liquid chromatography (HILIC) has found application in the determination of polar molecules. This alternative type of chromatography has become increasingly popular in the last five years and a considerable number of articles regarding the elucidation of its retention mechanisms and the development of methods are available. In order to achieve these goals, various types of theoretical and empirical mathematical models were utilized. However, the knowledge obtained from these models was the subject of various interpretations. The goal of this article is to list and discuss the papers in which these models were used in HILIC and give proper theoretical background of the models. In general, theoretical models in HILIC were applied in order to acquire the knowledge of dominant processes in the retention mechanism, retention prediction, and quantitative description of the influence of mobile phase-related factors on the retention and selectivity of the analytes on di...fferent types of stationary phases. In addition, empirical models were used for detailed assessment of the retention behavior in terms of both single factor and factor interactions influence on analyte retention and selectivity. Furthermore, they have also shown a great potential in the optimization of HILIC methods in the method development process.
Ključne reči:
factor influence / hydrophilic interaction liquid chromatography / quantitative structure retention relationships / temperature effects / retention mechanisms / experimental designIzvor:
Instrumentation Science & Technology, 2014, 42, 3, 230-266Izdavač:
- Taylor & Francis Inc, Philadelphia
Finansiranje / projekti:
- Modelovanje različitih hromatografskih sistema sa hemometrijskim pristupom u farmaceutskoj analizi (RS-MESTD-Basic Research (BR or ON)-172052)
DOI: 10.1080/10739149.2013.865214
ISSN: 1073-9149
WoS: 000333935300002
Scopus: 2-s2.0-84896793512
Institucija/grupa
PharmacyTY - JOUR AU - Jovanović, Marko AU - Rakić, Tijana AU - Jančić-Stojanović, Biljana PY - 2014 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/2151 AB - Hydrophilic interaction liquid chromatography (HILIC) has found application in the determination of polar molecules. This alternative type of chromatography has become increasingly popular in the last five years and a considerable number of articles regarding the elucidation of its retention mechanisms and the development of methods are available. In order to achieve these goals, various types of theoretical and empirical mathematical models were utilized. However, the knowledge obtained from these models was the subject of various interpretations. The goal of this article is to list and discuss the papers in which these models were used in HILIC and give proper theoretical background of the models. In general, theoretical models in HILIC were applied in order to acquire the knowledge of dominant processes in the retention mechanism, retention prediction, and quantitative description of the influence of mobile phase-related factors on the retention and selectivity of the analytes on different types of stationary phases. In addition, empirical models were used for detailed assessment of the retention behavior in terms of both single factor and factor interactions influence on analyte retention and selectivity. Furthermore, they have also shown a great potential in the optimization of HILIC methods in the method development process. PB - Taylor & Francis Inc, Philadelphia T2 - Instrumentation Science & Technology T1 - Theoretical and empirical models in hydrophilic interaction liquid chromatography VL - 42 IS - 3 SP - 230 EP - 266 DO - 10.1080/10739149.2013.865214 ER -
@article{ author = "Jovanović, Marko and Rakić, Tijana and Jančić-Stojanović, Biljana", year = "2014", abstract = "Hydrophilic interaction liquid chromatography (HILIC) has found application in the determination of polar molecules. This alternative type of chromatography has become increasingly popular in the last five years and a considerable number of articles regarding the elucidation of its retention mechanisms and the development of methods are available. In order to achieve these goals, various types of theoretical and empirical mathematical models were utilized. However, the knowledge obtained from these models was the subject of various interpretations. The goal of this article is to list and discuss the papers in which these models were used in HILIC and give proper theoretical background of the models. In general, theoretical models in HILIC were applied in order to acquire the knowledge of dominant processes in the retention mechanism, retention prediction, and quantitative description of the influence of mobile phase-related factors on the retention and selectivity of the analytes on different types of stationary phases. In addition, empirical models were used for detailed assessment of the retention behavior in terms of both single factor and factor interactions influence on analyte retention and selectivity. Furthermore, they have also shown a great potential in the optimization of HILIC methods in the method development process.", publisher = "Taylor & Francis Inc, Philadelphia", journal = "Instrumentation Science & Technology", title = "Theoretical and empirical models in hydrophilic interaction liquid chromatography", volume = "42", number = "3", pages = "230-266", doi = "10.1080/10739149.2013.865214" }
Jovanović, M., Rakić, T.,& Jančić-Stojanović, B.. (2014). Theoretical and empirical models in hydrophilic interaction liquid chromatography. in Instrumentation Science & Technology Taylor & Francis Inc, Philadelphia., 42(3), 230-266. https://doi.org/10.1080/10739149.2013.865214
Jovanović M, Rakić T, Jančić-Stojanović B. Theoretical and empirical models in hydrophilic interaction liquid chromatography. in Instrumentation Science & Technology. 2014;42(3):230-266. doi:10.1080/10739149.2013.865214 .
Jovanović, Marko, Rakić, Tijana, Jančić-Stojanović, Biljana, "Theoretical and empirical models in hydrophilic interaction liquid chromatography" in Instrumentation Science & Technology, 42, no. 3 (2014):230-266, https://doi.org/10.1080/10739149.2013.865214 . .