Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials
Само за регистроване кориснике
2020
Аутори
Jakšić, JovanaOstojić, Sanja
Micić, Darko
Tokić-Vujošević, Zorana
Milovanović, Jelena
Karkalić, Radovan
O'Connor, Kevin E.
Kenny, Shane T.
Casey, William
Nikodinović-Runić, Jasmina
Maslak, Veselin
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33°C to 66°C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schröder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoa...tes also showed potential to be applied in development of PCMs.
Кључне речи:
biopolymer / 3-hydroxy fatty acids / eutectic mixtures / phase change materials / thermophysical propertiesИзвор:
International Journal of Energy Research, 2020, 44, 2, 1294-1302Издавач:
- John Wiley & Sons, Ltd.
Финансирање / пројекти:
- Дизајн, синтеза и испитивање наномолекулских машина на бази фулерена (RS-172002)
- Bioplastech BP2017
DOI: 10.1002/er.4934
ISSN: 0363-907X
WoS: 000495538000001
Scopus: 2-s2.0-85075197383
Институција/група
PharmacyTY - JOUR AU - Jakšić, Jovana AU - Ostojić, Sanja AU - Micić, Darko AU - Tokić-Vujošević, Zorana AU - Milovanović, Jelena AU - Karkalić, Radovan AU - O'Connor, Kevin E. AU - Kenny, Shane T. AU - Casey, William AU - Nikodinović-Runić, Jasmina AU - Maslak, Veselin PY - 2020 UR - https://farfar.pharmacy.bg.ac.rs/handle/123456789/3534 AB - In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33°C to 66°C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schröder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs. PB - John Wiley & Sons, Ltd. T2 - International Journal of Energy Research T1 - Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials VL - 44 IS - 2 SP - 1294 EP - 1302 DO - 10.1002/er.4934 ER -
@article{ author = "Jakšić, Jovana and Ostojić, Sanja and Micić, Darko and Tokić-Vujošević, Zorana and Milovanović, Jelena and Karkalić, Radovan and O'Connor, Kevin E. and Kenny, Shane T. and Casey, William and Nikodinović-Runić, Jasmina and Maslak, Veselin", year = "2020", abstract = "In the present work, we describe the chemical synthesis of 3-HFAs as prominent derivatives of fatty acids and assess if they could be applied as phase change materials (PCM). In addition, 3-HFAs were obtained by depolymerization of a bacterial biopolymeric material, polyhydroxyalkanoate. Thermal properties of 3-hydoxyoctanoic, decanoic, and dodecanoic acids are reported for the first time. These materials showed the potential to be applied as PCM in temperature range from 33°C to 66°C. In order to expand the temperature range for application of 3-HFAs as PCM, eutectic mass ratios of three kinds of binary mixtures of 3-HFAs were calculated, and their properties were predicted using the Schröder-van Laar equation. Thermal properties of these mixtures were validated by differential scanning calorimetry (DSC) analysis. These results showed that eutectics considerably expanded the scope of applications of 3-HFAs as PCMs. 3-HFAs originating from biotechnologically obtained polyhydroxyalkanoates also showed potential to be applied in development of PCMs.", publisher = "John Wiley & Sons, Ltd.", journal = "International Journal of Energy Research", title = "Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials", volume = "44", number = "2", pages = "1294-1302", doi = "10.1002/er.4934" }
Jakšić, J., Ostojić, S., Micić, D., Tokić-Vujošević, Z., Milovanović, J., Karkalić, R., O'Connor, K. E., Kenny, S. T., Casey, W., Nikodinović-Runić, J.,& Maslak, V.. (2020). Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials. in International Journal of Energy Research John Wiley & Sons, Ltd.., 44(2), 1294-1302. https://doi.org/10.1002/er.4934
Jakšić J, Ostojić S, Micić D, Tokić-Vujošević Z, Milovanović J, Karkalić R, O'Connor KE, Kenny ST, Casey W, Nikodinović-Runić J, Maslak V. Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials. in International Journal of Energy Research. 2020;44(2):1294-1302. doi:10.1002/er.4934 .
Jakšić, Jovana, Ostojić, Sanja, Micić, Darko, Tokić-Vujošević, Zorana, Milovanović, Jelena, Karkalić, Radovan, O'Connor, Kevin E., Kenny, Shane T., Casey, William, Nikodinović-Runić, Jasmina, Maslak, Veselin, "Thermal properties of 3-hydroxy fatty acids and their binary mixtures as phase change energy storage materials" in International Journal of Energy Research, 44, no. 2 (2020):1294-1302, https://doi.org/10.1002/er.4934 . .