Saičić, Radomir N.

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orcid::0000-0003-3653-8294
  • Saičić, Radomir N. (6)
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Author's Bibliography

A Useful Synthetic Equivalent of a Hydroxyacetone Enolate

Bigović, Miljan; Maslak, Veselin; Tokić-Vujošević, Zorana; Divjaković, Vladimir; Saičić, Radomir N.

(Amer Chemical Soc, Washington, 2011)

TY  - JOUR
AU  - Bigović, Miljan
AU  - Maslak, Veselin
AU  - Tokić-Vujošević, Zorana
AU  - Divjaković, Vladimir
AU  - Saičić, Radomir N.
PY  - 2011
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1482
AB  - Indium promoted allyiation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords and-alpha,beta-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions Into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldois.
PB  - Amer Chemical Soc, Washington
T2  - Organic Letters
T1  - A Useful Synthetic Equivalent of a Hydroxyacetone Enolate
VL  - 13
IS  - 17
SP  - 4720
EP  - 4723
DO  - 10.1021/ol2019357
ER  - 
@article{
author = "Bigović, Miljan and Maslak, Veselin and Tokić-Vujošević, Zorana and Divjaković, Vladimir and Saičić, Radomir N.",
year = "2011",
abstract = "Indium promoted allyiation of carbonyl compounds with 4-(bromomethyl)-1,3-dioxol-2-one diastereoselectively affords and-alpha,beta-dihydroxyketones, protected as enol carbonates. These initial products can be deprotected to free dihydroxyketones or transformed under mild conditions Into the corresponding cyclic carbonates, which constitutes a useful approach to hydroxyacetone aldois.",
publisher = "Amer Chemical Soc, Washington",
journal = "Organic Letters",
title = "A Useful Synthetic Equivalent of a Hydroxyacetone Enolate",
volume = "13",
number = "17",
pages = "4720-4723",
doi = "10.1021/ol2019357"
}
Bigović, M., Maslak, V., Tokić-Vujošević, Z., Divjaković, V.,& Saičić, R. N.. (2011). A Useful Synthetic Equivalent of a Hydroxyacetone Enolate. in Organic Letters
Amer Chemical Soc, Washington., 13(17), 4720-4723.
https://doi.org/10.1021/ol2019357
Bigović M, Maslak V, Tokić-Vujošević Z, Divjaković V, Saičić RN. A Useful Synthetic Equivalent of a Hydroxyacetone Enolate. in Organic Letters. 2011;13(17):4720-4723.
doi:10.1021/ol2019357 .
Bigović, Miljan, Maslak, Veselin, Tokić-Vujošević, Zorana, Divjaković, Vladimir, Saičić, Radomir N., "A Useful Synthetic Equivalent of a Hydroxyacetone Enolate" in Organic Letters, 13, no. 17 (2011):4720-4723,
https://doi.org/10.1021/ol2019357 . .
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Palladium-catalyzed cross-couplings of allylic phosphates

Maslak, Veselin; Tokić-Vujošević, Zorana; Saičić, Radomir N.

(Pergamon-Elsevier Science Ltd, Oxford, 2009)

TY  - JOUR
AU  - Maslak, Veselin
AU  - Tokić-Vujošević, Zorana
AU  - Saičić, Radomir N.
PY  - 2009
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1220
AB  - A range of palladium-catalyzed cross-coupling reactions can be performed using allylic phosphates as electrophiles. Both conventional heating and microwave irradiation can be used.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Tetrahedron-Asymmetry
T1  - Palladium-catalyzed cross-couplings of allylic phosphates
VL  - 50
IS  - 16
SP  - 1858
EP  - 1860
DO  - 10.1016/j.tetlet.2009.02.026
ER  - 
@article{
author = "Maslak, Veselin and Tokić-Vujošević, Zorana and Saičić, Radomir N.",
year = "2009",
abstract = "A range of palladium-catalyzed cross-coupling reactions can be performed using allylic phosphates as electrophiles. Both conventional heating and microwave irradiation can be used.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Tetrahedron-Asymmetry",
title = "Palladium-catalyzed cross-couplings of allylic phosphates",
volume = "50",
number = "16",
pages = "1858-1860",
doi = "10.1016/j.tetlet.2009.02.026"
}
Maslak, V., Tokić-Vujošević, Z.,& Saičić, R. N.. (2009). Palladium-catalyzed cross-couplings of allylic phosphates. in Tetrahedron-Asymmetry
Pergamon-Elsevier Science Ltd, Oxford., 50(16), 1858-1860.
https://doi.org/10.1016/j.tetlet.2009.02.026
Maslak V, Tokić-Vujošević Z, Saičić RN. Palladium-catalyzed cross-couplings of allylic phosphates. in Tetrahedron-Asymmetry. 2009;50(16):1858-1860.
doi:10.1016/j.tetlet.2009.02.026 .
Maslak, Veselin, Tokić-Vujošević, Zorana, Saičić, Radomir N., "Palladium-catalyzed cross-couplings of allylic phosphates" in Tetrahedron-Asymmetry, 50, no. 16 (2009):1858-1860,
https://doi.org/10.1016/j.tetlet.2009.02.026 . .
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A useful synthetic equivalent of an acetone enolate

Maslak, Veselin; Tokić-Vujošević, Zorana; Ferjancić, Zorana; Saičić, Radomir N.

(Pergamon-Elsevier Science Ltd, Oxford, 2009)

TY  - JOUR
AU  - Maslak, Veselin
AU  - Tokić-Vujošević, Zorana
AU  - Ferjancić, Zorana
AU  - Saičić, Radomir N.
PY  - 2009
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/1204
AB  - 2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Tetrahedron-Asymmetry
T1  - A useful synthetic equivalent of an acetone enolate
VL  - 50
IS  - 48
SP  - 6709
EP  - 6711
DO  - 10.1016/j.tetlet.2009.09.113
ER  - 
@article{
author = "Maslak, Veselin and Tokić-Vujošević, Zorana and Ferjancić, Zorana and Saičić, Radomir N.",
year = "2009",
abstract = "2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Tetrahedron-Asymmetry",
title = "A useful synthetic equivalent of an acetone enolate",
volume = "50",
number = "48",
pages = "6709-6711",
doi = "10.1016/j.tetlet.2009.09.113"
}
Maslak, V., Tokić-Vujošević, Z., Ferjancić, Z.,& Saičić, R. N.. (2009). A useful synthetic equivalent of an acetone enolate. in Tetrahedron-Asymmetry
Pergamon-Elsevier Science Ltd, Oxford., 50(48), 6709-6711.
https://doi.org/10.1016/j.tetlet.2009.09.113
Maslak V, Tokić-Vujošević Z, Ferjancić Z, Saičić RN. A useful synthetic equivalent of an acetone enolate. in Tetrahedron-Asymmetry. 2009;50(48):6709-6711.
doi:10.1016/j.tetlet.2009.09.113 .
Maslak, Veselin, Tokić-Vujošević, Zorana, Ferjancić, Zorana, Saičić, Radomir N., "A useful synthetic equivalent of an acetone enolate" in Tetrahedron-Asymmetry, 50, no. 48 (2009):6709-6711,
https://doi.org/10.1016/j.tetlet.2009.09.113 . .
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Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C

Matović, Radomir; Ivković, Aleksandar; Manojlović, Marija; Tokić-Vujošević, Zorana; Saičić, Radomir N.

(Amer Chemical Soc, Washington, 2006)

TY  - JOUR
AU  - Matović, Radomir
AU  - Ivković, Aleksandar
AU  - Manojlović, Marija
AU  - Tokić-Vujošević, Zorana
AU  - Saičić, Radomir N.
PY  - 2006
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/685
AB  - The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Organic Chemistry
T1  - Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C
VL  - 71
IS  - 25
SP  - 9411
EP  - 9419
DO  - 10.1021/jo061790j
ER  - 
@article{
author = "Matović, Radomir and Ivković, Aleksandar and Manojlović, Marija and Tokić-Vujošević, Zorana and Saičić, Radomir N.",
year = "2006",
abstract = "The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Organic Chemistry",
title = "Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C",
volume = "71",
number = "25",
pages = "9411-9419",
doi = "10.1021/jo061790j"
}
Matović, R., Ivković, A., Manojlović, M., Tokić-Vujošević, Z.,& Saičić, R. N.. (2006). Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C. in Journal of Organic Chemistry
Amer Chemical Soc, Washington., 71(25), 9411-9419.
https://doi.org/10.1021/jo061790j
Matović R, Ivković A, Manojlović M, Tokić-Vujošević Z, Saičić RN. Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C. in Journal of Organic Chemistry. 2006;71(25):9411-9419.
doi:10.1021/jo061790j .
Matović, Radomir, Ivković, Aleksandar, Manojlović, Marija, Tokić-Vujošević, Zorana, Saičić, Radomir N., "Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C" in Journal of Organic Chemistry, 71, no. 25 (2006):9411-9419,
https://doi.org/10.1021/jo061790j . .
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Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach

Tokić-Vujošević, Zorana; Petrović, G; Rakić, B; Matović, Radomir; Saičić, Radomir N.

(Taylor & Francis Inc, Philadelphia, 2005)

TY  - JOUR
AU  - Tokić-Vujošević, Zorana
AU  - Petrović, G
AU  - Rakić, B
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2005
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/638
AB  - Immunomodulator (-)-cytoxazone and its epimer (+)-epi-cytoxazone were synthesized starting from (D)-(-)-4-hydroxyphenylglycine. Homologation of the amino acid was achieved via the corresponding aldehyde, by a cyanohydrin reaction. The racemization of highly sensible amido aldehyde was efficiently suppressed when the oxidation of the parent aminoalcohol was performed by a modified Dess-Martin procedure.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Tenside Surfactants Detergents
T1  - Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach
VL  - 35
IS  - 3
SP  - 435
EP  - 447
DO  - 10.1081/SCC-200048953
ER  - 
@article{
author = "Tokić-Vujošević, Zorana and Petrović, G and Rakić, B and Matović, Radomir and Saičić, Radomir N.",
year = "2005",
abstract = "Immunomodulator (-)-cytoxazone and its epimer (+)-epi-cytoxazone were synthesized starting from (D)-(-)-4-hydroxyphenylglycine. Homologation of the amino acid was achieved via the corresponding aldehyde, by a cyanohydrin reaction. The racemization of highly sensible amido aldehyde was efficiently suppressed when the oxidation of the parent aminoalcohol was performed by a modified Dess-Martin procedure.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Tenside Surfactants Detergents",
title = "Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach",
volume = "35",
number = "3",
pages = "435-447",
doi = "10.1081/SCC-200048953"
}
Tokić-Vujošević, Z., Petrović, G., Rakić, B., Matović, R.,& Saičić, R. N.. (2005). Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach. in Tenside Surfactants Detergents
Taylor & Francis Inc, Philadelphia., 35(3), 435-447.
https://doi.org/10.1081/SCC-200048953
Tokić-Vujošević Z, Petrović G, Rakić B, Matović R, Saičić RN. Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach. in Tenside Surfactants Detergents. 2005;35(3):435-447.
doi:10.1081/SCC-200048953 .
Tokić-Vujošević, Zorana, Petrović, G, Rakić, B, Matović, Radomir, Saičić, Radomir N., "Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach" in Tenside Surfactants Detergents, 35, no. 3 (2005):435-447,
https://doi.org/10.1081/SCC-200048953 . .
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Stereoselective synthesis of α-hydroxy-β-amino acids: The chiral pool approach

Tasić, Gordana; Matović, Radomir; Saičić, Radomir N.

(Srpsko hemijsko društvo, Beograd, 2004)

TY  - JOUR
AU  - Tasić, Gordana
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2004
UR  - https://farfar.pharmacy.bg.ac.rs/handle/123456789/548
AB  - A method for the stereoselective homologation of -amino acids into syn-α-hydroxy-β-amino acids is described, based on the conversion of stereoisomeric cyanohydrins into trans-oxazolines. The synthetic potential of the method is illustrated in the enantioselective formal synthesis of Bestatin.
AB  - Opisana je metoda za stereoselektivnu sintezu α-hidroksi-β-aminokiselina syn-konfiguracije, polazeći od α-aminokiselina, kao prirodnih hiralnih prekursora. Enantioselektivnost procesa zavisi od strukture polazne aminokiseline, kao i reakcionih uslova. Primena ove metode ilustrovana je u sintezi (2S,3R)-3-amino-2-hidroksi-4-fenilbutanske kiseline, konstituenta nekoliko važnih biološki aktivnih jedinjenja.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Stereoselective synthesis of α-hydroxy-β-amino acids: The chiral pool approach
T1  - Stereoselektivne sinteze α-hidroksi-β-aminokiselina iz prirodnih hiralnih prekursora
VL  - 69
IS  - 11
SP  - 981
EP  - 990
DO  - 10.2298/JSC0411981T
ER  - 
@article{
author = "Tasić, Gordana and Matović, Radomir and Saičić, Radomir N.",
year = "2004",
abstract = "A method for the stereoselective homologation of -amino acids into syn-α-hydroxy-β-amino acids is described, based on the conversion of stereoisomeric cyanohydrins into trans-oxazolines. The synthetic potential of the method is illustrated in the enantioselective formal synthesis of Bestatin., Opisana je metoda za stereoselektivnu sintezu α-hidroksi-β-aminokiselina syn-konfiguracije, polazeći od α-aminokiselina, kao prirodnih hiralnih prekursora. Enantioselektivnost procesa zavisi od strukture polazne aminokiseline, kao i reakcionih uslova. Primena ove metode ilustrovana je u sintezi (2S,3R)-3-amino-2-hidroksi-4-fenilbutanske kiseline, konstituenta nekoliko važnih biološki aktivnih jedinjenja.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Stereoselective synthesis of α-hydroxy-β-amino acids: The chiral pool approach, Stereoselektivne sinteze α-hidroksi-β-aminokiselina iz prirodnih hiralnih prekursora",
volume = "69",
number = "11",
pages = "981-990",
doi = "10.2298/JSC0411981T"
}
Tasić, G., Matović, R.,& Saičić, R. N.. (2004). Stereoselective synthesis of α-hydroxy-β-amino acids: The chiral pool approach. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 69(11), 981-990.
https://doi.org/10.2298/JSC0411981T
Tasić G, Matović R, Saičić RN. Stereoselective synthesis of α-hydroxy-β-amino acids: The chiral pool approach. in Journal of the Serbian Chemical Society. 2004;69(11):981-990.
doi:10.2298/JSC0411981T .
Tasić, Gordana, Matović, Radomir, Saičić, Radomir N., "Stereoselective synthesis of α-hydroxy-β-amino acids: The chiral pool approach" in Journal of the Serbian Chemical Society, 69, no. 11 (2004):981-990,
https://doi.org/10.2298/JSC0411981T . .
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