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Stereoselective synthesis of chiral beta(2,3)-disubstituted-beta-amino acid derivatives using Pd/In transmetallation cascade processes
(Pergamon-Elsevier Science Ltd, Oxford, 2008)
A new, highly efficient synthesis of chiral beta(2.3)-disubstituted-beta-amino acid derivatives has been developed, based on an allylation procedure employing allene and a catalytic Pd/In bimetallic process.
Reactive organoallyl species generated from aryl halides and allene: allylation of alpha,beta-unsaturated aldehydes and cyclic ketones employing Pd/In transmetallation processes
(Pergamon-Elsevier Science Ltd, Oxford, 2008)
Allylation of alpha,beta-unsaturated aldehydes and cyclic ketones promoted by Pd/In transmetallation processes has been Studied. The unsaturated aldehydes underwent regioselective 1,2-addition to afford secondary homoally ...